Evaluation Model of Hard Limestone Reformation and Strength Weakening Based on Acidic Effect

The typical thick-hard limestone roof with high failure pressure and easy fracture closure under in situ stress is extremely prone to induce disasters, which seriously threatens the safe production of coal mines. The modification of carbonate minerals by acidic effects can effectively realize the we...

Full description

Bibliographic Details
Main Authors: Mingxiao Hou, Bingxiang Huang, Xinglong Zhao, Xuejie Jiao, Xufei Jiang, Zheng Sun
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/13/8/1101
_version_ 1797583671922786304
author Mingxiao Hou
Bingxiang Huang
Xinglong Zhao
Xuejie Jiao
Xufei Jiang
Zheng Sun
author_facet Mingxiao Hou
Bingxiang Huang
Xinglong Zhao
Xuejie Jiao
Xufei Jiang
Zheng Sun
author_sort Mingxiao Hou
collection DOAJ
description The typical thick-hard limestone roof with high failure pressure and easy fracture closure under in situ stress is extremely prone to induce disasters, which seriously threatens the safe production of coal mines. The modification of carbonate minerals by acidic effects can effectively realize the weakening control of hard limestone strata. In this study, a multi-factor orthogonal experiment was designed for limestone acidification reactions, and the evaluation model for the reformation and strength weakening of hard limestone based on the acidic effect was established accordingly. The results showed that there is an order in the influence of various factors on the reaction parameters and strength indices of acidified limestone, and the improvement of rock properties by the level difference of acid concentration is significantly better than that of acid type and acidification time. Through numerical analysis, the evaluation model of limestone reformation and strength weakening considering the acid reaction parameters is given. The reliability of the model passed the credibility test and experimental verification, which can effectively reflect the strength response characteristics of acidified limestone. The simulated annealing (SA) algorithm is introduced to derive the optimal acidification system suitable for limestone weakening. Combined with the model, the control mechanism of the acidic effect on hard limestone strata was analyzed. The acidic effect can not only induce the rapid generation and expansion of micro-cracks at mineral-containing crystal defects, but also make the cracks remain relatively open under in situ stress due to the differential interaction on mineral components, which is conducive to the bearing capacity reduction and structural damage of limestone rock mass. The research results provide theoretical guidance for the acidification control of hard limestone strata in underground mines.
first_indexed 2024-03-10T23:42:12Z
format Article
id doaj.art-111c3b1d6ed04cfdae6a769f094ca4bf
institution Directory Open Access Journal
issn 2075-163X
language English
last_indexed 2024-03-10T23:42:12Z
publishDate 2023-08-01
publisher MDPI AG
record_format Article
series Minerals
spelling doaj.art-111c3b1d6ed04cfdae6a769f094ca4bf2023-11-19T02:21:50ZengMDPI AGMinerals2075-163X2023-08-01138110110.3390/min13081101Evaluation Model of Hard Limestone Reformation and Strength Weakening Based on Acidic EffectMingxiao Hou0Bingxiang Huang1Xinglong Zhao2Xuejie Jiao3Xufei Jiang4Zheng Sun5State Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Xuzhou 221116, ChinaState Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Xuzhou 221116, ChinaState Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Xuzhou 221116, ChinaState Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Xuzhou 221116, ChinaState Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Xuzhou 221116, ChinaState Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Xuzhou 221116, ChinaThe typical thick-hard limestone roof with high failure pressure and easy fracture closure under in situ stress is extremely prone to induce disasters, which seriously threatens the safe production of coal mines. The modification of carbonate minerals by acidic effects can effectively realize the weakening control of hard limestone strata. In this study, a multi-factor orthogonal experiment was designed for limestone acidification reactions, and the evaluation model for the reformation and strength weakening of hard limestone based on the acidic effect was established accordingly. The results showed that there is an order in the influence of various factors on the reaction parameters and strength indices of acidified limestone, and the improvement of rock properties by the level difference of acid concentration is significantly better than that of acid type and acidification time. Through numerical analysis, the evaluation model of limestone reformation and strength weakening considering the acid reaction parameters is given. The reliability of the model passed the credibility test and experimental verification, which can effectively reflect the strength response characteristics of acidified limestone. The simulated annealing (SA) algorithm is introduced to derive the optimal acidification system suitable for limestone weakening. Combined with the model, the control mechanism of the acidic effect on hard limestone strata was analyzed. The acidic effect can not only induce the rapid generation and expansion of micro-cracks at mineral-containing crystal defects, but also make the cracks remain relatively open under in situ stress due to the differential interaction on mineral components, which is conducive to the bearing capacity reduction and structural damage of limestone rock mass. The research results provide theoretical guidance for the acidification control of hard limestone strata in underground mines.https://www.mdpi.com/2075-163X/13/8/1101acidic effecthard stratumevaluation modelcrystal defectstrength weakening
spellingShingle Mingxiao Hou
Bingxiang Huang
Xinglong Zhao
Xuejie Jiao
Xufei Jiang
Zheng Sun
Evaluation Model of Hard Limestone Reformation and Strength Weakening Based on Acidic Effect
Minerals
acidic effect
hard stratum
evaluation model
crystal defect
strength weakening
title Evaluation Model of Hard Limestone Reformation and Strength Weakening Based on Acidic Effect
title_full Evaluation Model of Hard Limestone Reformation and Strength Weakening Based on Acidic Effect
title_fullStr Evaluation Model of Hard Limestone Reformation and Strength Weakening Based on Acidic Effect
title_full_unstemmed Evaluation Model of Hard Limestone Reformation and Strength Weakening Based on Acidic Effect
title_short Evaluation Model of Hard Limestone Reformation and Strength Weakening Based on Acidic Effect
title_sort evaluation model of hard limestone reformation and strength weakening based on acidic effect
topic acidic effect
hard stratum
evaluation model
crystal defect
strength weakening
url https://www.mdpi.com/2075-163X/13/8/1101
work_keys_str_mv AT mingxiaohou evaluationmodelofhardlimestonereformationandstrengthweakeningbasedonacidiceffect
AT bingxianghuang evaluationmodelofhardlimestonereformationandstrengthweakeningbasedonacidiceffect
AT xinglongzhao evaluationmodelofhardlimestonereformationandstrengthweakeningbasedonacidiceffect
AT xuejiejiao evaluationmodelofhardlimestonereformationandstrengthweakeningbasedonacidiceffect
AT xufeijiang evaluationmodelofhardlimestonereformationandstrengthweakeningbasedonacidiceffect
AT zhengsun evaluationmodelofhardlimestonereformationandstrengthweakeningbasedonacidiceffect