1D Copper(I) Coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n: Synthesis of Microparticles and Single Crystals, Crystal Structure, and Thermal Study
In this research, 1D four-coordinate copper(I) coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n (1) with thiocyanate anion as bridging ligand, where Clba2-1,2-pn = N,Nʹ-bis(2,4-chlorobenzylidene)propane-1,2-diamine), was synthesized by slow evaporation of solvent at room temperature and characterized b...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2019-06-01
|
| Series: | Iranian Journal of Chemistry & Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.ijcce.ac.ir/article_31729_4a1edb10c7bd1863f3e2b7999588f6d5.pdf |
| Summary: | In this research, 1D four-coordinate copper(I) coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n (1) with thiocyanate anion as bridging ligand, where Clba2-1,2-pn = N,Nʹ-bis(2,4-chlorobenzylidene)propane-1,2-diamine), was synthesized by slow evaporation of solvent at room temperature and characterized by elemental analysis (CHN) and single-crystal X-ray diffraction. Microparticles of 1 were prepared by an ultrasonic bath assisted synthesis and characterized by Scanning Electron Microscopy (SEM) and elemental analysis. Thermal stability of 1 was studied by ThermoGravimetry (TG) and Differential Thermal Analysis (DTA). The structure of 1 consists of 1D polymeric chain in which copper(I) ions are bridged by two thiocyanate groups in an end-to-end fashion, with Cu×××Cu separation 5.686(4) Å. |
|---|---|
| ISSN: | 1021-9986 1021-9986 |