EFFECT OF DIFFERENT SOLVENT ON ASYMMETRIC POLYSULFONE (PSF) MEMBRANES FOR CO2/CH4 SEPARATION

The asymmetric membranes solution were developed for CO2/CH4 separation by mixing polysulfone (PSf) with NMethyl-2-pyrrolidone (NMP). A volatile solvent, Tetrahydrofuran (THF) was introduced into the casting solution by various loading (0 to 75%) to form a high gas separation performance of asymmet...

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Main Authors: N. F. A. Rozuki, M.H. Tajuddin, N. Yusof
Format: Article
Language:English
Published: Zibeline International 2018-01-01
Series:Environment & Ecosystem Science
Subjects:
Online Access:https://environecosystem.com/archives/2ees2018/2ees2018-11-14.pdf
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author N. F. A. Rozuki
M.H. Tajuddin
N. Yusof
author_facet N. F. A. Rozuki
M.H. Tajuddin
N. Yusof
author_sort N. F. A. Rozuki
collection DOAJ
description The asymmetric membranes solution were developed for CO2/CH4 separation by mixing polysulfone (PSf) with NMethyl-2-pyrrolidone (NMP). A volatile solvent, Tetrahydrofuran (THF) was introduced into the casting solution by various loading (0 to 75%) to form a high gas separation performance of asymmetric membranes via dry/wet phase inversion method. The produced membranes were characterized using Scanning Electron Microscopic (SEM), Fourier Transform Infrared Spectroscopy (FTIR) and gas permeability test. SEM images of a membrane with NMP as a solvent has the thickest dense layer while a membrane with THF as a solvent has the thinnest thickness of the membrane. FTIR results indicating the present of sulfur dioxide (SO2) and methyl (CH3) group at wavelength 1170 cm-1 and 2969 cm-1 respectively verifying the use of PSf as a polymer. As for gas permeation test, the used of THF as a solvent shows the highest CO2/CH4 selectivity with the lowest permeability.
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spelling doaj.art-123d9d7c019e4cf388348d0ff96d14382022-12-22T02:12:34ZengZibeline InternationalEnvironment & Ecosystem Science2521-08822521-04832018-01-0122111410.26480/ees.02.2018.11.14EFFECT OF DIFFERENT SOLVENT ON ASYMMETRIC POLYSULFONE (PSF) MEMBRANES FOR CO2/CH4 SEPARATIONN. F. A. Rozuki M.H. TajuddinN. YusofThe asymmetric membranes solution were developed for CO2/CH4 separation by mixing polysulfone (PSf) with NMethyl-2-pyrrolidone (NMP). A volatile solvent, Tetrahydrofuran (THF) was introduced into the casting solution by various loading (0 to 75%) to form a high gas separation performance of asymmetric membranes via dry/wet phase inversion method. The produced membranes were characterized using Scanning Electron Microscopic (SEM), Fourier Transform Infrared Spectroscopy (FTIR) and gas permeability test. SEM images of a membrane with NMP as a solvent has the thickest dense layer while a membrane with THF as a solvent has the thinnest thickness of the membrane. FTIR results indicating the present of sulfur dioxide (SO2) and methyl (CH3) group at wavelength 1170 cm-1 and 2969 cm-1 respectively verifying the use of PSf as a polymer. As for gas permeation test, the used of THF as a solvent shows the highest CO2/CH4 selectivity with the lowest permeability.https://environecosystem.com/archives/2ees2018/2ees2018-11-14.pdfGas separationVolatile solventTetrahydrofuranPolysulfone.
spellingShingle N. F. A. Rozuki
M.H. Tajuddin
N. Yusof
EFFECT OF DIFFERENT SOLVENT ON ASYMMETRIC POLYSULFONE (PSF) MEMBRANES FOR CO2/CH4 SEPARATION
Environment & Ecosystem Science
Gas separation
Volatile solvent
Tetrahydrofuran
Polysulfone.
title EFFECT OF DIFFERENT SOLVENT ON ASYMMETRIC POLYSULFONE (PSF) MEMBRANES FOR CO2/CH4 SEPARATION
title_full EFFECT OF DIFFERENT SOLVENT ON ASYMMETRIC POLYSULFONE (PSF) MEMBRANES FOR CO2/CH4 SEPARATION
title_fullStr EFFECT OF DIFFERENT SOLVENT ON ASYMMETRIC POLYSULFONE (PSF) MEMBRANES FOR CO2/CH4 SEPARATION
title_full_unstemmed EFFECT OF DIFFERENT SOLVENT ON ASYMMETRIC POLYSULFONE (PSF) MEMBRANES FOR CO2/CH4 SEPARATION
title_short EFFECT OF DIFFERENT SOLVENT ON ASYMMETRIC POLYSULFONE (PSF) MEMBRANES FOR CO2/CH4 SEPARATION
title_sort effect of different solvent on asymmetric polysulfone psf membranes for co2 ch4 separation
topic Gas separation
Volatile solvent
Tetrahydrofuran
Polysulfone.
url https://environecosystem.com/archives/2ees2018/2ees2018-11-14.pdf
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