Fixed bed adsorption of chromium and the Weibull function

Fixed bed adsorption of toxic metal ions such as chromium is a research area of current interest. Mathematical models are routinely used to summarize breakthrough results of metal ions, which often display varying degrees of curve asymmetry. This work introduces the Weibull function as a simple mode...

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Main Author: Khim Hoong Chu
Format: Article
Language:English
Published: Elsevier 2021-11-01
Series:Journal of Hazardous Materials Letters
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666911021000101
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author Khim Hoong Chu
author_facet Khim Hoong Chu
author_sort Khim Hoong Chu
collection DOAJ
description Fixed bed adsorption of toxic metal ions such as chromium is a research area of current interest. Mathematical models are routinely used to summarize breakthrough results of metal ions, which often display varying degrees of curve asymmetry. This work introduces the Weibull function as a simple model for correlating asymmetric breakthrough curves of chromium. The Weibull function is similar to the widely used Bohart-Adams model in several aspects. For example, they both produce sigmoid or S-shaped curves. Their simple mathematical forms can be linearized and linear regression can then be used to estimate their parameters. However, the Weibull function, unlike the Bohart-Adams model, can track the trajectory of asymmetric breakthrough data. Applying the Weibull function to published breakthrough data of chromium, this article illustrates its outright superiority versus the Bohart-Adams model in representing highly asymmetric data. Both equations provide satisfactory fits to breakthrough data exhibiting a moderate degree of curve asymmetry.
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spelling doaj.art-124173357b6c4c77924d8d88557e917a2022-12-21T19:33:57ZengElsevierJournal of Hazardous Materials Letters2666-91102021-11-012100022Fixed bed adsorption of chromium and the Weibull functionKhim Hoong Chu0Honeychem Research, Auckland 1142, New ZealandFixed bed adsorption of toxic metal ions such as chromium is a research area of current interest. Mathematical models are routinely used to summarize breakthrough results of metal ions, which often display varying degrees of curve asymmetry. This work introduces the Weibull function as a simple model for correlating asymmetric breakthrough curves of chromium. The Weibull function is similar to the widely used Bohart-Adams model in several aspects. For example, they both produce sigmoid or S-shaped curves. Their simple mathematical forms can be linearized and linear regression can then be used to estimate their parameters. However, the Weibull function, unlike the Bohart-Adams model, can track the trajectory of asymmetric breakthrough data. Applying the Weibull function to published breakthrough data of chromium, this article illustrates its outright superiority versus the Bohart-Adams model in representing highly asymmetric data. Both equations provide satisfactory fits to breakthrough data exhibiting a moderate degree of curve asymmetry.http://www.sciencedirect.com/science/article/pii/S2666911021000101Asymmetric breakthrough curveBohart-AdamsFixed bed adsorptionProbability distributionWeibull function
spellingShingle Khim Hoong Chu
Fixed bed adsorption of chromium and the Weibull function
Journal of Hazardous Materials Letters
Asymmetric breakthrough curve
Bohart-Adams
Fixed bed adsorption
Probability distribution
Weibull function
title Fixed bed adsorption of chromium and the Weibull function
title_full Fixed bed adsorption of chromium and the Weibull function
title_fullStr Fixed bed adsorption of chromium and the Weibull function
title_full_unstemmed Fixed bed adsorption of chromium and the Weibull function
title_short Fixed bed adsorption of chromium and the Weibull function
title_sort fixed bed adsorption of chromium and the weibull function
topic Asymmetric breakthrough curve
Bohart-Adams
Fixed bed adsorption
Probability distribution
Weibull function
url http://www.sciencedirect.com/science/article/pii/S2666911021000101
work_keys_str_mv AT khimhoongchu fixedbedadsorptionofchromiumandtheweibullfunction