Experimental Comparison of Three Characterization Methods for Two Phase Change Materials Suitable for Domestic Hot Water Storage

This study presents an experimental comparison of three characterization methods for phase change materials (PCM). Two methods were carried out with a calorimeter, the first with direct scanning (DSC) and the second with step scanning (STEP). The third method is a fluxmetric (FM) characterization pe...

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Main Authors: Maxime Thonon, Laurent Zalewski, Stéphane Gibout, Erwin Franquet, Gilles Fraisse, Mickael Pailha
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/11/21/10229
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author Maxime Thonon
Laurent Zalewski
Stéphane Gibout
Erwin Franquet
Gilles Fraisse
Mickael Pailha
author_facet Maxime Thonon
Laurent Zalewski
Stéphane Gibout
Erwin Franquet
Gilles Fraisse
Mickael Pailha
author_sort Maxime Thonon
collection DOAJ
description This study presents an experimental comparison of three characterization methods for phase change materials (PCM). Two methods were carried out with a calorimeter, the first with direct scanning (DSC) and the second with step scanning (STEP). The third method is a fluxmetric (FM) characterization performed using a fluxmeter bench. For the three methods, paraffin RT58 and polymer PEG6000, two PCM suitable for domestic hot water (DHW) storage, were characterized. For each PCM, no significant difference was observed on the latent heat and the total energy exchanged between the three characterization methods. However, DSC and STEP methods did not enable the accurate characterization of the supercooling process observed with the FM method for polymer PEG6000. For PEG6000, the shape of the enthalpy curve of melting also differed between the experiments on the calorimeter—DSC and STEP—methods, and the FM method. Concerning the PCM comparison, RT58 and PEG6000 appeared to have an equivalent energy density but, as the mass density of PEG6000 is greater, more energy is stored inside the same volume for PEG6000. However, as PEG6000 experienced supercooling, the discharging temperature was lower than for RT58 and the material is therefore less adapted to DHW storage operating with partial phase change cycles where the PCM temperature does not decrease below 52 °C.
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spelling doaj.art-11fb953595624dadb7ae883916deb8732023-11-22T20:29:42ZengMDPI AGApplied Sciences2076-34172021-11-0111211022910.3390/app112110229Experimental Comparison of Three Characterization Methods for Two Phase Change Materials Suitable for Domestic Hot Water StorageMaxime Thonon0Laurent Zalewski1Stéphane Gibout2Erwin Franquet3Gilles Fraisse4Mickael Pailha5Laboratoire LOCIE, CNRS, Savoie Mont Blanc University, 73000 Chambéry, FranceLaboratoire de Génie Civil et Géo-Environnement, Institut Mines-Télécom, Junia, ULR 4515–LGCgE, Lille University, Université d’Artois, 62400 Béthune, FranceE2S UPPA, LaTEP, Pau et des Pays de l’Adour University, 64000 Pau, FrancePolytech’Lab, Côte d’Azur University, 06103 Nice, FranceLaboratoire LOCIE, CNRS, Savoie Mont Blanc University, 73000 Chambéry, FranceLaboratoire LOCIE, CNRS, Savoie Mont Blanc University, 73000 Chambéry, FranceThis study presents an experimental comparison of three characterization methods for phase change materials (PCM). Two methods were carried out with a calorimeter, the first with direct scanning (DSC) and the second with step scanning (STEP). The third method is a fluxmetric (FM) characterization performed using a fluxmeter bench. For the three methods, paraffin RT58 and polymer PEG6000, two PCM suitable for domestic hot water (DHW) storage, were characterized. For each PCM, no significant difference was observed on the latent heat and the total energy exchanged between the three characterization methods. However, DSC and STEP methods did not enable the accurate characterization of the supercooling process observed with the FM method for polymer PEG6000. For PEG6000, the shape of the enthalpy curve of melting also differed between the experiments on the calorimeter—DSC and STEP—methods, and the FM method. Concerning the PCM comparison, RT58 and PEG6000 appeared to have an equivalent energy density but, as the mass density of PEG6000 is greater, more energy is stored inside the same volume for PEG6000. However, as PEG6000 experienced supercooling, the discharging temperature was lower than for RT58 and the material is therefore less adapted to DHW storage operating with partial phase change cycles where the PCM temperature does not decrease below 52 °C.https://www.mdpi.com/2076-3417/11/21/10229phase change materiallatent heat storagedomestic hot waterexperimental characterizationthermal performances
spellingShingle Maxime Thonon
Laurent Zalewski
Stéphane Gibout
Erwin Franquet
Gilles Fraisse
Mickael Pailha
Experimental Comparison of Three Characterization Methods for Two Phase Change Materials Suitable for Domestic Hot Water Storage
Applied Sciences
phase change material
latent heat storage
domestic hot water
experimental characterization
thermal performances
title Experimental Comparison of Three Characterization Methods for Two Phase Change Materials Suitable for Domestic Hot Water Storage
title_full Experimental Comparison of Three Characterization Methods for Two Phase Change Materials Suitable for Domestic Hot Water Storage
title_fullStr Experimental Comparison of Three Characterization Methods for Two Phase Change Materials Suitable for Domestic Hot Water Storage
title_full_unstemmed Experimental Comparison of Three Characterization Methods for Two Phase Change Materials Suitable for Domestic Hot Water Storage
title_short Experimental Comparison of Three Characterization Methods for Two Phase Change Materials Suitable for Domestic Hot Water Storage
title_sort experimental comparison of three characterization methods for two phase change materials suitable for domestic hot water storage
topic phase change material
latent heat storage
domestic hot water
experimental characterization
thermal performances
url https://www.mdpi.com/2076-3417/11/21/10229
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