Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex

Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex

Fast intermetallic electron transfer is expected in principle in nanozised transition metal complexes, but has been prevented by the bridging ligands. Here the authors synthesize a mixed-valence iron metal-ligand nanocluster with cyanide bridges, showing extended delocalized electronic structure

Bibliographic Details
Main Authors: Wei Huang, Shuqi Wu, Xiangwei Gu, Yao Li, Atsushi Okazawa, Norimichi Kojima, Shinya Hayami, Michael L. Baker, Peter Bencok, Mariko Noguchi, Yuji Miyazaki, Motohiro Nakano, Takumi Nakanishi, Shinji Kanegawa, Yuji Inagaki, Tatsuya Kawae, Gui-Lin Zhuang, Yoshihito Shiota, Kazunari Yoshizawa, Dayu Wu, Osamu Sato
Format: Article
Language:English
Published: Nature Portfolio 2019-12-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-13279-y

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