Effect of viscoelasticity in polymer nanofiber electrospinning: Simulation using FENE-CR model

The uniaxial elongational flow of a polymer solution in the electrospinning process was investigated numerically and experimentally. The numerical model was constructed taking into account the viscoelasticity of the material. Therefore, governing equations were supported by a finite extensible non-l...

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Main Authors: Serife Akkoyun, Nuray Öktem
Format: Article
Language:English
Published: Elsevier 2021-06-01
Series:Engineering Science and Technology, an International Journal
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2215098620342786
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author Serife Akkoyun
Nuray Öktem
author_facet Serife Akkoyun
Nuray Öktem
author_sort Serife Akkoyun
collection DOAJ
description The uniaxial elongational flow of a polymer solution in the electrospinning process was investigated numerically and experimentally. The numerical model was constructed taking into account the viscoelasticity of the material. Therefore, governing equations were supported by a finite extensible non-linear elastic constitutive model and for the first time a FENE-CR model was used. This version of FENE model allows a good description of the rheology of extensional flows. For validation purposes, experimental studies were conducted using polymeric solutions of polyamide 6 (PA6). The main emphasis was made in determining the final fiber diameter and how initial polymer concentration acts on it. Further, the effect of the different concentration regimes on thinning dynamics was also examined. The comparative results of the numerical and experimental outcomes are sufficient to prove the predictive ability of the simulations. It can also be observed that the numerical approach adopted in this study captures not only the viscoelastic behavior of the material but also solidification of nanofibers due to solvent evaporation. As predictive quantitative models for electrospinning are lacking, this study gives good insights into the simulation of this process.
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spelling doaj.art-11a04b21b66e4f318c93a4aa1e2790da2022-12-21T22:31:38ZengElsevierEngineering Science and Technology, an International Journal2215-09862021-06-01243620630Effect of viscoelasticity in polymer nanofiber electrospinning: Simulation using FENE-CR modelSerife Akkoyun0Nuray Öktem1Ankara Yildirim Beyazit University, Department of Metallurgical and Materials Engineering, Ankara 06010, Turkey; Corresponding author.Ankara Yildirim Beyazit University, Department of Mathematics, Ankara 06010, TurkeyThe uniaxial elongational flow of a polymer solution in the electrospinning process was investigated numerically and experimentally. The numerical model was constructed taking into account the viscoelasticity of the material. Therefore, governing equations were supported by a finite extensible non-linear elastic constitutive model and for the first time a FENE-CR model was used. This version of FENE model allows a good description of the rheology of extensional flows. For validation purposes, experimental studies were conducted using polymeric solutions of polyamide 6 (PA6). The main emphasis was made in determining the final fiber diameter and how initial polymer concentration acts on it. Further, the effect of the different concentration regimes on thinning dynamics was also examined. The comparative results of the numerical and experimental outcomes are sufficient to prove the predictive ability of the simulations. It can also be observed that the numerical approach adopted in this study captures not only the viscoelastic behavior of the material but also solidification of nanofibers due to solvent evaporation. As predictive quantitative models for electrospinning are lacking, this study gives good insights into the simulation of this process.http://www.sciencedirect.com/science/article/pii/S2215098620342786ElectrospinningPolymer nanofiberFENE-CRElongational flowViscoelasticity
spellingShingle Serife Akkoyun
Nuray Öktem
Effect of viscoelasticity in polymer nanofiber electrospinning: Simulation using FENE-CR model
Engineering Science and Technology, an International Journal
Electrospinning
Polymer nanofiber
FENE-CR
Elongational flow
Viscoelasticity
title Effect of viscoelasticity in polymer nanofiber electrospinning: Simulation using FENE-CR model
title_full Effect of viscoelasticity in polymer nanofiber electrospinning: Simulation using FENE-CR model
title_fullStr Effect of viscoelasticity in polymer nanofiber electrospinning: Simulation using FENE-CR model
title_full_unstemmed Effect of viscoelasticity in polymer nanofiber electrospinning: Simulation using FENE-CR model
title_short Effect of viscoelasticity in polymer nanofiber electrospinning: Simulation using FENE-CR model
title_sort effect of viscoelasticity in polymer nanofiber electrospinning simulation using fene cr model
topic Electrospinning
Polymer nanofiber
FENE-CR
Elongational flow
Viscoelasticity
url http://www.sciencedirect.com/science/article/pii/S2215098620342786
work_keys_str_mv AT serifeakkoyun effectofviscoelasticityinpolymernanofiberelectrospinningsimulationusingfenecrmodel
AT nurayoktem effectofviscoelasticityinpolymernanofiberelectrospinningsimulationusingfenecrmodel