Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex
Fast intermetallic electron transfer is expected in principle in nanozised transition metal complexes, but has been prevented by the bridging ligands. Here the authors synthesize a mixed-valence iron metal-ligand nanocluster with cyanide bridges, showing extended delocalized electronic structure
| Main Authors: | , , , , , , , , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2019-12-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-019-13279-y |
| _version_ | 1818682312259272704 |
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| author | Wei Huang Shuqi Wu Xiangwei Gu Yao Li Atsushi Okazawa Norimichi Kojima Shinya Hayami Michael L. Baker Peter Bencok Mariko Noguchi Yuji Miyazaki Motohiro Nakano Takumi Nakanishi Shinji Kanegawa Yuji Inagaki Tatsuya Kawae Gui-Lin Zhuang Yoshihito Shiota Kazunari Yoshizawa Dayu Wu Osamu Sato |
| author_facet | Wei Huang Shuqi Wu Xiangwei Gu Yao Li Atsushi Okazawa Norimichi Kojima Shinya Hayami Michael L. Baker Peter Bencok Mariko Noguchi Yuji Miyazaki Motohiro Nakano Takumi Nakanishi Shinji Kanegawa Yuji Inagaki Tatsuya Kawae Gui-Lin Zhuang Yoshihito Shiota Kazunari Yoshizawa Dayu Wu Osamu Sato |
| author_sort | Wei Huang |
| collection | DOAJ |
| description | Fast intermetallic electron transfer is expected in principle in nanozised transition metal complexes, but has been prevented by the bridging ligands. Here the authors synthesize a mixed-valence iron metal-ligand nanocluster with cyanide bridges, showing extended delocalized electronic structure |
| first_indexed | 2024-12-17T10:16:50Z |
| format | Article |
| id | doaj.art-139c48ef6def400aa029e0e9c54d0a92 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-17T10:16:50Z |
| publishDate | 2019-12-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-139c48ef6def400aa029e0e9c54d0a922022-12-21T21:52:53ZengNature PortfolioNature Communications2041-17232019-12-011011910.1038/s41467-019-13279-yTemperature dependence of spherical electron transfer in a nanosized [Fe14] complexWei Huang0Shuqi Wu1Xiangwei Gu2Yao Li3Atsushi Okazawa4Norimichi Kojima5Shinya Hayami6Michael L. Baker7Peter Bencok8Mariko Noguchi9Yuji Miyazaki10Motohiro Nakano11Takumi Nakanishi12Shinji Kanegawa13Yuji Inagaki14Tatsuya Kawae15Gui-Lin Zhuang16Yoshihito Shiota17Kazunari Yoshizawa18Dayu Wu19Osamu Sato20Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis & Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityJiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis & Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou UniversityJiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis & Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou UniversityDepartment of Basic Science, Graduation School of Arts and Sciences, The University of TokyoToyota Physical and Chemical Research InstituteDepartment of Chemistry, Graduate School of Science and Technology and Institute of Pulsed Power Science (IPPS), Kumamoto UniversityThe School of Chemistry, The University of ManchesterDiamond Light Source, Science DivisionResearch Center for Structural Thermodynamics, Graduate School of Science, Osaka UniversityResearch Center for Structural Thermodynamics, Graduate School of Science, Osaka UniversityResearch Center for Structural Thermodynamics, Graduate School of Science, Osaka UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityDepartment of Applied Quantum Physics, Faculty of Engineering, Kyushu UniversityDepartment of Applied Quantum Physics, Faculty of Engineering, Kyushu UniversityInstitute of Industrial Catalysis, College of Chemical Engineering, State Key Lab Breeding Base of Green-Chemical Synthesis Technology, Zhejiang University of TechnologyInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityJiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis & Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou UniversityInstitute for Materials Chemistry and Engineering & IRCCS, Kyushu UniversityFast intermetallic electron transfer is expected in principle in nanozised transition metal complexes, but has been prevented by the bridging ligands. Here the authors synthesize a mixed-valence iron metal-ligand nanocluster with cyanide bridges, showing extended delocalized electronic structurehttps://doi.org/10.1038/s41467-019-13279-y |
| spellingShingle | Wei Huang Shuqi Wu Xiangwei Gu Yao Li Atsushi Okazawa Norimichi Kojima Shinya Hayami Michael L. Baker Peter Bencok Mariko Noguchi Yuji Miyazaki Motohiro Nakano Takumi Nakanishi Shinji Kanegawa Yuji Inagaki Tatsuya Kawae Gui-Lin Zhuang Yoshihito Shiota Kazunari Yoshizawa Dayu Wu Osamu Sato Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex Nature Communications |
| title | Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| title_full | Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| title_fullStr | Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| title_full_unstemmed | Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| title_short | Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex |
| title_sort | temperature dependence of spherical electron transfer in a nanosized fe14 complex |
| url | https://doi.org/10.1038/s41467-019-13279-y |
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