fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III)

In the title compound, [Co(C6H4NO2)3], the CoIII ion lies on a threefold rotation axis and is in a distorted octahedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxylate ligands. The ligands are coordinated in a chelate fashion, forming three five-...

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Main Authors: Irina A. Golenia, Alexander N. Boyko, Natalia V. Kotova, Matti Haukka, Valentina A. Kalibabchuk
Format: Article
Language:English
Published: International Union of Crystallography 2011-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811043303
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author Irina A. Golenia
Alexander N. Boyko
Natalia V. Kotova
Matti Haukka
Valentina A. Kalibabchuk
author_facet Irina A. Golenia
Alexander N. Boyko
Natalia V. Kotova
Matti Haukka
Valentina A. Kalibabchuk
author_sort Irina A. Golenia
collection DOAJ
description In the title compound, [Co(C6H4NO2)3], the CoIII ion lies on a threefold rotation axis and is in a distorted octahedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxylate ligands. The ligands are coordinated in a chelate fashion, forming three five-membered rings. In the crystal, translationally related complex molecules are organized into columns along [001] via C—H...O hydrogen bonds.
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spelling doaj.art-13009f9bab1f446f9adbeafb2d3bfc392022-12-21T20:22:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711m1596m159710.1107/S1600536811043303fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III)Irina A. GoleniaAlexander N. BoykoNatalia V. KotovaMatti HaukkaValentina A. KalibabchukIn the title compound, [Co(C6H4NO2)3], the CoIII ion lies on a threefold rotation axis and is in a distorted octahedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxylate ligands. The ligands are coordinated in a chelate fashion, forming three five-membered rings. In the crystal, translationally related complex molecules are organized into columns along [001] via C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811043303
spellingShingle Irina A. Golenia
Alexander N. Boyko
Natalia V. Kotova
Matti Haukka
Valentina A. Kalibabchuk
fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III)
Acta Crystallographica Section E
title fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III)
title_full fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III)
title_fullStr fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III)
title_full_unstemmed fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III)
title_short fac-Tris(pyridine-2-carboxylato-κ2N,O)cobalt(III)
title_sort fac tris pyridine 2 carboxylato amp 954 2n o cobalt iii
url http://scripts.iucr.org/cgi-bin/paper?S1600536811043303
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AT alexandernboyko factrispyridine2carboxylatoamp9542nocobaltiii
AT nataliavkotova factrispyridine2carboxylatoamp9542nocobaltiii
AT mattihaukka factrispyridine2carboxylatoamp9542nocobaltiii
AT valentinaakalibabchuk factrispyridine2carboxylatoamp9542nocobaltiii