Pre‐Industrial, Present and Future Atmospheric Soluble Iron Deposition and the Role of Aerosol Acidity and Oxalate Under CMIP6 Emissions
Abstract Atmospheric iron (Fe) deposition to the open ocean affects net primary productivity, nitrogen fixation, and carbon uptake. We investigate changes in soluble Fe (SFe) deposition from the pre‐industrial period to the late 21st century using the EC‐Earth3‐Iron Earth System model. EC‐Earth3‐Iro...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2023-06-01
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| Series: | Earth's Future |
| Online Access: | https://doi.org/10.1029/2022EF003353 |
| _version_ | 1797793284397989888 |
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| author | Elisa Bergas‐Massó María Gonçalves Ageitos Stelios Myriokefalitakis Ron L. Miller Twan vanNoije Philippe Le Sager Gilbert Montané Pinto Carlos Pérez García‐Pando |
| author_facet | Elisa Bergas‐Massó María Gonçalves Ageitos Stelios Myriokefalitakis Ron L. Miller Twan vanNoije Philippe Le Sager Gilbert Montané Pinto Carlos Pérez García‐Pando |
| author_sort | Elisa Bergas‐Massó |
| collection | DOAJ |
| description | Abstract Atmospheric iron (Fe) deposition to the open ocean affects net primary productivity, nitrogen fixation, and carbon uptake. We investigate changes in soluble Fe (SFe) deposition from the pre‐industrial period to the late 21st century using the EC‐Earth3‐Iron Earth System model. EC‐Earth3‐Iron considers various sources of Fe, including dust, fossil fuel combustion, and biomass burning, and features comprehensive atmospheric chemistry, representing atmospheric oxalate, sulfate, and Fe cycles. We show that anthropogenic activity has changed the magnitude and spatial distribution of SFe deposition by increasing combustion Fe emissions and atmospheric acidity and oxalate levels. We report that SFe deposition has doubled since the early industrial era, using the Coupled Model Intercomparison Project Phase 6 emission inventory. We highlight acidity as the main solubilization pathway for dust‐Fe and oxalate‐promoted processing for the solubilization of combustion‐Fe. We project a global SFe deposition increase of 40% by the late 21st century relative to present day under Shared Socioeconomic Pathway (SSP) 3–7.0, which assumes weak climate change mitigation policies. Conversely, SSPs with stronger mitigation pathways (1–2.6 and 2–4.5) result in 35% and 10% global decreases, respectively. Despite these differences, SFe deposition increases over the equatorial Pacific and decreases in the Southern Ocean (SO) for all SSPs. We further observe that deposition over the equatorial Pacific and SO are highly sensitive to future changes in dust emissions from Australia and South America, as well as from North Africa. Future studies should focus on the potential impact of climate‐ and human‐induced changes in dust and wildfires combined. |
| first_indexed | 2024-03-13T02:46:07Z |
| format | Article |
| id | doaj.art-13c4a38e82bf449d83866fe7f0ab4861 |
| institution | Directory Open Access Journal |
| issn | 2328-4277 |
| language | English |
| last_indexed | 2024-03-13T02:46:07Z |
| publishDate | 2023-06-01 |
| publisher | Wiley |
| record_format | Article |
| series | Earth's Future |
| spelling | doaj.art-13c4a38e82bf449d83866fe7f0ab48612023-06-28T17:32:43ZengWileyEarth's Future2328-42772023-06-01116n/an/a10.1029/2022EF003353Pre‐Industrial, Present and Future Atmospheric Soluble Iron Deposition and the Role of Aerosol Acidity and Oxalate Under CMIP6 EmissionsElisa Bergas‐Massó0María Gonçalves Ageitos1Stelios Myriokefalitakis2Ron L. Miller3Twan vanNoije4Philippe Le Sager5Gilbert Montané Pinto6Carlos Pérez García‐Pando7Barcelona Supercomputing Center (BSC) Barcelona SpainBarcelona Supercomputing Center (BSC) Barcelona SpainInstitute for Environmental Research and Sustainable Development (IERSD) National Observatory of Athens Penteli GreeceNASA Goddard Institute for Space Studies New York NY USARoyal Netherlands Meteorological Institute (KNMI) De Bilt The NetherlandsRoyal Netherlands Meteorological Institute (KNMI) De Bilt The NetherlandsBarcelona Supercomputing Center (BSC) Barcelona SpainBarcelona Supercomputing Center (BSC) Barcelona SpainAbstract Atmospheric iron (Fe) deposition to the open ocean affects net primary productivity, nitrogen fixation, and carbon uptake. We investigate changes in soluble Fe (SFe) deposition from the pre‐industrial period to the late 21st century using the EC‐Earth3‐Iron Earth System model. EC‐Earth3‐Iron considers various sources of Fe, including dust, fossil fuel combustion, and biomass burning, and features comprehensive atmospheric chemistry, representing atmospheric oxalate, sulfate, and Fe cycles. We show that anthropogenic activity has changed the magnitude and spatial distribution of SFe deposition by increasing combustion Fe emissions and atmospheric acidity and oxalate levels. We report that SFe deposition has doubled since the early industrial era, using the Coupled Model Intercomparison Project Phase 6 emission inventory. We highlight acidity as the main solubilization pathway for dust‐Fe and oxalate‐promoted processing for the solubilization of combustion‐Fe. We project a global SFe deposition increase of 40% by the late 21st century relative to present day under Shared Socioeconomic Pathway (SSP) 3–7.0, which assumes weak climate change mitigation policies. Conversely, SSPs with stronger mitigation pathways (1–2.6 and 2–4.5) result in 35% and 10% global decreases, respectively. Despite these differences, SFe deposition increases over the equatorial Pacific and decreases in the Southern Ocean (SO) for all SSPs. We further observe that deposition over the equatorial Pacific and SO are highly sensitive to future changes in dust emissions from Australia and South America, as well as from North Africa. Future studies should focus on the potential impact of climate‐ and human‐induced changes in dust and wildfires combined.https://doi.org/10.1029/2022EF003353 |
| spellingShingle | Elisa Bergas‐Massó María Gonçalves Ageitos Stelios Myriokefalitakis Ron L. Miller Twan vanNoije Philippe Le Sager Gilbert Montané Pinto Carlos Pérez García‐Pando Pre‐Industrial, Present and Future Atmospheric Soluble Iron Deposition and the Role of Aerosol Acidity and Oxalate Under CMIP6 Emissions Earth's Future |
| title | Pre‐Industrial, Present and Future Atmospheric Soluble Iron Deposition and the Role of Aerosol Acidity and Oxalate Under CMIP6 Emissions |
| title_full | Pre‐Industrial, Present and Future Atmospheric Soluble Iron Deposition and the Role of Aerosol Acidity and Oxalate Under CMIP6 Emissions |
| title_fullStr | Pre‐Industrial, Present and Future Atmospheric Soluble Iron Deposition and the Role of Aerosol Acidity and Oxalate Under CMIP6 Emissions |
| title_full_unstemmed | Pre‐Industrial, Present and Future Atmospheric Soluble Iron Deposition and the Role of Aerosol Acidity and Oxalate Under CMIP6 Emissions |
| title_short | Pre‐Industrial, Present and Future Atmospheric Soluble Iron Deposition and the Role of Aerosol Acidity and Oxalate Under CMIP6 Emissions |
| title_sort | pre industrial present and future atmospheric soluble iron deposition and the role of aerosol acidity and oxalate under cmip6 emissions |
| url | https://doi.org/10.1029/2022EF003353 |
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