One-Pot Synthesis of Cu(II) Complex with Partially Oxidized TTF Moieties
The one-pot synthesis of a Cu(II) complex with partially oxidized tetrathiafulvalene (TTF) moieties in its capping MT-Hsae-TTF ligands, [CuII(MT-sae-TTF)2] [CuICl2] was realized by the simultaneous occurrence of Cu(II) complexation and CuIICl2 mediated oxidation of TTF moieties. The crystal structur...
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MDPI AG
2012-07-01
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| Series: | Crystals |
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| Online Access: | http://www.mdpi.com/2073-4352/2/3/935 |
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| author | Hiroki Oshio Takuya Shiga Kiyotaka Mitsumoto Ryosuke Kitabatake Hiroyuki Nishikawa |
| author_facet | Hiroki Oshio Takuya Shiga Kiyotaka Mitsumoto Ryosuke Kitabatake Hiroyuki Nishikawa |
| author_sort | Hiroki Oshio |
| collection | DOAJ |
| description | The one-pot synthesis of a Cu(II) complex with partially oxidized tetrathiafulvalene (TTF) moieties in its capping MT-Hsae-TTF ligands, [CuII(MT-sae-TTF)2] [CuICl2] was realized by the simultaneous occurrence of Cu(II) complexation and CuIICl2 mediated oxidation of TTF moieties. The crystal structure was composed of one-dimensional columns formed by partially oxidized TTF moieties and thus the cation radical salt showed relatively high electrical conductivity. Tight binding band structure calculations indicated the existence of a Peierls gap due to the tetramerization of the TTF moieties in the one-dimensional stacking column at room temperature, which is consistent with the semiconducting behavior of this salt. |
| first_indexed | 2024-04-14T02:17:15Z |
| format | Article |
| id | doaj.art-113b125dc53641c3b5991ca314ddecfc |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-14T02:17:15Z |
| publishDate | 2012-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-113b125dc53641c3b5991ca314ddecfc2022-12-22T02:18:08ZengMDPI AGCrystals2073-43522012-07-012393594510.3390/cryst2030935One-Pot Synthesis of Cu(II) Complex with Partially Oxidized TTF MoietiesHiroki OshioTakuya ShigaKiyotaka MitsumotoRyosuke KitabatakeHiroyuki NishikawaThe one-pot synthesis of a Cu(II) complex with partially oxidized tetrathiafulvalene (TTF) moieties in its capping MT-Hsae-TTF ligands, [CuII(MT-sae-TTF)2] [CuICl2] was realized by the simultaneous occurrence of Cu(II) complexation and CuIICl2 mediated oxidation of TTF moieties. The crystal structure was composed of one-dimensional columns formed by partially oxidized TTF moieties and thus the cation radical salt showed relatively high electrical conductivity. Tight binding band structure calculations indicated the existence of a Peierls gap due to the tetramerization of the TTF moieties in the one-dimensional stacking column at room temperature, which is consistent with the semiconducting behavior of this salt.http://www.mdpi.com/2073-4352/2/3/935TTF-based metal complexSchiff base-type TTF-ligandpartial oxidation of TTFone-pot synthesiselectrical conductivityπ-d interaction |
| spellingShingle | Hiroki Oshio Takuya Shiga Kiyotaka Mitsumoto Ryosuke Kitabatake Hiroyuki Nishikawa One-Pot Synthesis of Cu(II) Complex with Partially Oxidized TTF Moieties Crystals TTF-based metal complex Schiff base-type TTF-ligand partial oxidation of TTF one-pot synthesis electrical conductivity π-d interaction |
| title | One-Pot Synthesis of Cu(II) Complex with Partially Oxidized TTF Moieties |
| title_full | One-Pot Synthesis of Cu(II) Complex with Partially Oxidized TTF Moieties |
| title_fullStr | One-Pot Synthesis of Cu(II) Complex with Partially Oxidized TTF Moieties |
| title_full_unstemmed | One-Pot Synthesis of Cu(II) Complex with Partially Oxidized TTF Moieties |
| title_short | One-Pot Synthesis of Cu(II) Complex with Partially Oxidized TTF Moieties |
| title_sort | one pot synthesis of cu ii complex with partially oxidized ttf moieties |
| topic | TTF-based metal complex Schiff base-type TTF-ligand partial oxidation of TTF one-pot synthesis electrical conductivity π-d interaction |
| url | http://www.mdpi.com/2073-4352/2/3/935 |
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