Solidification of two fused cast Al2O3–ZrO2–SiO2 materials in an aero acoustic levitator

Due to their excellent high-temperature properties and corrosion resistance, AZS materials are widely used in glas making. Two industrially available fused cast AZS materials were chosen for this study. One composition was close to the ternary eutectic of zirconia, mullite, and corundum. The other m...

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Main Authors: Jonas Niessen, D. Muehmer, T. Tonnesen, R. Telle, J. Gonzalez-Julian
Format: Article
Language:English
Published: Elsevier 2023-09-01
Series:Open Ceramics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666539523000950
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author Jonas Niessen
D. Muehmer
T. Tonnesen
R. Telle
J. Gonzalez-Julian
author_facet Jonas Niessen
D. Muehmer
T. Tonnesen
R. Telle
J. Gonzalez-Julian
author_sort Jonas Niessen
collection DOAJ
description Due to their excellent high-temperature properties and corrosion resistance, AZS materials are widely used in glas making. Two industrially available fused cast AZS materials were chosen for this study. One composition was close to the ternary eutectic of zirconia, mullite, and corundum. The other material was close to mullite composition with approx ten wt% ZrO2. The microstructure and phase composition of the received material was analyzed. Additionally, the materials were remelted in an aero acoustic levitator. The fused cast grains and the remelted samples showed significant differences in the microstructure and phase composition. Due to the high cooling rates and homogeneous nucleation under containerless conditions, both materials tended to form a glassy phase. Cooling samples with a pre-existent nucleus or controlled conditions yielded a fine-grained crystalline microstructure. For conventional cooling, the silica and alumina-rich material exhibited large corundum precipitates. In contrast, the containerless processed sample showed primary precipitation of mullite.
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spelling doaj.art-13e4993d8eda405686970812986b70ba2023-08-28T04:23:24ZengElsevierOpen Ceramics2666-53952023-09-0115100423Solidification of two fused cast Al2O3–ZrO2–SiO2 materials in an aero acoustic levitatorJonas Niessen0D. Muehmer1T. Tonnesen2R. Telle3J. Gonzalez-Julian4Corresponding author.; Institute of Mineral Engineering, Chair of Ceramics, RWTH Aachen University, Aachen, GermanyInstitute of Mineral Engineering, Chair of Ceramics, RWTH Aachen University, Aachen, GermanyInstitute of Mineral Engineering, Chair of Ceramics, RWTH Aachen University, Aachen, GermanyInstitute of Mineral Engineering, Chair of Ceramics, RWTH Aachen University, Aachen, GermanyInstitute of Mineral Engineering, Chair of Ceramics, RWTH Aachen University, Aachen, GermanyDue to their excellent high-temperature properties and corrosion resistance, AZS materials are widely used in glas making. Two industrially available fused cast AZS materials were chosen for this study. One composition was close to the ternary eutectic of zirconia, mullite, and corundum. The other material was close to mullite composition with approx ten wt% ZrO2. The microstructure and phase composition of the received material was analyzed. Additionally, the materials were remelted in an aero acoustic levitator. The fused cast grains and the remelted samples showed significant differences in the microstructure and phase composition. Due to the high cooling rates and homogeneous nucleation under containerless conditions, both materials tended to form a glassy phase. Cooling samples with a pre-existent nucleus or controlled conditions yielded a fine-grained crystalline microstructure. For conventional cooling, the silica and alumina-rich material exhibited large corundum precipitates. In contrast, the containerless processed sample showed primary precipitation of mullite.http://www.sciencedirect.com/science/article/pii/S2666539523000950Aero acoustic levitationAZSSolidification
spellingShingle Jonas Niessen
D. Muehmer
T. Tonnesen
R. Telle
J. Gonzalez-Julian
Solidification of two fused cast Al2O3–ZrO2–SiO2 materials in an aero acoustic levitator
Open Ceramics
Aero acoustic levitation
AZS
Solidification
title Solidification of two fused cast Al2O3–ZrO2–SiO2 materials in an aero acoustic levitator
title_full Solidification of two fused cast Al2O3–ZrO2–SiO2 materials in an aero acoustic levitator
title_fullStr Solidification of two fused cast Al2O3–ZrO2–SiO2 materials in an aero acoustic levitator
title_full_unstemmed Solidification of two fused cast Al2O3–ZrO2–SiO2 materials in an aero acoustic levitator
title_short Solidification of two fused cast Al2O3–ZrO2–SiO2 materials in an aero acoustic levitator
title_sort solidification of two fused cast al2o3 zro2 sio2 materials in an aero acoustic levitator
topic Aero acoustic levitation
AZS
Solidification
url http://www.sciencedirect.com/science/article/pii/S2666539523000950
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