Synthesis of novel Fe3O4 nanostructures surrounded by Ti-MOF nanostructures as bioactive and efficient catalysts in three-component synthesis of new pyrazole derivatives
Synthesis and reporting of new nanoparticles with diverse properties is important in chemistry. A one-step, rapid and controllable synthesis of the new Fe3O4 surrounded in Ti-MOF nanostructures was carried out with microwave technology. After identifying and confirming the structure, Fe3O4 surrounde...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2023-06-01
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| Series: | Frontiers in Materials |
| Subjects: | |
| Online Access: | https://www.frontiersin.org/articles/10.3389/fmats.2023.1156702/full |
| _version_ | 1827927695799877632 |
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| author | Balsam Qubais Saeed Ibrahem Waleed Hussein Humedy Chlib Alkaaby Sabrean Farhan Jawad Usama S. Altimari Ziyad Shihab Ahmed AL-Sarraj Ruwaida T. Shbeeb Salema K. Hadrawi Muath Suliman Mohammad Y. Alshahrani |
| author_facet | Balsam Qubais Saeed Ibrahem Waleed Hussein Humedy Chlib Alkaaby Sabrean Farhan Jawad Usama S. Altimari Ziyad Shihab Ahmed AL-Sarraj Ruwaida T. Shbeeb Salema K. Hadrawi Muath Suliman Mohammad Y. Alshahrani |
| author_sort | Balsam Qubais Saeed |
| collection | DOAJ |
| description | Synthesis and reporting of new nanoparticles with diverse properties is important in chemistry. A one-step, rapid and controllable synthesis of the new Fe3O4 surrounded in Ti-MOF nanostructures was carried out with microwave technology. After identifying and confirming the structure, Fe3O4 surrounded in Ti-MOF nanostructures was used as a suitable catalyst with high thermal resistance and recyclable in a three-component reaction of phenylhydrazine, malononitrile and aldehyde to synthesis novel pyrazole derivatives. Continuing investigations on Fe3O4 surrounded in Ti-MOF nanostructures, its antimicrobial properties were tested on Gram-positive bacterial species, Gram-negative bacterial species and fungi bacterial. Identification of Fe3O4 surrounded in Ti-MOF nanostructures with morphology and size distribution technique (SEM), surface area technique (BET), Infrared spectroscopy (FT-IR), Energy-Dispersive X-ray spectroscopy (EDX/EDX mapping), and Vibrating Sample Magnetometer (VSM) were performed. Synthesized pyrazole derivatives with Fe3O4 surrounded in Ti-MOF nanostructures than previously reported methods have less synthesis time and high efficiency. In antimicrobial properties high effects were observed based on MIC, MBC, and MFC values. |
| first_indexed | 2024-03-13T05:56:35Z |
| format | Article |
| id | doaj.art-122f9bc3b47f47b2891e51c0599a1b6b |
| institution | Directory Open Access Journal |
| issn | 2296-8016 |
| language | English |
| last_indexed | 2024-03-13T05:56:35Z |
| publishDate | 2023-06-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Materials |
| spelling | doaj.art-122f9bc3b47f47b2891e51c0599a1b6b2023-06-13T04:29:59ZengFrontiers Media S.A.Frontiers in Materials2296-80162023-06-011010.3389/fmats.2023.11567021156702Synthesis of novel Fe3O4 nanostructures surrounded by Ti-MOF nanostructures as bioactive and efficient catalysts in three-component synthesis of new pyrazole derivativesBalsam Qubais Saeed0Ibrahem Waleed1Hussein Humedy Chlib Alkaaby2Sabrean Farhan Jawad3Usama S. Altimari4Ziyad Shihab Ahmed AL-Sarraj5Ruwaida T. Shbeeb6Salema K. Hadrawi7Muath Suliman8Mohammad Y. Alshahrani9Department of Clinical Sciences, College of Medicine, University of Sharjah, Sharjah, United Arab EmiratesMedical Technical College, Al-Farahidi University, Baghdad, IraqAl-Manara College for Medical Sciences, Maysan, IraqPharmacy Department, Al-Mustaqbal University College, Babylon, IraqDepartment of Medical Engineering, Al-Nisour University College, Baghdad, IraqDepartment of Biomedialc Engineering, Ashur University College, Baghdad, IraqDepartment of Medical Engineering, Al-Hadi University College, Baghdad, IraqRefrigeration and Air-Conditioning Technical Engineering Department, College of Technical Engineering, The Islamic University, Najaf, IraqDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, King Khalid University, Abha, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, King Khalid University, Abha, Saudi ArabiaSynthesis and reporting of new nanoparticles with diverse properties is important in chemistry. A one-step, rapid and controllable synthesis of the new Fe3O4 surrounded in Ti-MOF nanostructures was carried out with microwave technology. After identifying and confirming the structure, Fe3O4 surrounded in Ti-MOF nanostructures was used as a suitable catalyst with high thermal resistance and recyclable in a three-component reaction of phenylhydrazine, malononitrile and aldehyde to synthesis novel pyrazole derivatives. Continuing investigations on Fe3O4 surrounded in Ti-MOF nanostructures, its antimicrobial properties were tested on Gram-positive bacterial species, Gram-negative bacterial species and fungi bacterial. Identification of Fe3O4 surrounded in Ti-MOF nanostructures with morphology and size distribution technique (SEM), surface area technique (BET), Infrared spectroscopy (FT-IR), Energy-Dispersive X-ray spectroscopy (EDX/EDX mapping), and Vibrating Sample Magnetometer (VSM) were performed. Synthesized pyrazole derivatives with Fe3O4 surrounded in Ti-MOF nanostructures than previously reported methods have less synthesis time and high efficiency. In antimicrobial properties high effects were observed based on MIC, MBC, and MFC values.https://www.frontiersin.org/articles/10.3389/fmats.2023.1156702/fullFe3O4/Ti-MOF nanostructuremagnetic nanocatalystpyrazoleGram-positive bacterial speciesGram-negative bacterial species |
| spellingShingle | Balsam Qubais Saeed Ibrahem Waleed Hussein Humedy Chlib Alkaaby Sabrean Farhan Jawad Usama S. Altimari Ziyad Shihab Ahmed AL-Sarraj Ruwaida T. Shbeeb Salema K. Hadrawi Muath Suliman Mohammad Y. Alshahrani Synthesis of novel Fe3O4 nanostructures surrounded by Ti-MOF nanostructures as bioactive and efficient catalysts in three-component synthesis of new pyrazole derivatives Frontiers in Materials Fe3O4/Ti-MOF nanostructure magnetic nanocatalyst pyrazole Gram-positive bacterial species Gram-negative bacterial species |
| title | Synthesis of novel Fe3O4 nanostructures surrounded by Ti-MOF nanostructures as bioactive and efficient catalysts in three-component synthesis of new pyrazole derivatives |
| title_full | Synthesis of novel Fe3O4 nanostructures surrounded by Ti-MOF nanostructures as bioactive and efficient catalysts in three-component synthesis of new pyrazole derivatives |
| title_fullStr | Synthesis of novel Fe3O4 nanostructures surrounded by Ti-MOF nanostructures as bioactive and efficient catalysts in three-component synthesis of new pyrazole derivatives |
| title_full_unstemmed | Synthesis of novel Fe3O4 nanostructures surrounded by Ti-MOF nanostructures as bioactive and efficient catalysts in three-component synthesis of new pyrazole derivatives |
| title_short | Synthesis of novel Fe3O4 nanostructures surrounded by Ti-MOF nanostructures as bioactive and efficient catalysts in three-component synthesis of new pyrazole derivatives |
| title_sort | synthesis of novel fe3o4 nanostructures surrounded by ti mof nanostructures as bioactive and efficient catalysts in three component synthesis of new pyrazole derivatives |
| topic | Fe3O4/Ti-MOF nanostructure magnetic nanocatalyst pyrazole Gram-positive bacterial species Gram-negative bacterial species |
| url | https://www.frontiersin.org/articles/10.3389/fmats.2023.1156702/full |
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