Thermodynamic Relations among Isotropic Material Properties in Conditions of Plane Shear Stress

We present new general relationships among the material properties of an isotropic material kept in homogeneous stress conditions with hydrostatic pressure and plane shear. The derivation is not limited to the proximity of the zero shear-stress and -strain condition, which allows us to identify the...

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Main Authors: Amilcare Porporato, Salvatore Calabrese, Tomasz Hueckel
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Entropy
Subjects:
Online Access:http://www.mdpi.com/1099-4300/21/3/295
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author Amilcare Porporato
Salvatore Calabrese
Tomasz Hueckel
author_facet Amilcare Porporato
Salvatore Calabrese
Tomasz Hueckel
author_sort Amilcare Porporato
collection DOAJ
description We present new general relationships among the material properties of an isotropic material kept in homogeneous stress conditions with hydrostatic pressure and plane shear. The derivation is not limited to the proximity of the zero shear-stress and -strain condition, which allows us to identify the relationship between adiabatic and isothermal shear compliances (inverse of the moduli of rigidity) along with new links, among others, between isobaric and isochoric shear thermal expansion coefficients and heat capacities at constant stress and constant shear strain. Such relationships are important for a variety of applications, including the determination of constitutive equations, the characterization of nanomaterials, and the identification of properties related to earthquakes precursors and complex media (e.g., soil) behavior. The results may be useful to investigate the behavior of materials during phase transitions involving shear or in non-homogeneous conditions within a local thermodynamic equilibrium framework.
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spelling doaj.art-12b5753b43e04a88ab88584f47162bc32022-12-22T04:01:03ZengMDPI AGEntropy1099-43002019-03-0121329510.3390/e21030295e21030295Thermodynamic Relations among Isotropic Material Properties in Conditions of Plane Shear StressAmilcare Porporato0Salvatore Calabrese1Tomasz Hueckel2Department of Civil and Environmental Engineering and Princeton Environmental Institute, Princeton University, Princeton, NJ 08544, USADepartment of Civil and Environmental Engineering and Princeton Environmental Institute, Princeton University, Princeton, NJ 08544, USADepartment of Civil and Environmental Engineering, Duke University, Durham, NC 27708, USAWe present new general relationships among the material properties of an isotropic material kept in homogeneous stress conditions with hydrostatic pressure and plane shear. The derivation is not limited to the proximity of the zero shear-stress and -strain condition, which allows us to identify the relationship between adiabatic and isothermal shear compliances (inverse of the moduli of rigidity) along with new links, among others, between isobaric and isochoric shear thermal expansion coefficients and heat capacities at constant stress and constant shear strain. Such relationships are important for a variety of applications, including the determination of constitutive equations, the characterization of nanomaterials, and the identification of properties related to earthquakes precursors and complex media (e.g., soil) behavior. The results may be useful to investigate the behavior of materials during phase transitions involving shear or in non-homogeneous conditions within a local thermodynamic equilibrium framework.http://www.mdpi.com/1099-4300/21/3/295material propertiesthermodynamicsthermodynamic transformationsextended Gibbs free energyplane sheardilatancy
spellingShingle Amilcare Porporato
Salvatore Calabrese
Tomasz Hueckel
Thermodynamic Relations among Isotropic Material Properties in Conditions of Plane Shear Stress
Entropy
material properties
thermodynamics
thermodynamic transformations
extended Gibbs free energy
plane shear
dilatancy
title Thermodynamic Relations among Isotropic Material Properties in Conditions of Plane Shear Stress
title_full Thermodynamic Relations among Isotropic Material Properties in Conditions of Plane Shear Stress
title_fullStr Thermodynamic Relations among Isotropic Material Properties in Conditions of Plane Shear Stress
title_full_unstemmed Thermodynamic Relations among Isotropic Material Properties in Conditions of Plane Shear Stress
title_short Thermodynamic Relations among Isotropic Material Properties in Conditions of Plane Shear Stress
title_sort thermodynamic relations among isotropic material properties in conditions of plane shear stress
topic material properties
thermodynamics
thermodynamic transformations
extended Gibbs free energy
plane shear
dilatancy
url http://www.mdpi.com/1099-4300/21/3/295
work_keys_str_mv AT amilcareporporato thermodynamicrelationsamongisotropicmaterialpropertiesinconditionsofplaneshearstress
AT salvatorecalabrese thermodynamicrelationsamongisotropicmaterialpropertiesinconditionsofplaneshearstress
AT tomaszhueckel thermodynamicrelationsamongisotropicmaterialpropertiesinconditionsofplaneshearstress