Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II)

In the neutral title complex, [HgCl2(C12H11NO3)], the HgII ion is pentacoordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yloxy)acetate ligand. The coordination around the HgII ion may be described as highly distorted trigonal–bipy...

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Main Authors: Yu-Hong Wang, Xue-Hua Zhu, Rui-Feng Song
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812026591
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author Yu-Hong Wang
Xue-Hua Zhu
Rui-Feng Song
author_facet Yu-Hong Wang
Xue-Hua Zhu
Rui-Feng Song
author_sort Yu-Hong Wang
collection DOAJ
description In the neutral title complex, [HgCl2(C12H11NO3)], the HgII ion is pentacoordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yloxy)acetate ligand. The coordination around the HgII ion may be described as highly distorted trigonal–bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg...Cl interaction, leading to a distorted octahedral coordination geometry around the HgII ion.
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spelling doaj.art-1279aea1e3de45b0b6bdefdb045310d92022-12-22T00:04:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m951m95110.1107/S1600536812026591Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II)Yu-Hong WangXue-Hua ZhuRui-Feng SongIn the neutral title complex, [HgCl2(C12H11NO3)], the HgII ion is pentacoordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yloxy)acetate ligand. The coordination around the HgII ion may be described as highly distorted trigonal–bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg...Cl interaction, leading to a distorted octahedral coordination geometry around the HgII ion.http://scripts.iucr.org/cgi-bin/paper?S1600536812026591
spellingShingle Yu-Hong Wang
Xue-Hua Zhu
Rui-Feng Song
Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II)
Acta Crystallographica Section E
title Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II)
title_full Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II)
title_fullStr Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II)
title_full_unstemmed Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II)
title_short Dichlorido[methyl 2-(quinolin-8-yloxy-κ2N,O)acetate-κO]mercury(II)
title_sort dichlorido methyl 2 quinolin 8 yloxy amp 954 2n o acetate amp 954 o mercury ii
url http://scripts.iucr.org/cgi-bin/paper?S1600536812026591
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AT xuehuazhu dichloridomethyl2quinolin8yloxyamp9542noacetateamp954omercuryii
AT ruifengsong dichloridomethyl2quinolin8yloxyamp9542noacetateamp954omercuryii