Mixed-Ligand Complexes of Co(II), Ni(II) And Cu(II) with Mercaptosuccinic Acid And 1, 10-Phenanthroline in Dimethylformamide Media
The ternary systems of Co(II), Ni(II) and Cu(II) complexes with Mercaptosuccinic acid as Primary Ligand and 1, 10-Phenanthroline as Secondary Ligand are investigated. The stability constants of the complexes were determined pH metrically in Dimethylformamide medium at 303K and I = 0.16 mol/L NaCl. T...
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| Format: | Article |
| Language: | English |
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PURKH
2019-12-01
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| Series: | To Chemistry Journal |
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| Online Access: | https://purkh.com/index.php/tochem/article/view/585 |
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| author | Tejeswara Rao Voonna Pushpa Raju Gali Lakshmi Kishore Pilli Nageswara Rao Gollapalli |
| author_facet | Tejeswara Rao Voonna Pushpa Raju Gali Lakshmi Kishore Pilli Nageswara Rao Gollapalli |
| author_sort | Tejeswara Rao Voonna |
| collection | DOAJ |
| description | The ternary systems of Co(II), Ni(II) and Cu(II) complexes with Mercaptosuccinic acid as Primary Ligand and 1, 10-Phenanthroline as Secondary Ligand are investigated. The stability constants of the complexes were determined pH metrically in Dimethylformamide medium at 303K and I = 0.16 mol/L NaCl. The predominant species detected are MLX, ML2X, MLXH and MLX2H. Models containing different numbers of species were refined by using the computer program MINIQUAD75. The best-fit chemical models were arrived at based on statistical parameters. The relative stabilities of the ternary complexes and species distributions of all complexes in solution were evaluated. |
| first_indexed | 2024-12-10T13:09:34Z |
| format | Article |
| id | doaj.art-1241159c110c47479023f6365d586c0e |
| institution | Directory Open Access Journal |
| issn | 2581-7507 |
| language | English |
| last_indexed | 2024-12-10T13:09:34Z |
| publishDate | 2019-12-01 |
| publisher | PURKH |
| record_format | Article |
| series | To Chemistry Journal |
| spelling | doaj.art-1241159c110c47479023f6365d586c0e2022-12-22T01:47:43ZengPURKHTo Chemistry Journal2581-75072019-12-014585Mixed-Ligand Complexes of Co(II), Ni(II) And Cu(II) with Mercaptosuccinic Acid And 1, 10-Phenanthroline in Dimethylformamide MediaTejeswara Rao Voonna0Pushpa Raju Gali1Lakshmi Kishore Pilli2Nageswara Rao Gollapalli3Andhra UniversityC.R CollegeMVR PG collegeAndhra UniversityThe ternary systems of Co(II), Ni(II) and Cu(II) complexes with Mercaptosuccinic acid as Primary Ligand and 1, 10-Phenanthroline as Secondary Ligand are investigated. The stability constants of the complexes were determined pH metrically in Dimethylformamide medium at 303K and I = 0.16 mol/L NaCl. The predominant species detected are MLX, ML2X, MLXH and MLX2H. Models containing different numbers of species were refined by using the computer program MINIQUAD75. The best-fit chemical models were arrived at based on statistical parameters. The relative stabilities of the ternary complexes and species distributions of all complexes in solution were evaluated.https://purkh.com/index.php/tochem/article/view/585Mixed-LigandMSAPhenPh Metric StudiesStability Constants |
| spellingShingle | Tejeswara Rao Voonna Pushpa Raju Gali Lakshmi Kishore Pilli Nageswara Rao Gollapalli Mixed-Ligand Complexes of Co(II), Ni(II) And Cu(II) with Mercaptosuccinic Acid And 1, 10-Phenanthroline in Dimethylformamide Media To Chemistry Journal Mixed-Ligand MSA Phen Ph Metric Studies Stability Constants |
| title | Mixed-Ligand Complexes of Co(II), Ni(II) And Cu(II) with Mercaptosuccinic Acid And 1, 10-Phenanthroline in Dimethylformamide Media |
| title_full | Mixed-Ligand Complexes of Co(II), Ni(II) And Cu(II) with Mercaptosuccinic Acid And 1, 10-Phenanthroline in Dimethylformamide Media |
| title_fullStr | Mixed-Ligand Complexes of Co(II), Ni(II) And Cu(II) with Mercaptosuccinic Acid And 1, 10-Phenanthroline in Dimethylformamide Media |
| title_full_unstemmed | Mixed-Ligand Complexes of Co(II), Ni(II) And Cu(II) with Mercaptosuccinic Acid And 1, 10-Phenanthroline in Dimethylformamide Media |
| title_short | Mixed-Ligand Complexes of Co(II), Ni(II) And Cu(II) with Mercaptosuccinic Acid And 1, 10-Phenanthroline in Dimethylformamide Media |
| title_sort | mixed ligand complexes of co ii ni ii and cu ii with mercaptosuccinic acid and 1 10 phenanthroline in dimethylformamide media |
| topic | Mixed-Ligand MSA Phen Ph Metric Studies Stability Constants |
| url | https://purkh.com/index.php/tochem/article/view/585 |
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