1D Copper(I) Coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n: Synthesis of Microparticles and Single Crystals, Crystal Structure, and Thermal Study
In this research, 1D four-coordinate copper(I) coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n (1) with thiocyanate anion as bridging ligand, where Clba2-1,2-pn = N,Nʹ-bis(2,4-chlorobenzylidene)propane-1,2-diamine), was synthesized by slow evaporation of solvent at room temperature and characterized b...
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2019-06-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
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| Online Access: | http://www.ijcce.ac.ir/article_31729_4a1edb10c7bd1863f3e2b7999588f6d5.pdf |
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| author | Aliakbar Dehno Khalaji Seyyed Javad Peyghoun Ali Reza Akbari Nourollah Feizi MichalMichal Dusek Vaclav Eigner |
| author_facet | Aliakbar Dehno Khalaji Seyyed Javad Peyghoun Ali Reza Akbari Nourollah Feizi MichalMichal Dusek Vaclav Eigner |
| author_sort | Aliakbar Dehno Khalaji |
| collection | DOAJ |
| description | In this research, 1D four-coordinate copper(I) coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n (1) with thiocyanate anion as bridging ligand, where Clba2-1,2-pn = N,Nʹ-bis(2,4-chlorobenzylidene)propane-1,2-diamine), was synthesized by slow evaporation of solvent at room temperature and characterized by elemental analysis (CHN) and single-crystal X-ray diffraction. Microparticles of 1 were prepared by an ultrasonic bath assisted synthesis and characterized by Scanning Electron Microscopy (SEM) and elemental analysis. Thermal stability of 1 was studied by ThermoGravimetry (TG) and Differential Thermal Analysis (DTA). The structure of 1 consists of 1D polymeric chain in which copper(I) ions are bridged by two thiocyanate groups in an end-to-end fashion, with Cu×××Cu separation 5.686(4) Å. |
| first_indexed | 2024-04-14T04:21:33Z |
| format | Article |
| id | doaj.art-12c2de2ded2b4020b1ffdae7d593e538 |
| institution | Directory Open Access Journal |
| issn | 1021-9986 1021-9986 |
| language | English |
| last_indexed | 2024-04-14T04:21:33Z |
| publishDate | 2019-06-01 |
| publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
| record_format | Article |
| series | Iranian Journal of Chemistry & Chemical Engineering |
| spelling | doaj.art-12c2de2ded2b4020b1ffdae7d593e5382022-12-22T02:12:28ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862019-06-01383145150317291D Copper(I) Coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n: Synthesis of Microparticles and Single Crystals, Crystal Structure, and Thermal StudyAliakbar Dehno Khalaji0Seyyed Javad Peyghoun1Ali Reza Akbari2Nourollah Feizi3MichalMichal Dusek4Vaclav Eigner5Department of Chemistry, Faculty of Science, Golestan University, Gorgan, I.R. IRANShahid Beheshti Shining Brilliant Talent High School, Education in Behshahr, Behshahr, I.R. IRANDepartment of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, I.R. IRANDepartment of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, I.R. IRANInstitute of Physic of the Czech Academy of Sciences, Na Slovance 2, 182 21 Prague, CZECH RepublicInstitute of Physic of the Czech Academy of Sciences, Na Slovance 2, 182 21 Prague, CZECH RepublicIn this research, 1D four-coordinate copper(I) coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n (1) with thiocyanate anion as bridging ligand, where Clba2-1,2-pn = N,Nʹ-bis(2,4-chlorobenzylidene)propane-1,2-diamine), was synthesized by slow evaporation of solvent at room temperature and characterized by elemental analysis (CHN) and single-crystal X-ray diffraction. Microparticles of 1 were prepared by an ultrasonic bath assisted synthesis and characterized by Scanning Electron Microscopy (SEM) and elemental analysis. Thermal stability of 1 was studied by ThermoGravimetry (TG) and Differential Thermal Analysis (DTA). The structure of 1 consists of 1D polymeric chain in which copper(I) ions are bridged by two thiocyanate groups in an end-to-end fashion, with Cu×××Cu separation 5.686(4) Å.http://www.ijcce.ac.ir/article_31729_4a1edb10c7bd1863f3e2b7999588f6d5.pdfsingle-crystal x-ray diffractionfour-coordinate1d copper(i) coordination polymermicroparticles |
| spellingShingle | Aliakbar Dehno Khalaji Seyyed Javad Peyghoun Ali Reza Akbari Nourollah Feizi MichalMichal Dusek Vaclav Eigner 1D Copper(I) Coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n: Synthesis of Microparticles and Single Crystals, Crystal Structure, and Thermal Study Iranian Journal of Chemistry & Chemical Engineering single-crystal x-ray diffraction four-coordinate 1d copper(i) coordination polymer microparticles |
| title | 1D Copper(I) Coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n: Synthesis of Microparticles and Single Crystals, Crystal Structure, and Thermal Study |
| title_full | 1D Copper(I) Coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n: Synthesis of Microparticles and Single Crystals, Crystal Structure, and Thermal Study |
| title_fullStr | 1D Copper(I) Coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n: Synthesis of Microparticles and Single Crystals, Crystal Structure, and Thermal Study |
| title_full_unstemmed | 1D Copper(I) Coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n: Synthesis of Microparticles and Single Crystals, Crystal Structure, and Thermal Study |
| title_short | 1D Copper(I) Coordination Polymer [Cu(Clba2-1,2-pn)(NCS)]n: Synthesis of Microparticles and Single Crystals, Crystal Structure, and Thermal Study |
| title_sort | 1d copper i coordination polymer cu clba2 1 2 pn ncs n synthesis of microparticles and single crystals crystal structure and thermal study |
| topic | single-crystal x-ray diffraction four-coordinate 1d copper(i) coordination polymer microparticles |
| url | http://www.ijcce.ac.ir/article_31729_4a1edb10c7bd1863f3e2b7999588f6d5.pdf |
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