Metal-Selective Processing from the Los Sulfatos Porphyry-Type Deposit in Chile: Co, Au, and Re Recovery Workflows Based on Advanced Geochemical Characterization

Sulfides extracted from porphyry-type deposits can contain a number of metals critical for the global energy transition, e.g., Co and precious metals such as Au and Re. These metals are currently determined on composite mineral samples, which commonly results in their dilution. Thus, it is possible...

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Main Authors: Germán Velásquez, Humberto Estay, Iván Vela, Stefano Salvi, Marcial Pablo
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/10/6/531
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author Germán Velásquez
Humberto Estay
Iván Vela
Stefano Salvi
Marcial Pablo
author_facet Germán Velásquez
Humberto Estay
Iván Vela
Stefano Salvi
Marcial Pablo
author_sort Germán Velásquez
collection DOAJ
description Sulfides extracted from porphyry-type deposits can contain a number of metals critical for the global energy transition, e.g., Co and precious metals such as Au and Re. These metals are currently determined on composite mineral samples, which commonly results in their dilution. Thus, it is possible that some metals of interest are overlooked during metallurgical processing and are subsequently lost to tailings. Here, an advanced geochemical characterization is implemented directly on metal-bearing sulfides, determining the grade of each targeted trace metal and recognizing its specific host mineral. Results show that pyrite is a prime host mineral for Co (up to 24,000 ppm) and commonly contains Au (up to 5 ppm), while molybdenite contains high grades of Re (up to 514 ppm) and Au (up to 31 ppm). Both minerals represent around 0.2% of the mineralized samples. The dataset is used to evaluate the possibility of extracting trace metals as by-products during Cu-sulfide processing, by the addition of unit operations to conventional plant designs. A remarkable advantage of the proposed workflows is that costs of mining, crushing, and grinding stages are accounted for in the copper production investments. The proposed geochemical characterization can be applied to other porphyry-type operations to improve the metallic benefits from a single deposit.
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spelling doaj.art-135e7c00014342c8aac00e18d68fa3ed2023-11-20T03:31:45ZengMDPI AGMinerals2075-163X2020-06-0110653110.3390/min10060531Metal-Selective Processing from the Los Sulfatos Porphyry-Type Deposit in Chile: Co, Au, and Re Recovery Workflows Based on Advanced Geochemical CharacterizationGermán Velásquez0Humberto Estay1Iván Vela2Stefano Salvi3Marcial Pablo4Advanced Mining Technology Center (AMTC), FCFM, Universidad de Chile, Santiago 8370451, ChileAdvanced Mining Technology Center (AMTC), FCFM, Universidad de Chile, Santiago 8370451, ChileSuperintendence of Geology, Los Bronces Underground Project, Anglo American Sur S.A., Santiago 7550103, ChileGéosciences Environnement Toulouse (GET), Université de Toulouse, CNRS, GET, IRD, OMP, 14 Av. Edouard Belin, 31400 Toulouse, FranceSuperintendence of Geology, Los Bronces Underground Project, Anglo American Sur S.A., Santiago 7550103, ChileSulfides extracted from porphyry-type deposits can contain a number of metals critical for the global energy transition, e.g., Co and precious metals such as Au and Re. These metals are currently determined on composite mineral samples, which commonly results in their dilution. Thus, it is possible that some metals of interest are overlooked during metallurgical processing and are subsequently lost to tailings. Here, an advanced geochemical characterization is implemented directly on metal-bearing sulfides, determining the grade of each targeted trace metal and recognizing its specific host mineral. Results show that pyrite is a prime host mineral for Co (up to 24,000 ppm) and commonly contains Au (up to 5 ppm), while molybdenite contains high grades of Re (up to 514 ppm) and Au (up to 31 ppm). Both minerals represent around 0.2% of the mineralized samples. The dataset is used to evaluate the possibility of extracting trace metals as by-products during Cu-sulfide processing, by the addition of unit operations to conventional plant designs. A remarkable advantage of the proposed workflows is that costs of mining, crushing, and grinding stages are accounted for in the copper production investments. The proposed geochemical characterization can be applied to other porphyry-type operations to improve the metallic benefits from a single deposit.https://www.mdpi.com/2075-163X/10/6/531cobalt supplyrheniumgoldby-productspyrite processinggeo-metallurgy
spellingShingle Germán Velásquez
Humberto Estay
Iván Vela
Stefano Salvi
Marcial Pablo
Metal-Selective Processing from the Los Sulfatos Porphyry-Type Deposit in Chile: Co, Au, and Re Recovery Workflows Based on Advanced Geochemical Characterization
Minerals
cobalt supply
rhenium
gold
by-products
pyrite processing
geo-metallurgy
title Metal-Selective Processing from the Los Sulfatos Porphyry-Type Deposit in Chile: Co, Au, and Re Recovery Workflows Based on Advanced Geochemical Characterization
title_full Metal-Selective Processing from the Los Sulfatos Porphyry-Type Deposit in Chile: Co, Au, and Re Recovery Workflows Based on Advanced Geochemical Characterization
title_fullStr Metal-Selective Processing from the Los Sulfatos Porphyry-Type Deposit in Chile: Co, Au, and Re Recovery Workflows Based on Advanced Geochemical Characterization
title_full_unstemmed Metal-Selective Processing from the Los Sulfatos Porphyry-Type Deposit in Chile: Co, Au, and Re Recovery Workflows Based on Advanced Geochemical Characterization
title_short Metal-Selective Processing from the Los Sulfatos Porphyry-Type Deposit in Chile: Co, Au, and Re Recovery Workflows Based on Advanced Geochemical Characterization
title_sort metal selective processing from the los sulfatos porphyry type deposit in chile co au and re recovery workflows based on advanced geochemical characterization
topic cobalt supply
rhenium
gold
by-products
pyrite processing
geo-metallurgy
url https://www.mdpi.com/2075-163X/10/6/531
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