Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate
The structure of the dinuclear title complex, [Cu2(C10H8N7)2(NO3)2(H2O)2]·2H2O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The CuII ions in the dimer display a distorted octahedral coordination geometry and are bridged by two triazole rings, forming an...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-04-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016003479 |
| _version_ | 1798031651279732736 |
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| author | Roman Doroschuk |
| author_facet | Roman Doroschuk |
| author_sort | Roman Doroschuk |
| collection | DOAJ |
| description | The structure of the dinuclear title complex, [Cu2(C10H8N7)2(NO3)2(H2O)2]·2H2O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The CuII ions in the dimer display a distorted octahedral coordination geometry and are bridged by two triazole rings, forming an approximately planar Cu2N4 core (r.m.s. deviation = 0.049 Å). In the crystal, O—H...O, O—H...N and C—H...O hydrogen bonds and π–π interactions link the molecules into a three-dimensional network. |
| first_indexed | 2024-04-11T19:59:51Z |
| format | Article |
| id | doaj.art-1355976d64aa45848ccc810bbff5e563 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T19:59:51Z |
| publishDate | 2016-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-1355976d64aa45848ccc810bbff5e5632022-12-22T04:05:38ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-04-0172448648810.1107/S2056989016003479rz5185Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrateRoman Doroschuk0Department of Inorganic Chemistry, Taras Shevchenko National University of Kyiv, 64, Volodymyrska Str., 01033, Kyiv, UkraineThe structure of the dinuclear title complex, [Cu2(C10H8N7)2(NO3)2(H2O)2]·2H2O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The CuII ions in the dimer display a distorted octahedral coordination geometry and are bridged by two triazole rings, forming an approximately planar Cu2N4 core (r.m.s. deviation = 0.049 Å). In the crystal, O—H...O, O—H...N and C—H...O hydrogen bonds and π–π interactions link the molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2056989016003479crystal structure1,2,4-triazoledinuclear copper complexhydrogen bonds |
| spellingShingle | Roman Doroschuk Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate Acta Crystallographica Section E: Crystallographic Communications crystal structure 1,2,4-triazole dinuclear copper complex hydrogen bonds |
| title | Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate |
| title_full | Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate |
| title_fullStr | Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate |
| title_full_unstemmed | Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate |
| title_short | Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate |
| title_sort | crystal structure of bis μ2 3 pyridin 2 yl 5 1 2 4 triazol 1 yl methyl 1 2 4 triazolato bis aquanitratocopper ii dihydrate |
| topic | crystal structure 1,2,4-triazole dinuclear copper complex hydrogen bonds |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016003479 |
| work_keys_str_mv | AT romandoroschuk crystalstructureofbism23pyridin2yl5124triazol1ylmethyl124triazolatobisaquanitratocopperiidihydrate |