Bis[4-(dimethylamino)pyridinium] tetrachloridocuprate(II)
The asymmetric unit of the title salt, (C7H11N2)2[CuCl4], comprises half a tetrahedral tetrachloridocuprate anion, being located on a twofold axis, and a protonated 4-(dimethylamino)pyridine cation. The geometry around the CuII ion is highly distorted with the range of Cl—Cu—Cl a...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813028006 |
| _version_ | 1798018577604804608 |
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| author | Sofiane Bouacida Rafika Bouchene Amina Khadri Ratiba Belhouas Hocine Merazig |
| author_facet | Sofiane Bouacida Rafika Bouchene Amina Khadri Ratiba Belhouas Hocine Merazig |
| author_sort | Sofiane Bouacida |
| collection | DOAJ |
| description | The asymmetric unit of the title salt, (C7H11N2)2[CuCl4], comprises half a tetrahedral tetrachloridocuprate anion, being located on a twofold axis, and a protonated 4-(dimethylamino)pyridine cation. The geometry around the CuII ion is highly distorted with the range of Cl—Cu—Cl angles being 94.94 (1)–141.03 (1)°. The crystal structure is stabilized by N—H...Cl and C—H...Cl hydrogen bonds. In the three-dimensional network, cations and anions pack in the lattice so as to generate chains of [CuCl4]2− anions separated by two orientations of cation layers, which are interlocked through π–π stacking contacts between pairs of pyridine rings, with centroid–centroid distances of 3.7874 (7) Å. |
| first_indexed | 2024-04-11T16:25:13Z |
| format | Article |
| id | doaj.art-1331145c1b0b4f94aea1ebec5205900b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:25:13Z |
| publishDate | 2013-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1331145c1b0b4f94aea1ebec5205900b2022-12-22T04:14:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911m610m61110.1107/S1600536813028006Bis[4-(dimethylamino)pyridinium] tetrachloridocuprate(II)Sofiane BouacidaRafika BoucheneAmina KhadriRatiba BelhouasHocine MerazigThe asymmetric unit of the title salt, (C7H11N2)2[CuCl4], comprises half a tetrahedral tetrachloridocuprate anion, being located on a twofold axis, and a protonated 4-(dimethylamino)pyridine cation. The geometry around the CuII ion is highly distorted with the range of Cl—Cu—Cl angles being 94.94 (1)–141.03 (1)°. The crystal structure is stabilized by N—H...Cl and C—H...Cl hydrogen bonds. In the three-dimensional network, cations and anions pack in the lattice so as to generate chains of [CuCl4]2− anions separated by two orientations of cation layers, which are interlocked through π–π stacking contacts between pairs of pyridine rings, with centroid–centroid distances of 3.7874 (7) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536813028006 |
| spellingShingle | Sofiane Bouacida Rafika Bouchene Amina Khadri Ratiba Belhouas Hocine Merazig Bis[4-(dimethylamino)pyridinium] tetrachloridocuprate(II) Acta Crystallographica Section E |
| title | Bis[4-(dimethylamino)pyridinium] tetrachloridocuprate(II) |
| title_full | Bis[4-(dimethylamino)pyridinium] tetrachloridocuprate(II) |
| title_fullStr | Bis[4-(dimethylamino)pyridinium] tetrachloridocuprate(II) |
| title_full_unstemmed | Bis[4-(dimethylamino)pyridinium] tetrachloridocuprate(II) |
| title_short | Bis[4-(dimethylamino)pyridinium] tetrachloridocuprate(II) |
| title_sort | bis 4 dimethylamino pyridinium tetrachloridocuprate ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813028006 |
| work_keys_str_mv | AT sofianebouacida bis4dimethylaminopyridiniumtetrachloridocuprateii AT rafikabouchene bis4dimethylaminopyridiniumtetrachloridocuprateii AT aminakhadri bis4dimethylaminopyridiniumtetrachloridocuprateii AT ratibabelhouas bis4dimethylaminopyridiniumtetrachloridocuprateii AT hocinemerazig bis4dimethylaminopyridiniumtetrachloridocuprateii |