Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ2O:O′]bis[(methanol)tris(nitrato-κ2O,O′)terbium(III)]
In the centrosymmetric dinuclear title complex, [Tb2(NO3)6(C10H8N2O2)2(CH3OH)2], the Tb atoms are bridged by the carboxylate groups of the two 4-(1H-imidazol-3-ium-1-yl)benzoate (iba) ligands. The iba ligand adopts a zwitterionic form with a protonated imidazole group. The Tb atom adopts a distorted...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811002443 |
| _version_ | 1818999159994187776 |
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| author | Yeong-Min Jung Soon W. Lee |
| author_facet | Yeong-Min Jung Soon W. Lee |
| author_sort | Yeong-Min Jung |
| collection | DOAJ |
| description | In the centrosymmetric dinuclear title complex, [Tb2(NO3)6(C10H8N2O2)2(CH3OH)2], the Tb atoms are bridged by the carboxylate groups of the two 4-(1H-imidazol-3-ium-1-yl)benzoate (iba) ligands. The iba ligand adopts a zwitterionic form with a protonated imidazole group. The Tb atom adopts a distorted tricapped trigonal–prismatic coordination geometry and is coordinated by six O atoms of three chelating nitrate ions, one O atom of the methanol molecule and two O atoms of two iba ligands. The intramolecular Tb...Tb separation is 5.1419 (3) Å. O—H...O and N—H...O hydrogen bonds connect complex molecules into a two-dimensional network. |
| first_indexed | 2024-12-20T22:13:00Z |
| format | Article |
| id | doaj.art-1214c1ab5fa64f4c9d5ab6bf9804518a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:13:00Z |
| publishDate | 2011-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1214c1ab5fa64f4c9d5ab6bf9804518a2022-12-21T19:25:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672m253m25410.1107/S1600536811002443Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ2O:O′]bis[(methanol)tris(nitrato-κ2O,O′)terbium(III)]Yeong-Min JungSoon W. LeeIn the centrosymmetric dinuclear title complex, [Tb2(NO3)6(C10H8N2O2)2(CH3OH)2], the Tb atoms are bridged by the carboxylate groups of the two 4-(1H-imidazol-3-ium-1-yl)benzoate (iba) ligands. The iba ligand adopts a zwitterionic form with a protonated imidazole group. The Tb atom adopts a distorted tricapped trigonal–prismatic coordination geometry and is coordinated by six O atoms of three chelating nitrate ions, one O atom of the methanol molecule and two O atoms of two iba ligands. The intramolecular Tb...Tb separation is 5.1419 (3) Å. O—H...O and N—H...O hydrogen bonds connect complex molecules into a two-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536811002443 |
| spellingShingle | Yeong-Min Jung Soon W. Lee Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ2O:O′]bis[(methanol)tris(nitrato-κ2O,O′)terbium(III)] Acta Crystallographica Section E |
| title | Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ2O:O′]bis[(methanol)tris(nitrato-κ2O,O′)terbium(III)] |
| title_full | Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ2O:O′]bis[(methanol)tris(nitrato-κ2O,O′)terbium(III)] |
| title_fullStr | Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ2O:O′]bis[(methanol)tris(nitrato-κ2O,O′)terbium(III)] |
| title_full_unstemmed | Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ2O:O′]bis[(methanol)tris(nitrato-κ2O,O′)terbium(III)] |
| title_short | Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ2O:O′]bis[(methanol)tris(nitrato-κ2O,O′)terbium(III)] |
| title_sort | bis amp 956 4 1h imidazol 3 ium 1 yl benzoato amp 954 2o o amp 8242 bis methanol tris nitrato amp 954 2o o amp 8242 terbium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811002443 |
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