Crystal structure of dichlorido(1,2-phenylenediamine-κ2N,N′)platinum(II)
The PtII atom in the title compound, [PtCl2{(C6H4)(NH2)2}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenylenediamine ligand and two Cl− ions. In the crystal, the planar complex molecules are stacked parallel...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2017-07-01
|
| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989017008477 |
| _version_ | 1819003476021084160 |
|---|---|
| author | Yosuke Konno Nobuyuki Matsushita |
| author_facet | Yosuke Konno Nobuyuki Matsushita |
| author_sort | Yosuke Konno |
| collection | DOAJ |
| description | The PtII atom in the title compound, [PtCl2{(C6H4)(NH2)2}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenylenediamine ligand and two Cl− ions. In the crystal, the planar complex molecules are stacked parallel to the c axis, resulting in a columnar structure. In a column, an infinite almost straight Pt...Pt chain is formed, suggesting weak metal–metal interactions [Pt...Pt = 3.3475 (8) Å]. The crystal packing is stabilized by a three-dimensional N—H...Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent molecules. |
| first_indexed | 2024-12-20T23:21:36Z |
| format | Article |
| id | doaj.art-11e8e4d6f3f840a49e24e04fc3aa940d |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T23:21:36Z |
| publishDate | 2017-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-11e8e4d6f3f840a49e24e04fc3aa940d2022-12-21T19:23:30ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-07-017371009101210.1107/S2056989017008477wm5396Crystal structure of dichlorido(1,2-phenylenediamine-κ2N,N′)platinum(II)Yosuke Konno0Nobuyuki Matsushita1Department of Chemistry, Graduate School of Arts and Sciences, The University of Tokyo, Komaba 3-8-1, Meguro-ku, Tokyo, 153-8902, JapanDepartment of Chemistry & Research Center for Smart Molecules, Rikkyo University, Nishi-Ikebukuro 3-34-1, Toshima-ku, Tokyo, 171-8501, JapanThe PtII atom in the title compound, [PtCl2{(C6H4)(NH2)2}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenylenediamine ligand and two Cl− ions. In the crystal, the planar complex molecules are stacked parallel to the c axis, resulting in a columnar structure. In a column, an infinite almost straight Pt...Pt chain is formed, suggesting weak metal–metal interactions [Pt...Pt = 3.3475 (8) Å]. The crystal packing is stabilized by a three-dimensional N—H...Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent molecules.http://scripts.iucr.org/cgi-bin/paper?S2056989017008477crystal structurecolumnar structureinfinite metal chainplatinum(II) complexhydrogen bonding |
| spellingShingle | Yosuke Konno Nobuyuki Matsushita Crystal structure of dichlorido(1,2-phenylenediamine-κ2N,N′)platinum(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure columnar structure infinite metal chain platinum(II) complex hydrogen bonding |
| title | Crystal structure of dichlorido(1,2-phenylenediamine-κ2N,N′)platinum(II) |
| title_full | Crystal structure of dichlorido(1,2-phenylenediamine-κ2N,N′)platinum(II) |
| title_fullStr | Crystal structure of dichlorido(1,2-phenylenediamine-κ2N,N′)platinum(II) |
| title_full_unstemmed | Crystal structure of dichlorido(1,2-phenylenediamine-κ2N,N′)platinum(II) |
| title_short | Crystal structure of dichlorido(1,2-phenylenediamine-κ2N,N′)platinum(II) |
| title_sort | crystal structure of dichlorido 1 2 phenylenediamine κ2n n platinum ii |
| topic | crystal structure columnar structure infinite metal chain platinum(II) complex hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989017008477 |
| work_keys_str_mv | AT yosukekonno crystalstructureofdichlorido12phenylenediaminek2nnplatinumii AT nobuyukimatsushita crystalstructureofdichlorido12phenylenediaminek2nnplatinumii |