Polymerization of Hexene-1 and Propylene over Supported Titanium–Magnesium Catalyst: Comparative Data on the Polymerization Kinetics and Molecular Weight Characteristics of Polymers
Data are presented on the great differences of the kinetics of hexene-1 and propylene polymerization over the same supported titanium–magnesium catalyst, as well as molecular weight and molecular weight distribution of the polymers produced. It is found that the composition of cocatalysts (AlEt<s...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-12-01
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| Series: | Polymers |
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| Online Access: | https://www.mdpi.com/2073-4360/15/1/87 |
| _version_ | 1797406480205348864 |
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| author | Mikhail Matsko Ludmila Echevskaya Vladimir Zakharov |
| author_facet | Mikhail Matsko Ludmila Echevskaya Vladimir Zakharov |
| author_sort | Mikhail Matsko |
| collection | DOAJ |
| description | Data are presented on the great differences of the kinetics of hexene-1 and propylene polymerization over the same supported titanium–magnesium catalyst, as well as molecular weight and molecular weight distribution of the polymers produced. It is found that the composition of cocatalysts (AlEt<sub>3</sub> or Al(i-Bu)<sub>3</sub> greatly affects the kinetics of hexene-1 polymerization and molecular weight distribution of polyhexene, contrary to data obtained at propylene polymerization. The presence of hydrogen at hexene-1 polymerization leads to a much higher increase of activity in comparison with propylene polymerization. Possible reasons for these differences are discussed on the basis of experimental results. |
| first_indexed | 2024-03-09T03:26:05Z |
| format | Article |
| id | doaj.art-12695c0c9fb448a2b95e46aded9cb8d7 |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-09T03:26:05Z |
| publishDate | 2022-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-12695c0c9fb448a2b95e46aded9cb8d72023-12-03T15:01:20ZengMDPI AGPolymers2073-43602022-12-011518710.3390/polym15010087Polymerization of Hexene-1 and Propylene over Supported Titanium–Magnesium Catalyst: Comparative Data on the Polymerization Kinetics and Molecular Weight Characteristics of PolymersMikhail Matsko0Ludmila Echevskaya1Vladimir Zakharov2Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, RussiaBoreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, RussiaBoreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, RussiaData are presented on the great differences of the kinetics of hexene-1 and propylene polymerization over the same supported titanium–magnesium catalyst, as well as molecular weight and molecular weight distribution of the polymers produced. It is found that the composition of cocatalysts (AlEt<sub>3</sub> or Al(i-Bu)<sub>3</sub> greatly affects the kinetics of hexene-1 polymerization and molecular weight distribution of polyhexene, contrary to data obtained at propylene polymerization. The presence of hydrogen at hexene-1 polymerization leads to a much higher increase of activity in comparison with propylene polymerization. Possible reasons for these differences are discussed on the basis of experimental results.https://www.mdpi.com/2073-4360/15/1/87hexene-1 polymerizationpropylene polymerizationtitanium-magnesium catalystmolecular weightmolecular weight distribution polyhexenepolypropylene |
| spellingShingle | Mikhail Matsko Ludmila Echevskaya Vladimir Zakharov Polymerization of Hexene-1 and Propylene over Supported Titanium–Magnesium Catalyst: Comparative Data on the Polymerization Kinetics and Molecular Weight Characteristics of Polymers Polymers hexene-1 polymerization propylene polymerization titanium-magnesium catalyst molecular weight molecular weight distribution polyhexene polypropylene |
| title | Polymerization of Hexene-1 and Propylene over Supported Titanium–Magnesium Catalyst: Comparative Data on the Polymerization Kinetics and Molecular Weight Characteristics of Polymers |
| title_full | Polymerization of Hexene-1 and Propylene over Supported Titanium–Magnesium Catalyst: Comparative Data on the Polymerization Kinetics and Molecular Weight Characteristics of Polymers |
| title_fullStr | Polymerization of Hexene-1 and Propylene over Supported Titanium–Magnesium Catalyst: Comparative Data on the Polymerization Kinetics and Molecular Weight Characteristics of Polymers |
| title_full_unstemmed | Polymerization of Hexene-1 and Propylene over Supported Titanium–Magnesium Catalyst: Comparative Data on the Polymerization Kinetics and Molecular Weight Characteristics of Polymers |
| title_short | Polymerization of Hexene-1 and Propylene over Supported Titanium–Magnesium Catalyst: Comparative Data on the Polymerization Kinetics and Molecular Weight Characteristics of Polymers |
| title_sort | polymerization of hexene 1 and propylene over supported titanium magnesium catalyst comparative data on the polymerization kinetics and molecular weight characteristics of polymers |
| topic | hexene-1 polymerization propylene polymerization titanium-magnesium catalyst molecular weight molecular weight distribution polyhexene polypropylene |
| url | https://www.mdpi.com/2073-4360/15/1/87 |
| work_keys_str_mv | AT mikhailmatsko polymerizationofhexene1andpropyleneoversupportedtitaniummagnesiumcatalystcomparativedataonthepolymerizationkineticsandmolecularweightcharacteristicsofpolymers AT ludmilaechevskaya polymerizationofhexene1andpropyleneoversupportedtitaniummagnesiumcatalystcomparativedataonthepolymerizationkineticsandmolecularweightcharacteristicsofpolymers AT vladimirzakharov polymerizationofhexene1andpropyleneoversupportedtitaniummagnesiumcatalystcomparativedataonthepolymerizationkineticsandmolecularweightcharacteristicsofpolymers |