Solvatochromism Study on the Copper(II) Complexes Containing 3–Substituted Derivatives of Acetylacetonate Ligands
Solvatochromic properties of a series of bis(3–substituted derivatives of acetylacetone) copper(II) (X-acacH , X = Cl, H. CH3) complexes were studied. All the complexes demonstrated negative solvatochromism. Among the complexes the Cu(Cl-acac)2, demonstrated the most solvatochromism. A multi-par...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Babol Noshirvani University of Technology
2012-01-01
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| Series: | Iranica Journal of Energy and Environment |
| Subjects: | |
| Online Access: | http://www.ijee.net/Journal/ijee/vol3/no1/12.pdf |
| Summary: | Solvatochromic properties of a series of bis(3–substituted derivatives of acetylacetone) copper(II) (X-acacH , X = Cl, H. CH3) complexes were studied. All the complexes demonstrated negative solvatochromism. Among the complexes the Cu(Cl-acac)2, demonstrated the most solvatochromism. A multi-parametric equation has been utilized to explain the solvent effect on the d-d transition of the complexes using SPSS/PC software. The stepwise multiple linear regression (SMLR) method demonstrated that the donor power of the solvent plays the most important role in the solvatochromism of the compounds. |
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| ISSN: | 2079-2115 2079-2123 |