Synthesis of La9.33Si6O26 nano-photocatalysts by ultrasonically accelerated method for comparing water treatment efficiency with changing conditions

Lanthanum silicates nanoparticles with La9.33Si6O26 formula provided through sonochemical procedure in the presence of tetraethylenepentamine. The amine of tetraethylenepentamine plays two roles of alkaline agent and masking agent for controlling the morphology and size in the reaction process. Effe...

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Main Authors: Kamran Mahdavi, Masoud Salavati-Niasari, Omid Amiri, Mojgan Ghanbari
Format: Article
Language:English
Published: Elsevier 2022-01-01
Series:Arabian Journal of Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535221004962
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author Kamran Mahdavi
Masoud Salavati-Niasari
Omid Amiri
Mojgan Ghanbari
author_facet Kamran Mahdavi
Masoud Salavati-Niasari
Omid Amiri
Mojgan Ghanbari
author_sort Kamran Mahdavi
collection DOAJ
description Lanthanum silicates nanoparticles with La9.33Si6O26 formula provided through sonochemical procedure in the presence of tetraethylenepentamine. The amine of tetraethylenepentamine plays two roles of alkaline agent and masking agent for controlling the morphology and size in the reaction process. Effect of sonication time and applying sonication method (non-stop or pulsed) as important parameters studied on the product characteristics. The obtained ideal sample applied as photocatalyst material for degradation of series of organic dyes. Also, dye concentration, catalyst dosage and pH are operational parameters in water treatment that choose to study in the designed photocatalytic tests. The photocatalytic degradation mechanism inquired to study the scavengers for active agents. Therefore, ideal efficiency (61.70%) obtained in the presence of 0.03 g La9.33 Si6 O26 nano-photocatalysts in 10 ppm acid red 14 in the pH of 11 which proceeds in terms of mechanism with the help of superoxide species.
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spelling doaj.art-123e57886ceb43c190da0872d59bbc182022-12-21T16:58:37ZengElsevierArabian Journal of Chemistry1878-53522022-01-01151103481Synthesis of La9.33Si6O26 nano-photocatalysts by ultrasonically accelerated method for comparing water treatment efficiency with changing conditionsKamran Mahdavi0Masoud Salavati-Niasari1Omid Amiri2Mojgan Ghanbari3Institute of Nano Science and Nano Technology, University of Kashan, Kashan P. O. Box.87317-51167, Islamic Republic of IranInstitute of Nano Science and Nano Technology, University of Kashan, Kashan P. O. Box.87317-51167, Islamic Republic of Iran; Corresponding author.Department of Chemistry, College of Science, University of Raparin, Rania, Kurdistan Region, IraqDepartment of Chemistry, College of Science, University of Raparin, Rania, Kurdistan Region, IraqLanthanum silicates nanoparticles with La9.33Si6O26 formula provided through sonochemical procedure in the presence of tetraethylenepentamine. The amine of tetraethylenepentamine plays two roles of alkaline agent and masking agent for controlling the morphology and size in the reaction process. Effect of sonication time and applying sonication method (non-stop or pulsed) as important parameters studied on the product characteristics. The obtained ideal sample applied as photocatalyst material for degradation of series of organic dyes. Also, dye concentration, catalyst dosage and pH are operational parameters in water treatment that choose to study in the designed photocatalytic tests. The photocatalytic degradation mechanism inquired to study the scavengers for active agents. Therefore, ideal efficiency (61.70%) obtained in the presence of 0.03 g La9.33 Si6 O26 nano-photocatalysts in 10 ppm acid red 14 in the pH of 11 which proceeds in terms of mechanism with the help of superoxide species.http://www.sciencedirect.com/science/article/pii/S1878535221004962ApatiteUltrasonicPhotocatalystNanoparticlesLa9.33Si6O26
spellingShingle Kamran Mahdavi
Masoud Salavati-Niasari
Omid Amiri
Mojgan Ghanbari
Synthesis of La9.33Si6O26 nano-photocatalysts by ultrasonically accelerated method for comparing water treatment efficiency with changing conditions
Arabian Journal of Chemistry
Apatite
Ultrasonic
Photocatalyst
Nanoparticles
La9.33Si6O26
title Synthesis of La9.33Si6O26 nano-photocatalysts by ultrasonically accelerated method for comparing water treatment efficiency with changing conditions
title_full Synthesis of La9.33Si6O26 nano-photocatalysts by ultrasonically accelerated method for comparing water treatment efficiency with changing conditions
title_fullStr Synthesis of La9.33Si6O26 nano-photocatalysts by ultrasonically accelerated method for comparing water treatment efficiency with changing conditions
title_full_unstemmed Synthesis of La9.33Si6O26 nano-photocatalysts by ultrasonically accelerated method for comparing water treatment efficiency with changing conditions
title_short Synthesis of La9.33Si6O26 nano-photocatalysts by ultrasonically accelerated method for comparing water treatment efficiency with changing conditions
title_sort synthesis of la9 33si6o26 nano photocatalysts by ultrasonically accelerated method for comparing water treatment efficiency with changing conditions
topic Apatite
Ultrasonic
Photocatalyst
Nanoparticles
La9.33Si6O26
url http://www.sciencedirect.com/science/article/pii/S1878535221004962
work_keys_str_mv AT kamranmahdavi synthesisofla933si6o26nanophotocatalystsbyultrasonicallyacceleratedmethodforcomparingwatertreatmentefficiencywithchangingconditions
AT masoudsalavatiniasari synthesisofla933si6o26nanophotocatalystsbyultrasonicallyacceleratedmethodforcomparingwatertreatmentefficiencywithchangingconditions
AT omidamiri synthesisofla933si6o26nanophotocatalystsbyultrasonicallyacceleratedmethodforcomparingwatertreatmentefficiencywithchangingconditions
AT mojganghanbari synthesisofla933si6o26nanophotocatalystsbyultrasonicallyacceleratedmethodforcomparingwatertreatmentefficiencywithchangingconditions