Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles
Abstract In this work, a cost-effective, environmentally friendly, and convenient method for synthesizing a novel heterogeneous catalyst via modification of polystyrene using tetrazole-copper magnetic complex [Ps@Tet-Cu(II)@Fe3O4] has been successfully developed. The synthesized complex was analyzed...
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2023-02-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-023-30198-7 |
| _version_ | 1797864805850152960 |
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| author | Mahmoud Nasrollahzadeh Narjes Motahharifar Khatereh Pakzad Zahra Khorsandi Talat Baran Jinghan Wang Benjamin Kruppke Hossein Ali Khonakdar |
| author_facet | Mahmoud Nasrollahzadeh Narjes Motahharifar Khatereh Pakzad Zahra Khorsandi Talat Baran Jinghan Wang Benjamin Kruppke Hossein Ali Khonakdar |
| author_sort | Mahmoud Nasrollahzadeh |
| collection | DOAJ |
| description | Abstract In this work, a cost-effective, environmentally friendly, and convenient method for synthesizing a novel heterogeneous catalyst via modification of polystyrene using tetrazole-copper magnetic complex [Ps@Tet-Cu(II)@Fe3O4] has been successfully developed. The synthesized complex was analyzed using TEM (transmission electron microscopy), HRTEM (high resolution-transmission electron microscopy), STEM (scanning transmission electron microscopy), FFT (Fast Fourier transform), XRD (X-ray diffraction), FT-IR (Fourier transform-infrared spectroscopy), TG/DTG (Thermogravimetry and differential thermogravimetry), ICP-OES (Inductively coupled plasma-optical emission spectrometry), Vibrating sample magnetometer (VSM), EDS (energy dispersive X-ray spectroscopy), and elemental mapping. N-Sulfonyl-N-aryl tetrazoles were synthesized in high yields from N-sulfonyl-N-aryl cyanamides and sodium azide using Ps@Tet-Cu(II)@Fe3O4 nanocatalyst. The Ps@Tet-Cu(II)@Fe3O4 complex can be recycled and reused easily multiple times using an external magnet without significant loss of catalytic activity. |
| first_indexed | 2024-04-09T22:58:02Z |
| format | Article |
| id | doaj.art-1123d7990f8c45d3ad9d72b434f0c8a5 |
| institution | Directory Open Access Journal |
| issn | 2045-2322 |
| language | English |
| last_indexed | 2024-04-09T22:58:02Z |
| publishDate | 2023-02-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj.art-1123d7990f8c45d3ad9d72b434f0c8a52023-03-22T11:07:08ZengNature PortfolioScientific Reports2045-23222023-02-0113111710.1038/s41598-023-30198-7Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazolesMahmoud Nasrollahzadeh0Narjes Motahharifar1Khatereh Pakzad2Zahra Khorsandi3Talat Baran4Jinghan Wang5Benjamin Kruppke6Hossein Ali Khonakdar7Department of Chemistry, Faculty of Science, University of QomDepartment of Chemistry, Faculty of Science, University of QomDepartment of Chemistry, Faculty of Science, University of QomDepartment of Chemistry, Faculty of Science, University of QomDepartment of Chemistry, Faculty of Science and Letters, Aksaray UniversityDepartment of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National UniversityMax Bergmann Center of Biomaterials, Institute of Materials Science, Technische Universität DresdenMax Bergmann Center of Biomaterials, Institute of Materials Science, Technische Universität DresdenAbstract In this work, a cost-effective, environmentally friendly, and convenient method for synthesizing a novel heterogeneous catalyst via modification of polystyrene using tetrazole-copper magnetic complex [Ps@Tet-Cu(II)@Fe3O4] has been successfully developed. The synthesized complex was analyzed using TEM (transmission electron microscopy), HRTEM (high resolution-transmission electron microscopy), STEM (scanning transmission electron microscopy), FFT (Fast Fourier transform), XRD (X-ray diffraction), FT-IR (Fourier transform-infrared spectroscopy), TG/DTG (Thermogravimetry and differential thermogravimetry), ICP-OES (Inductively coupled plasma-optical emission spectrometry), Vibrating sample magnetometer (VSM), EDS (energy dispersive X-ray spectroscopy), and elemental mapping. N-Sulfonyl-N-aryl tetrazoles were synthesized in high yields from N-sulfonyl-N-aryl cyanamides and sodium azide using Ps@Tet-Cu(II)@Fe3O4 nanocatalyst. The Ps@Tet-Cu(II)@Fe3O4 complex can be recycled and reused easily multiple times using an external magnet without significant loss of catalytic activity.https://doi.org/10.1038/s41598-023-30198-7 |
| spellingShingle | Mahmoud Nasrollahzadeh Narjes Motahharifar Khatereh Pakzad Zahra Khorsandi Talat Baran Jinghan Wang Benjamin Kruppke Hossein Ali Khonakdar Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles Scientific Reports |
| title | Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles |
| title_full | Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles |
| title_fullStr | Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles |
| title_full_unstemmed | Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles |
| title_short | Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles |
| title_sort | synthesis of a magnetic polystyrene supported cu ii containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of n sulfonyl n aryl tetrazoles |
| url | https://doi.org/10.1038/s41598-023-30198-7 |
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