Permeability of Hydrate-Bearing Sediment Formed from CO<sub>2</sub>-N<sub>2</sub> Mixture

CO<sub>2</sub>-N<sub>2</sub>-mixture injection can be used for the exploitation and reformation of natural gas hydrate reservoirs. The permeability evolution of sediments in the presence of CO<sub>2</sub>-N<sub>2</sub> hydrate is very important. In cur...

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Bibliographic Details
Main Authors: Nan Li, Ziyang Fan, Haoran Ma, Shuai Jia, Jingyu Kan, Changyu Sun, Shun Liu
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Journal of Marine Science and Engineering
Subjects:
Online Access:https://www.mdpi.com/2077-1312/11/2/376
Description
Summary:CO<sub>2</sub>-N<sub>2</sub>-mixture injection can be used for the exploitation and reformation of natural gas hydrate reservoirs. The permeability evolution of sediments in the presence of CO<sub>2</sub>-N<sub>2</sub> hydrate is very important. In current permeability tests, hydrate-bearing sediment formed from CO<sub>2</sub>-N<sub>2</sub> gas mixture is rarely involved. In this work, hydrate-bearing sediment was formed from CO<sub>2</sub>-N<sub>2</sub> mixtures, and a constant flow method was employed to measure the permeability of the hydrate-bearing sediments. The effects of CO<sub>2</sub> mole fraction and hydrate saturation on the permeability were investigated. The results show that gas composition is the key factor affecting hydrate formation. Hydrate saturation increases with increasing CO<sub>2</sub> mole fraction in the gas mixture. The presence of hydrate formed from a CO<sub>2</sub>-N<sub>2</sub> mixture leads to a sharp permeability reduction. The higher the fraction of CO<sub>2</sub> in the injected gas mixture, the lower the sediment’s permeability. Our measured permeability data were also compared with and fitted to prediction models. The pore-filling model underestimates the permeability of hydrate-bearing sediments formed from a CO<sub>2</sub>-N<sub>2</sub> gas mixture. The fitted hydrate saturation index in the Masuda model is 15.35, slightly higher than the general values, which means that the formed hydrates tend to occupy the pore center, and even block the pore throat.
ISSN:2077-1312