Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ2O1,O1′)(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)nickel(II) heptahydrate
In the title compound, [Ni(C9H4O6)(C12H12N2)(H2O)2]·7H2O, the NiII atom is six-coordinated by two O atoms from a chelating carboxylate group of a 5-carboxybenzene-1,3-dicarboxylate ligand, two O atoms of two water molecules and two N atoms from a 6,6′-dimethyl-2,2&...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811032090 |
| _version_ | 1828142869587689472 |
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| author | Wen-Wen Shan Han-Lin Xiong Chong-Zhen Mei |
| author_facet | Wen-Wen Shan Han-Lin Xiong Chong-Zhen Mei |
| author_sort | Wen-Wen Shan |
| collection | DOAJ |
| description | In the title compound, [Ni(C9H4O6)(C12H12N2)(H2O)2]·7H2O, the NiII atom is six-coordinated by two O atoms from a chelating carboxylate group of a 5-carboxybenzene-1,3-dicarboxylate ligand, two O atoms of two water molecules and two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand in a distorted octahedral geometry. The compound exhibits a three-dimensional supramolecular structure composed of the complex molecules and lattice water molecules, which are linked together by intermolecular O—H...O hydrogen bonds and partly overlapping π–π interactions between the pyridine and benzene rings [centroid–centroid distances = 3.922 (2) and 3.921 (2) Å]. One of the lattice water molecules is disordered over two positions in an occupancy ratio of 0.521 (6):0.479 (6). |
| first_indexed | 2024-04-11T19:47:47Z |
| format | Article |
| id | doaj.art-110d7ca60c4141d9ba6dfb72c1e098c3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:47:47Z |
| publishDate | 2011-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-110d7ca60c4141d9ba6dfb72c1e098c32022-12-22T04:06:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679m1244m124510.1107/S1600536811032090Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ2O1,O1′)(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)nickel(II) heptahydrateWen-Wen ShanHan-Lin XiongChong-Zhen MeiIn the title compound, [Ni(C9H4O6)(C12H12N2)(H2O)2]·7H2O, the NiII atom is six-coordinated by two O atoms from a chelating carboxylate group of a 5-carboxybenzene-1,3-dicarboxylate ligand, two O atoms of two water molecules and two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand in a distorted octahedral geometry. The compound exhibits a three-dimensional supramolecular structure composed of the complex molecules and lattice water molecules, which are linked together by intermolecular O—H...O hydrogen bonds and partly overlapping π–π interactions between the pyridine and benzene rings [centroid–centroid distances = 3.922 (2) and 3.921 (2) Å]. One of the lattice water molecules is disordered over two positions in an occupancy ratio of 0.521 (6):0.479 (6).http://scripts.iucr.org/cgi-bin/paper?S1600536811032090 |
| spellingShingle | Wen-Wen Shan Han-Lin Xiong Chong-Zhen Mei Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ2O1,O1′)(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)nickel(II) heptahydrate Acta Crystallographica Section E |
| title | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ2O1,O1′)(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)nickel(II) heptahydrate |
| title_full | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ2O1,O1′)(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)nickel(II) heptahydrate |
| title_fullStr | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ2O1,O1′)(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)nickel(II) heptahydrate |
| title_full_unstemmed | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ2O1,O1′)(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)nickel(II) heptahydrate |
| title_short | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ2O1,O1′)(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)nickel(II) heptahydrate |
| title_sort | diaqua 5 carboxybenzene 1 3 dicarboxylato amp 954 2o1 o1 amp 8242 6 6 amp 8242 dimethyl 2 2 amp 8242 bipyridine amp 954 2n n amp 8242 nickel ii heptahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811032090 |
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