Incorporation of europium III complex into nanoparticles and films obtained by the Sol-Gel methodology

The sol-gel process is very effective for the preparation of new materials with potential applications in optics, sensors, catalyst supports, coatings, and specialty inorganic polymers that can be used as hosts for the accommodation of organic molecules. The low temperature employed in the process i...

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Main Authors: Faley Jean de Sousa, Gilberto Pansani Altino de Lima, Lílian Rodrigues Ávila, Katia Jorge Ciuffi, Paulo Sergio Calefi, Eduardo José Nassar
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2010-03-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392010000100015
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author Faley Jean de Sousa
Gilberto Pansani Altino de Lima
Lílian Rodrigues Ávila
Katia Jorge Ciuffi
Paulo Sergio Calefi
Eduardo José Nassar
author_facet Faley Jean de Sousa
Gilberto Pansani Altino de Lima
Lílian Rodrigues Ávila
Katia Jorge Ciuffi
Paulo Sergio Calefi
Eduardo José Nassar
author_sort Faley Jean de Sousa
collection DOAJ
description The sol-gel process is very effective for the preparation of new materials with potential applications in optics, sensors, catalyst supports, coatings, and specialty inorganic polymers that can be used as hosts for the accommodation of organic molecules. The low temperature employed in the process is the main advantage of this methodology. In this work, the europium (III) complex with 1,10-phenantroline was prepared, and this luminescent complex was incorporated into silica nanoparticles and films by the sol-gel process. The nanoparticles were obtained by the modified Stöber methodology. The films were obtained by the dip-coating technique, at different deposition rates and numbers of layers. The nanoparticles and films were characterized by photoluminescence, thermal analysis, and Raman and infrared spectroscopies. Characterization revealed that the europium (III) complex was not affected upon incorporation into the nanoparticles and films, opening a new field for the application of these materials.
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publishDate 2010-03-01
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spelling doaj.art-1298e304b75747d9884a8136cacc94272022-12-21T18:22:16ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392010-03-01131717510.1590/S1516-14392010000100015Incorporation of europium III complex into nanoparticles and films obtained by the Sol-Gel methodologyFaley Jean de SousaGilberto Pansani Altino de LimaLílian Rodrigues ÁvilaKatia Jorge CiuffiPaulo Sergio CalefiEduardo José NassarThe sol-gel process is very effective for the preparation of new materials with potential applications in optics, sensors, catalyst supports, coatings, and specialty inorganic polymers that can be used as hosts for the accommodation of organic molecules. The low temperature employed in the process is the main advantage of this methodology. In this work, the europium (III) complex with 1,10-phenantroline was prepared, and this luminescent complex was incorporated into silica nanoparticles and films by the sol-gel process. The nanoparticles were obtained by the modified Stöber methodology. The films were obtained by the dip-coating technique, at different deposition rates and numbers of layers. The nanoparticles and films were characterized by photoluminescence, thermal analysis, and Raman and infrared spectroscopies. Characterization revealed that the europium (III) complex was not affected upon incorporation into the nanoparticles and films, opening a new field for the application of these materials.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392010000100015photoluminescenceeuropium (III)nanoparticlesfilmsdip-coating
spellingShingle Faley Jean de Sousa
Gilberto Pansani Altino de Lima
Lílian Rodrigues Ávila
Katia Jorge Ciuffi
Paulo Sergio Calefi
Eduardo José Nassar
Incorporation of europium III complex into nanoparticles and films obtained by the Sol-Gel methodology
Materials Research
photoluminescence
europium (III)
nanoparticles
films
dip-coating
title Incorporation of europium III complex into nanoparticles and films obtained by the Sol-Gel methodology
title_full Incorporation of europium III complex into nanoparticles and films obtained by the Sol-Gel methodology
title_fullStr Incorporation of europium III complex into nanoparticles and films obtained by the Sol-Gel methodology
title_full_unstemmed Incorporation of europium III complex into nanoparticles and films obtained by the Sol-Gel methodology
title_short Incorporation of europium III complex into nanoparticles and films obtained by the Sol-Gel methodology
title_sort incorporation of europium iii complex into nanoparticles and films obtained by the sol gel methodology
topic photoluminescence
europium (III)
nanoparticles
films
dip-coating
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392010000100015
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