Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex
Fast intermetallic electron transfer is expected in principle in nanozised transition metal complexes, but has been prevented by the bridging ligands. Here the authors synthesize a mixed-valence iron metal-ligand nanocluster with cyanide bridges, showing extended delocalized electronic structure
Bibliographic Details
| Main Authors: |
Wei Huang,
Shuqi Wu,
Xiangwei Gu,
Yao Li,
Atsushi Okazawa,
Norimichi Kojima,
Shinya Hayami,
Michael L. Baker,
Peter Bencok,
Mariko Noguchi,
Yuji Miyazaki,
Motohiro Nakano,
Takumi Nakanishi,
Shinji Kanegawa,
Yuji Inagaki,
Tatsuya Kawae,
Gui-Lin Zhuang,
Yoshihito Shiota,
Kazunari Yoshizawa,
Dayu Wu,
Osamu Sato |
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| Format: | Article
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| Language: | English |
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| Published: |
Nature Portfolio
2019-12-01
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| Series: | Nature Communications
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| Online Access: | https://doi.org/10.1038/s41467-019-13279-y
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