Application of Covalent Organic Frameworks (COFs) in Cyclic Carbonate Production using a Green Method: An Overview

One of the strategies suggested for solving the greenhouse gas problem is the transformation of CO<sub>2</sub> into valuable chemicals, such as carbamates, cyclic carbonates, oxazolidones and tetramic acids. Among these chemicals, cyclic carbonates can be used in lithium-ion batteries as...

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Bibliographic Details
Main Author: Gamze Ozcakir
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Materials Proceedings
Subjects:
Online Access:https://www.mdpi.com/2673-4605/14/1/24
Description
Summary:One of the strategies suggested for solving the greenhouse gas problem is the transformation of CO<sub>2</sub> into valuable chemicals, such as carbamates, cyclic carbonates, oxazolidones and tetramic acids. Among these chemicals, cyclic carbonates can be used in lithium-ion batteries as electrolytes. Cyclic carbonate production via CO<sub>2</sub> cycloaddition is feasible method in terms of thermodynamic and atom economy. However, CO<sub>2</sub> transformation processes require high energy. So, researchers have studied several catalysts. Covalent organic frameworks (COFs) can have success even under humid conditions in cyclic carbonate production via CO<sub>2</sub> cycloaddition. The features of COFs are low density, large surface area and adjustable pore size and structure.
ISSN:2673-4605