1-{[(Cyclohexyloxy)carbonyl]oxy}ethyl 3-{[2′-(2-ethyl-2H-tetrazol-5-yl)biphenyl-4-yl]methyl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate
In the title compound, C33H34N6O6, the dihydrobenzimidazol-2-one ring system is essentially planar (r.m.s. deviation = 0.021 Å). The cyclohexane ring adopts a chair conformation. In the 5-(biphenyl-2-yl)-2H-tetrazole fragment, the tetrazole ring is twisted away from the at...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-04-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810011049 |
| _version_ | 1831602445230276608 |
|---|---|
| author | A. Mohan P. Ramesh D. Saravanan M. N. Ponnuswamy |
| author_facet | A. Mohan P. Ramesh D. Saravanan M. N. Ponnuswamy |
| author_sort | A. Mohan |
| collection | DOAJ |
| description | In the title compound, C33H34N6O6, the dihydrobenzimidazol-2-one ring system is essentially planar (r.m.s. deviation = 0.021 Å). The cyclohexane ring adopts a chair conformation. In the 5-(biphenyl-2-yl)-2H-tetrazole fragment, the tetrazole ring is twisted away from the attached benzene ring by 35.73 (11)° and the two benzene rings form a dihedral angle of 68.00 (9)°. An intramolecular C—H...O interaction is observed. In the crystal, the molecules are linked into a zigzag chain running along the b axis by intermolecular N—H...O hydrogen bonds. |
| first_indexed | 2024-12-18T15:21:08Z |
| format | Article |
| id | doaj.art-12404d4550864792930c1b3b924e9b99 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:21:08Z |
| publishDate | 2010-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-12404d4550864792930c1b3b924e9b992022-12-21T21:03:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664o998o99810.1107/S16005368100110491-{[(Cyclohexyloxy)carbonyl]oxy}ethyl 3-{[2′-(2-ethyl-2H-tetrazol-5-yl)biphenyl-4-yl]methyl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylateA. MohanP. RameshD. SaravananM. N. PonnuswamyIn the title compound, C33H34N6O6, the dihydrobenzimidazol-2-one ring system is essentially planar (r.m.s. deviation = 0.021 Å). The cyclohexane ring adopts a chair conformation. In the 5-(biphenyl-2-yl)-2H-tetrazole fragment, the tetrazole ring is twisted away from the attached benzene ring by 35.73 (11)° and the two benzene rings form a dihedral angle of 68.00 (9)°. An intramolecular C—H...O interaction is observed. In the crystal, the molecules are linked into a zigzag chain running along the b axis by intermolecular N—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536810011049 |
| spellingShingle | A. Mohan P. Ramesh D. Saravanan M. N. Ponnuswamy 1-{[(Cyclohexyloxy)carbonyl]oxy}ethyl 3-{[2′-(2-ethyl-2H-tetrazol-5-yl)biphenyl-4-yl]methyl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate Acta Crystallographica Section E |
| title | 1-{[(Cyclohexyloxy)carbonyl]oxy}ethyl 3-{[2′-(2-ethyl-2H-tetrazol-5-yl)biphenyl-4-yl]methyl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate |
| title_full | 1-{[(Cyclohexyloxy)carbonyl]oxy}ethyl 3-{[2′-(2-ethyl-2H-tetrazol-5-yl)biphenyl-4-yl]methyl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate |
| title_fullStr | 1-{[(Cyclohexyloxy)carbonyl]oxy}ethyl 3-{[2′-(2-ethyl-2H-tetrazol-5-yl)biphenyl-4-yl]methyl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate |
| title_full_unstemmed | 1-{[(Cyclohexyloxy)carbonyl]oxy}ethyl 3-{[2′-(2-ethyl-2H-tetrazol-5-yl)biphenyl-4-yl]methyl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate |
| title_short | 1-{[(Cyclohexyloxy)carbonyl]oxy}ethyl 3-{[2′-(2-ethyl-2H-tetrazol-5-yl)biphenyl-4-yl]methyl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate |
| title_sort | 1 cyclohexyloxy carbonyl oxy ethyl 3 2 amp 8242 2 ethyl 2h tetrazol 5 yl biphenyl 4 yl methyl 2 oxo 2 3 dihydro 1h benzimidazole 4 carboxylate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810011049 |
| work_keys_str_mv | AT amohan 1cyclohexyloxycarbonyloxyethyl32amp82422ethyl2htetrazol5ylbiphenyl4ylmethyl2oxo23dihydro1hbenzimidazole4carboxylate AT pramesh 1cyclohexyloxycarbonyloxyethyl32amp82422ethyl2htetrazol5ylbiphenyl4ylmethyl2oxo23dihydro1hbenzimidazole4carboxylate AT dsaravanan 1cyclohexyloxycarbonyloxyethyl32amp82422ethyl2htetrazol5ylbiphenyl4ylmethyl2oxo23dihydro1hbenzimidazole4carboxylate AT mnponnuswamy 1cyclohexyloxycarbonyloxyethyl32amp82422ethyl2htetrazol5ylbiphenyl4ylmethyl2oxo23dihydro1hbenzimidazole4carboxylate |