Voltammetry in Determination of Trace Amounts of Lanthanides—A Review
This paper presents an overview of approaches proposed in the scientific literature for the voltammetric determination of rare earth elements (mainly cerium and europium individually, as well as various lanthanides simultaneously) in manifold kinds of samples. The work is divided into chapters descr...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-11-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/28/23/7755 |
| _version_ | 1797399821333561344 |
|---|---|
| author | Malgorzata Grabarczyk Marzena Fialek Edyta Wlazlowska |
| author_facet | Malgorzata Grabarczyk Marzena Fialek Edyta Wlazlowska |
| author_sort | Malgorzata Grabarczyk |
| collection | DOAJ |
| description | This paper presents an overview of approaches proposed in the scientific literature for the voltammetric determination of rare earth elements (mainly cerium and europium individually, as well as various lanthanides simultaneously) in manifold kinds of samples. The work is divided into chapters describing the most important aspects affecting the sensitivity of the proposed methods: the technique adopted (AdSV, ASV, CSV), complexing agents used, the kind of working electrode (mercury-based, noble metal or carbon electrodes) and the most popular electrode modifiers (e.g., metal film, carbon nanotubes, molecularly imprinted polymers). Analytical parameters of the procedures presented in the paper are collected in tables. The subsequent chapters are devoted to a detailed discussion of potential inorganic and organic interfering factors. The possibilities of simultaneous determination of several lanthanides in one sample and the influence of other lanthanides on the determined rare earth element were also discussed. Finally, the applications of the voltammetric procedures to the determination of rare earth metals in real samples with miscellaneous matrix is described. All analytical results were tabulated in order to compare the analytical suitability of the proposed procedures. |
| first_indexed | 2024-03-09T01:45:39Z |
| format | Article |
| id | doaj.art-131dba19ec424993a63a651688d777c2 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T01:45:39Z |
| publishDate | 2023-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-131dba19ec424993a63a651688d777c22023-12-08T15:22:14ZengMDPI AGMolecules1420-30492023-11-012823775510.3390/molecules28237755Voltammetry in Determination of Trace Amounts of Lanthanides—A ReviewMalgorzata Grabarczyk0Marzena Fialek1Edyta Wlazlowska2Department of Analytical Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, 20-031 Lublin, PolandDepartment of Analytical Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, 20-031 Lublin, PolandDepartment of Analytical Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, 20-031 Lublin, PolandThis paper presents an overview of approaches proposed in the scientific literature for the voltammetric determination of rare earth elements (mainly cerium and europium individually, as well as various lanthanides simultaneously) in manifold kinds of samples. The work is divided into chapters describing the most important aspects affecting the sensitivity of the proposed methods: the technique adopted (AdSV, ASV, CSV), complexing agents used, the kind of working electrode (mercury-based, noble metal or carbon electrodes) and the most popular electrode modifiers (e.g., metal film, carbon nanotubes, molecularly imprinted polymers). Analytical parameters of the procedures presented in the paper are collected in tables. The subsequent chapters are devoted to a detailed discussion of potential inorganic and organic interfering factors. The possibilities of simultaneous determination of several lanthanides in one sample and the influence of other lanthanides on the determined rare earth element were also discussed. Finally, the applications of the voltammetric procedures to the determination of rare earth metals in real samples with miscellaneous matrix is described. All analytical results were tabulated in order to compare the analytical suitability of the proposed procedures.https://www.mdpi.com/1420-3049/28/23/7755reviewrare earth elementsstripping voltammetry methodworking electrodecomplexing agentinterferences |
| spellingShingle | Malgorzata Grabarczyk Marzena Fialek Edyta Wlazlowska Voltammetry in Determination of Trace Amounts of Lanthanides—A Review Molecules review rare earth elements stripping voltammetry method working electrode complexing agent interferences |
| title | Voltammetry in Determination of Trace Amounts of Lanthanides—A Review |
| title_full | Voltammetry in Determination of Trace Amounts of Lanthanides—A Review |
| title_fullStr | Voltammetry in Determination of Trace Amounts of Lanthanides—A Review |
| title_full_unstemmed | Voltammetry in Determination of Trace Amounts of Lanthanides—A Review |
| title_short | Voltammetry in Determination of Trace Amounts of Lanthanides—A Review |
| title_sort | voltammetry in determination of trace amounts of lanthanides a review |
| topic | review rare earth elements stripping voltammetry method working electrode complexing agent interferences |
| url | https://www.mdpi.com/1420-3049/28/23/7755 |
| work_keys_str_mv | AT malgorzatagrabarczyk voltammetryindeterminationoftraceamountsoflanthanidesareview AT marzenafialek voltammetryindeterminationoftraceamountsoflanthanidesareview AT edytawlazlowska voltammetryindeterminationoftraceamountsoflanthanidesareview |