(8-Bromo-2,7-dimethoxy-1-naphthyl)(4-chlorophenyl)methanone
In the title compound, C19H14BrClO3, the naphthalene ring system and the benzene ring make a dihedral angle of 77.36 (10)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810009463 |
| _version_ | 1819105672281718784 |
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| author | Ryosuke Mitsui Atsushi Nagasawa Shoji Watanabe Akiko Okamoto Noriyuki Yonezawa |
| author_facet | Ryosuke Mitsui Atsushi Nagasawa Shoji Watanabe Akiko Okamoto Noriyuki Yonezawa |
| author_sort | Ryosuke Mitsui |
| collection | DOAJ |
| description | In the title compound, C19H14BrClO3, the naphthalene ring system and the benzene ring make a dihedral angle of 77.36 (10)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 75.73 (15)° versus 2.33 (17)°. In the crystal structure, a π–π interaction is formed between naphthalene ring systems, with a centroid–centroid distance of 3.8363 (14) Å and a lateral offset of 1.606 Å. Intermolecular C—H...Br and C—H...O hydrogen bonds and a C—H...π contact are present in the crystal structure. |
| first_indexed | 2024-12-22T02:25:58Z |
| format | Article |
| id | doaj.art-11c96b24ba1a4d97b7be64629185d5bb |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:25:58Z |
| publishDate | 2010-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-11c96b24ba1a4d97b7be64629185d5bb2022-12-21T18:42:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664o873o87310.1107/S1600536810009463(8-Bromo-2,7-dimethoxy-1-naphthyl)(4-chlorophenyl)methanoneRyosuke MitsuiAtsushi NagasawaShoji WatanabeAkiko OkamotoNoriyuki YonezawaIn the title compound, C19H14BrClO3, the naphthalene ring system and the benzene ring make a dihedral angle of 77.36 (10)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 75.73 (15)° versus 2.33 (17)°. In the crystal structure, a π–π interaction is formed between naphthalene ring systems, with a centroid–centroid distance of 3.8363 (14) Å and a lateral offset of 1.606 Å. Intermolecular C—H...Br and C—H...O hydrogen bonds and a C—H...π contact are present in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536810009463 |
| spellingShingle | Ryosuke Mitsui Atsushi Nagasawa Shoji Watanabe Akiko Okamoto Noriyuki Yonezawa (8-Bromo-2,7-dimethoxy-1-naphthyl)(4-chlorophenyl)methanone Acta Crystallographica Section E |
| title | (8-Bromo-2,7-dimethoxy-1-naphthyl)(4-chlorophenyl)methanone |
| title_full | (8-Bromo-2,7-dimethoxy-1-naphthyl)(4-chlorophenyl)methanone |
| title_fullStr | (8-Bromo-2,7-dimethoxy-1-naphthyl)(4-chlorophenyl)methanone |
| title_full_unstemmed | (8-Bromo-2,7-dimethoxy-1-naphthyl)(4-chlorophenyl)methanone |
| title_short | (8-Bromo-2,7-dimethoxy-1-naphthyl)(4-chlorophenyl)methanone |
| title_sort | 8 bromo 2 7 dimethoxy 1 naphthyl 4 chlorophenyl methanone |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810009463 |
| work_keys_str_mv | AT ryosukemitsui 8bromo27dimethoxy1naphthyl4chlorophenylmethanone AT atsushinagasawa 8bromo27dimethoxy1naphthyl4chlorophenylmethanone AT shojiwatanabe 8bromo27dimethoxy1naphthyl4chlorophenylmethanone AT akikookamoto 8bromo27dimethoxy1naphthyl4chlorophenylmethanone AT noriyukiyonezawa 8bromo27dimethoxy1naphthyl4chlorophenylmethanone |