Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II)
In the neutral title complex, [HgCl2(C12H11NO3)], the HgII ion is pentacoordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yloxy)acetate ligand. The coordination around the HgII ion may be described as highly distorted trigonal–bipy...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2012-07-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812026591 |
_version_ | 1818286022725730304 |
---|---|
author | Yu-Hong Wang Xue-Hua Zhu Rui-Feng Song |
author_facet | Yu-Hong Wang Xue-Hua Zhu Rui-Feng Song |
author_sort | Yu-Hong Wang |
collection | DOAJ |
description | In the neutral title complex, [HgCl2(C12H11NO3)], the HgII ion is pentacoordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yloxy)acetate ligand. The coordination around the HgII ion may be described as highly distorted trigonal–bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg...Cl interaction, leading to a distorted octahedral coordination geometry around the HgII ion. |
first_indexed | 2024-12-13T01:17:59Z |
format | Article |
id | doaj.art-1279aea1e3de45b0b6bdefdb045310d9 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-13T01:17:59Z |
publishDate | 2012-07-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-1279aea1e3de45b0b6bdefdb045310d92022-12-22T00:04:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m951m95110.1107/S1600536812026591Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II)Yu-Hong WangXue-Hua ZhuRui-Feng SongIn the neutral title complex, [HgCl2(C12H11NO3)], the HgII ion is pentacoordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yloxy)acetate ligand. The coordination around the HgII ion may be described as highly distorted trigonal–bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg...Cl interaction, leading to a distorted octahedral coordination geometry around the HgII ion.http://scripts.iucr.org/cgi-bin/paper?S1600536812026591 |
spellingShingle | Yu-Hong Wang Xue-Hua Zhu Rui-Feng Song Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II) Acta Crystallographica Section E |
title | Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II) |
title_full | Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II) |
title_fullStr | Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II) |
title_full_unstemmed | Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II) |
title_short | Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II) |
title_sort | dichlorido methyl 2 quinolin 8 yloxy amp 954 2n o acetate amp 954 o mercury ii |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536812026591 |
work_keys_str_mv | AT yuhongwang dichloridomethyl2quinolin8yloxyamp9542noacetateamp954omercuryii AT xuehuazhu dichloridomethyl2quinolin8yloxyamp9542noacetateamp954omercuryii AT ruifengsong dichloridomethyl2quinolin8yloxyamp9542noacetateamp954omercuryii |