| Summary: | An effective approach for preparing electrically conductive multiscale SiAlON-based nanocomposites with 10 wt.% and 20 wt.% of titanium nitride was developed. Fully dense samples were obtained by spark plasma sintering (SPS) at 1700 °C and 80 MPa for 30 min. The morphology of nanocomposites was observed using scanning electron microscopy and the effects of TiN particles on the mechanical properties and electrical resistivity were studied. It was found that the addition of 20 wt.% TiN increased the hardness and fracture toughness compared to the commercial ceramic analogue TC3030. Meanwhile, the presence of TiN particles reduced the flexural strength of the nanocomposites due to the shrinkage difference between TiN particles and ceramic matrix during cooling, which led to tensile residual stresses and, consequently, to changes in strength values. In addition, the electrical resistivity of nanocomposites decreased with the increase of TiN content and reached 1.6 × 10<sup>−4</sup> Ω∙m for 20 wt.% amount of second phase, which consequently made them suitable for electrical discharge machining. In addition to enhanced mechanical and electrical properties, under identical conditions, SPS-sintered multiscale nanocomposites exhibited a higher wear resistance (more than about 1.5-times) compared to the commercial sample due to their higher toughness and hardness.
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