Mechanical Aging Test and Sealing Performance of Thermoplastic Vulcanizate as Sealing Gasket in Automotive Fuel Cell Applications

Ethylene–propylene–diene monomer (EPDM) rubber is one of the rapidly developing synthetic rubbers for use as a gasket material in proton exchange membrane (PEM) fuel cell applications. Despite its excellent elastic and sealing properties, EPDM faces challenges such as molding processability and recy...

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Main Authors: Hyungu Im, Sunkyoung Jeoung
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/8/1872
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author Hyungu Im
Sunkyoung Jeoung
author_facet Hyungu Im
Sunkyoung Jeoung
author_sort Hyungu Im
collection DOAJ
description Ethylene–propylene–diene monomer (EPDM) rubber is one of the rapidly developing synthetic rubbers for use as a gasket material in proton exchange membrane (PEM) fuel cell applications. Despite its excellent elastic and sealing properties, EPDM faces challenges such as molding processability and recycling ability. To overcome these challenges, thermoplastic vulcanizate (TPV), which comprises vulcanized EPDM in polypropylene matrix, was investigated as a gasket material for PEM fuel cell applications. TPV showed better long-term stability in terms of tension and compression set behaviors under accelerated aging conditions than EPDM. Additionally, TPV exhibited significantly higher crosslinking density and surface hardness than EPDM, regardless of the test temperature and aging time. TPV and EPDM showed similar leakage rates for the entire range of test inlet pressure values, regardless of the applied temperature. Therefore, we can conclude that TPV exhibits a similar sealing capability with more stable mechanical properties compared with commercialized EPDM gaskets in terms of He leakage performance.
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spelling doaj.art-1243cdbc4a62462a8a20f3a6182b8b732023-11-17T21:01:47ZengMDPI AGPolymers2073-43602023-04-01158187210.3390/polym15081872Mechanical Aging Test and Sealing Performance of Thermoplastic Vulcanizate as Sealing Gasket in Automotive Fuel Cell ApplicationsHyungu Im0Sunkyoung Jeoung1Material Technology R&D Division, Korea Automotive Technology Institute, Cheonan-si 31214, Republic of KoreaMaterial Technology R&D Division, Korea Automotive Technology Institute, Cheonan-si 31214, Republic of KoreaEthylene–propylene–diene monomer (EPDM) rubber is one of the rapidly developing synthetic rubbers for use as a gasket material in proton exchange membrane (PEM) fuel cell applications. Despite its excellent elastic and sealing properties, EPDM faces challenges such as molding processability and recycling ability. To overcome these challenges, thermoplastic vulcanizate (TPV), which comprises vulcanized EPDM in polypropylene matrix, was investigated as a gasket material for PEM fuel cell applications. TPV showed better long-term stability in terms of tension and compression set behaviors under accelerated aging conditions than EPDM. Additionally, TPV exhibited significantly higher crosslinking density and surface hardness than EPDM, regardless of the test temperature and aging time. TPV and EPDM showed similar leakage rates for the entire range of test inlet pressure values, regardless of the applied temperature. Therefore, we can conclude that TPV exhibits a similar sealing capability with more stable mechanical properties compared with commercialized EPDM gaskets in terms of He leakage performance.https://www.mdpi.com/2073-4360/15/8/1872mechanical ageingsealing performancefuel cellthermoplastic vulcanizateEPDM/TPV
spellingShingle Hyungu Im
Sunkyoung Jeoung
Mechanical Aging Test and Sealing Performance of Thermoplastic Vulcanizate as Sealing Gasket in Automotive Fuel Cell Applications
Polymers
mechanical ageing
sealing performance
fuel cell
thermoplastic vulcanizate
EPDM/TPV
title Mechanical Aging Test and Sealing Performance of Thermoplastic Vulcanizate as Sealing Gasket in Automotive Fuel Cell Applications
title_full Mechanical Aging Test and Sealing Performance of Thermoplastic Vulcanizate as Sealing Gasket in Automotive Fuel Cell Applications
title_fullStr Mechanical Aging Test and Sealing Performance of Thermoplastic Vulcanizate as Sealing Gasket in Automotive Fuel Cell Applications
title_full_unstemmed Mechanical Aging Test and Sealing Performance of Thermoplastic Vulcanizate as Sealing Gasket in Automotive Fuel Cell Applications
title_short Mechanical Aging Test and Sealing Performance of Thermoplastic Vulcanizate as Sealing Gasket in Automotive Fuel Cell Applications
title_sort mechanical aging test and sealing performance of thermoplastic vulcanizate as sealing gasket in automotive fuel cell applications
topic mechanical ageing
sealing performance
fuel cell
thermoplastic vulcanizate
EPDM/TPV
url https://www.mdpi.com/2073-4360/15/8/1872
work_keys_str_mv AT hyunguim mechanicalagingtestandsealingperformanceofthermoplasticvulcanizateassealinggasketinautomotivefuelcellapplications
AT sunkyoungjeoung mechanicalagingtestandsealingperformanceofthermoplasticvulcanizateassealinggasketinautomotivefuelcellapplications