Ethanol as a Probe for the Mechanism of Bubble Nucleation in the Diet Coke and Mentos Experiment

The Diet Coke and Mentos experiment involves dropping Mentos candies into carbonated beverages to produce a fountain. This simple experiment has enjoyed popularity with science teachers and the general public. Studies of the physicochemical processes involved in the generation of the fountain have b...

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Main Authors: Thomas S. Kuntzleman, Jacob T. Kuntzleman
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/26/6/1691
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author Thomas S. Kuntzleman
Jacob T. Kuntzleman
author_facet Thomas S. Kuntzleman
Jacob T. Kuntzleman
author_sort Thomas S. Kuntzleman
collection DOAJ
description The Diet Coke and Mentos experiment involves dropping Mentos candies into carbonated beverages to produce a fountain. This simple experiment has enjoyed popularity with science teachers and the general public. Studies of the physicochemical processes involved in the generation of the fountain have been largely informed by the physics of bubble nucleation. Herein, we probe the effect of ethanol addition on the Diet Coke and Mentos experiment to explore the impact that beverage surface tension and viscosity have on the heights of fountains achieved. Our results indicate that current descriptions of the effects of surface tension and viscosity are not completely understood. We also extend and apply a previously reported, simplified version of Brunauer–Emmett–Teller theory to investigate kinetic and mechanistic aspects of bubble nucleation on the surface of Mentos candies in carbonated beverages. A combination of this new theory and experiment allows for the estimation that the nucleation sites on the Mentos candy that catalyze degassing are 1–3 μm in size, and that between 50,000 and 300,000 of these sites actively nucleate bubbles on a single Mentos candy. While the methods employed are not highly sophisticated, they have potential to stimulate fresh investigations and insights into bubble nucleation in carbonated beverages.
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spelling doaj.art-13bad28d3bab46899922d1a036b0889f2023-11-21T10:54:52ZengMDPI AGMolecules1420-30492021-03-01266169110.3390/molecules26061691Ethanol as a Probe for the Mechanism of Bubble Nucleation in the Diet Coke and Mentos ExperimentThomas S. Kuntzleman0Jacob T. Kuntzleman1Department of Chemistry, Spring Arbor University, Spring Arbor, MI 49283, USADepartment of Physics, Duke University, Durham, NC 27710, USAThe Diet Coke and Mentos experiment involves dropping Mentos candies into carbonated beverages to produce a fountain. This simple experiment has enjoyed popularity with science teachers and the general public. Studies of the physicochemical processes involved in the generation of the fountain have been largely informed by the physics of bubble nucleation. Herein, we probe the effect of ethanol addition on the Diet Coke and Mentos experiment to explore the impact that beverage surface tension and viscosity have on the heights of fountains achieved. Our results indicate that current descriptions of the effects of surface tension and viscosity are not completely understood. We also extend and apply a previously reported, simplified version of Brunauer–Emmett–Teller theory to investigate kinetic and mechanistic aspects of bubble nucleation on the surface of Mentos candies in carbonated beverages. A combination of this new theory and experiment allows for the estimation that the nucleation sites on the Mentos candy that catalyze degassing are 1–3 μm in size, and that between 50,000 and 300,000 of these sites actively nucleate bubbles on a single Mentos candy. While the methods employed are not highly sophisticated, they have potential to stimulate fresh investigations and insights into bubble nucleation in carbonated beverages.https://www.mdpi.com/1420-3049/26/6/1691bubble nucleationbubblessurface sciencesodacarbonated beveragessparkling water
spellingShingle Thomas S. Kuntzleman
Jacob T. Kuntzleman
Ethanol as a Probe for the Mechanism of Bubble Nucleation in the Diet Coke and Mentos Experiment
Molecules
bubble nucleation
bubbles
surface science
soda
carbonated beverages
sparkling water
title Ethanol as a Probe for the Mechanism of Bubble Nucleation in the Diet Coke and Mentos Experiment
title_full Ethanol as a Probe for the Mechanism of Bubble Nucleation in the Diet Coke and Mentos Experiment
title_fullStr Ethanol as a Probe for the Mechanism of Bubble Nucleation in the Diet Coke and Mentos Experiment
title_full_unstemmed Ethanol as a Probe for the Mechanism of Bubble Nucleation in the Diet Coke and Mentos Experiment
title_short Ethanol as a Probe for the Mechanism of Bubble Nucleation in the Diet Coke and Mentos Experiment
title_sort ethanol as a probe for the mechanism of bubble nucleation in the diet coke and mentos experiment
topic bubble nucleation
bubbles
surface science
soda
carbonated beverages
sparkling water
url https://www.mdpi.com/1420-3049/26/6/1691
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