fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III)
In the title compound, [Co(C6H4NO2)3], the CoIII ion lies on a threefold rotation axis and is in a distorted octahedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxylate ligands. The ligands are coordinated in a chelate fashion, forming three five-...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011-11-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811043303 |
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author | Irina A. Golenia Alexander N. Boyko Natalia V. Kotova Matti Haukka Valentina A. Kalibabchuk |
author_facet | Irina A. Golenia Alexander N. Boyko Natalia V. Kotova Matti Haukka Valentina A. Kalibabchuk |
author_sort | Irina A. Golenia |
collection | DOAJ |
description | In the title compound, [Co(C6H4NO2)3], the CoIII ion lies on a threefold rotation axis and is in a distorted octahedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxylate ligands. The ligands are coordinated in a chelate fashion, forming three five-membered rings. In the crystal, translationally related complex molecules are organized into columns along [001] via C—H...O hydrogen bonds. |
first_indexed | 2024-12-19T12:04:47Z |
format | Article |
id | doaj.art-13009f9bab1f446f9adbeafb2d3bfc39 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-19T12:04:47Z |
publishDate | 2011-11-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-13009f9bab1f446f9adbeafb2d3bfc392022-12-21T20:22:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711m1596m159710.1107/S1600536811043303fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III)Irina A. GoleniaAlexander N. BoykoNatalia V. KotovaMatti HaukkaValentina A. KalibabchukIn the title compound, [Co(C6H4NO2)3], the CoIII ion lies on a threefold rotation axis and is in a distorted octahedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxylate ligands. The ligands are coordinated in a chelate fashion, forming three five-membered rings. In the crystal, translationally related complex molecules are organized into columns along [001] via C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811043303 |
spellingShingle | Irina A. Golenia Alexander N. Boyko Natalia V. Kotova Matti Haukka Valentina A. Kalibabchuk fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III) Acta Crystallographica Section E |
title | fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III) |
title_full | fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III) |
title_fullStr | fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III) |
title_full_unstemmed | fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III) |
title_short | fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III) |
title_sort | fac tris pyridine 2 carboxylato amp 954 2n o cobalt iii |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536811043303 |
work_keys_str_mv | AT irinaagolenia factrispyridine2carboxylatoamp9542nocobaltiii AT alexandernboyko factrispyridine2carboxylatoamp9542nocobaltiii AT nataliavkotova factrispyridine2carboxylatoamp9542nocobaltiii AT mattihaukka factrispyridine2carboxylatoamp9542nocobaltiii AT valentinaakalibabchuk factrispyridine2carboxylatoamp9542nocobaltiii |