Coordination-induced O-H/N-H bond weakening by a redox non-innocent, aluminum-containing radical

Abstract Several renewable energy schemes aim to use the chemical bonds in abundant molecules like water and ammonia as energy reservoirs. Because the O-H and N-H bonds are quite strong (>100 kcal/mol), it is necessary to identify substances that dramatically weaken these bonds to facilitate prot...

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Bibliographic Details
Main Authors: Soumen Sinhababu, Roushan Prakash Singh, Maxim R. Radzhabov, Jugal Kumawat, Daniel H. Ess, Neal P. Mankad
Format: Article
Language:English
Published: Nature Portfolio 2024-02-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-024-45721-1