SYNTHESIS, CRYSTAL STRUCTURE AND LUMINESCENT PROPERTY OF A DINUCLEAR Tb(II) COMPLEX WITH HOMOPHTHALIC ACID AND 2,2’-BIPYRIDYL
A novel dinuclear Tb(III) complex, [Tb(bpy)2L2] (bpy = 2,2’-bipyridine, H2L = homophthalic acid), has been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. The Tb(III) complex is monoclinic, space group P21/c with a = 9.368(2) Å, b = 15.948(4) Å, c = 12.216(3...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2015-07-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201502&vol=2&aid=4238 |
| _version_ | 1819069580342984704 |
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| author | LI-HUA WANG |
| author_facet | LI-HUA WANG |
| author_sort | LI-HUA WANG |
| collection | DOAJ |
| description | A novel dinuclear Tb(III) complex, [Tb(bpy)2L2] (bpy = 2,2’-bipyridine, H2L = homophthalic acid), has been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. The Tb(III) complex is monoclinic, space group P21/c with a = 9.368(2) Å, b = 15.948(4) Å, c = 12.216(3) Å, β = 103.023(4)º, V= 1778.2(7) Å3, Z = 2, Dc = 1.910 mg·m-3, μ = 4.011 mm-1, F(000) = 996, and final R1 = 0.0602, ωR2 = 0.2192. The result shows that the Tb(III) center is seven-coordination with a N2O5 distorted pengonal bipyramidal geometry. The luminescent property of Tb(III) complex was investigated. |
| first_indexed | 2024-12-21T16:52:18Z |
| format | Article |
| id | doaj.art-13fcaa0dfd53494ca2c6a0157e389c9c |
| institution | Directory Open Access Journal |
| issn | 1582-540X 1582-540X |
| language | English |
| last_indexed | 2024-12-21T16:52:18Z |
| publishDate | 2015-07-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj.art-13fcaa0dfd53494ca2c6a0157e389c9c2022-12-21T18:56:50ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2015-07-01162179183SYNTHESIS, CRYSTAL STRUCTURE AND LUMINESCENT PROPERTY OF A DINUCLEAR Tb(II) COMPLEX WITH HOMOPHTHALIC ACID AND 2,2’-BIPYRIDYLLI-HUA WANG0College of Information and Engineering, Weifang University, Weifang 261061, P. R. China A novel dinuclear Tb(III) complex, [Tb(bpy)2L2] (bpy = 2,2’-bipyridine, H2L = homophthalic acid), has been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. The Tb(III) complex is monoclinic, space group P21/c with a = 9.368(2) Å, b = 15.948(4) Å, c = 12.216(3) Å, β = 103.023(4)º, V= 1778.2(7) Å3, Z = 2, Dc = 1.910 mg·m-3, μ = 4.011 mm-1, F(000) = 996, and final R1 = 0.0602, ωR2 = 0.2192. The result shows that the Tb(III) center is seven-coordination with a N2O5 distorted pengonal bipyramidal geometry. The luminescent property of Tb(III) complex was investigated.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201502&vol=2&aid=4238dinuclear Tb(III) complexluminescence propertysynthesisstructural characterization |
| spellingShingle | LI-HUA WANG SYNTHESIS, CRYSTAL STRUCTURE AND LUMINESCENT PROPERTY OF A DINUCLEAR Tb(II) COMPLEX WITH HOMOPHTHALIC ACID AND 2,2’-BIPYRIDYL Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry dinuclear Tb(III) complex luminescence property synthesis structural characterization |
| title | SYNTHESIS, CRYSTAL STRUCTURE AND LUMINESCENT PROPERTY OF A DINUCLEAR Tb(II) COMPLEX WITH HOMOPHTHALIC ACID AND 2,2’-BIPYRIDYL |
| title_full | SYNTHESIS, CRYSTAL STRUCTURE AND LUMINESCENT PROPERTY OF A DINUCLEAR Tb(II) COMPLEX WITH HOMOPHTHALIC ACID AND 2,2’-BIPYRIDYL |
| title_fullStr | SYNTHESIS, CRYSTAL STRUCTURE AND LUMINESCENT PROPERTY OF A DINUCLEAR Tb(II) COMPLEX WITH HOMOPHTHALIC ACID AND 2,2’-BIPYRIDYL |
| title_full_unstemmed | SYNTHESIS, CRYSTAL STRUCTURE AND LUMINESCENT PROPERTY OF A DINUCLEAR Tb(II) COMPLEX WITH HOMOPHTHALIC ACID AND 2,2’-BIPYRIDYL |
| title_short | SYNTHESIS, CRYSTAL STRUCTURE AND LUMINESCENT PROPERTY OF A DINUCLEAR Tb(II) COMPLEX WITH HOMOPHTHALIC ACID AND 2,2’-BIPYRIDYL |
| title_sort | synthesis crystal structure and luminescent property of a dinuclear tb ii complex with homophthalic acid and 2 2 bipyridyl |
| topic | dinuclear Tb(III) complex luminescence property synthesis structural characterization |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201502&vol=2&aid=4238 |
| work_keys_str_mv | AT lihuawang synthesiscrystalstructureandluminescentpropertyofadinucleartbiicomplexwithhomophthalicacidand22bipyridyl |