Synthesis, Characterization and Performance of Cu 2 for Solar Cell Application SnSe 3
Cu2SnSe3 (CTSe) powders were prepared by solvothermal (SR) and solid state reactions (SSR) using low cost starting materials. The crystal structure, morphology, UV-Vis absorbance, electrochemical and solar energy properties were investigated using X-ray Diffraction (XRD), Field Emission Scanning Ele...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
Academy Publishing Center
2017-12-01
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Series: | Renewable Energy and Sustainable Development |
Subjects: | |
Online Access: | http://apc.aast.edu/ojs/index.php/RESD/article/view/03.3.244 |
Summary: | Cu2SnSe3 (CTSe) powders were prepared by solvothermal (SR) and solid state reactions (SSR) using low cost starting materials. The crystal structure, morphology, UV-Vis absorbance, electrochemical and solar energy properties were investigated using X-ray Diffraction (XRD), Field Emission Scanning Electron
Microscopy (FESEM), Electrochemical Impedance Spectroscopy (EIS) and solar energy applications using I-V characteristics measurements. A single cubic Cu2SnSe3 was obtained for the two methods of preparations. The calculated crystallite size (L) values for CTSe prepared by SR and SSR are 24.1 and 30.3 nm, respectively. UV-Vis. spectra for SR and SSR preparations showed maximum absorbencies at 240 nm with band gap (Eg) values of 0.9 and 1.4 eV, respectively. The charge transfer resistances (Rct) were equal to 3.5 and 24 for photoelectrochemical cells (PEC) and the calculated conductivities were equal to 3x10-2 and 2x10-2 S.cm for samples that prepared by SR and SSR methods, respectively. A good photoelectrochemical cell (PCE) has accomplished power conversion efficiency per unit area of about 0.84 and 0.64 % for cells prepared by SR and SSR, respectively. |
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ISSN: | 2356-8518 2356-8569 |