Chemisorption of n-Butylamine and n-Butylmercaptan on Fluoride-Modified CoMo/AlO Catalysts

The chemisorption of n-butylamine (n-BA) and n-butylmercaptan (n-BM) on cobalt–molybdenum catalysts supported on alumina containing fluoride ions was studied. The active phases of the catalysts were introduced in two ways: either simultaneously or in two stages. It was shown that the chemisorption o...

Full description

Bibliographic Details
Main Authors: Z. Sarbak, A. Pogorzelska
Format: Article
Language:English
Published: SAGE Publications 2002-11-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/02636170260555813
_version_ 1797283077973606400
author Z. Sarbak
A. Pogorzelska
author_facet Z. Sarbak
A. Pogorzelska
author_sort Z. Sarbak
collection DOAJ
description The chemisorption of n-butylamine (n-BA) and n-butylmercaptan (n-BM) on cobalt–molybdenum catalysts supported on alumina containing fluoride ions was studied. The active phases of the catalysts were introduced in two ways: either simultaneously or in two stages. It was shown that the chemisorption of n-BA increased with increasing concentration of fluoride ions, but no such relationship was observed for n-BM. The sequence in which fluoride ions and CoMo were introduced had no significant effect on the effectiveness of chemisorption.
first_indexed 2024-03-07T17:25:51Z
format Article
id doaj.art-140a6fcf47d045f18860dde52ce471b8
institution Directory Open Access Journal
issn 0263-6174
2048-4038
language English
last_indexed 2024-03-07T17:25:51Z
publishDate 2002-11-01
publisher SAGE Publications
record_format Article
series Adsorption Science & Technology
spelling doaj.art-140a6fcf47d045f18860dde52ce471b82024-03-02T19:08:07ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382002-11-012010.1260/02636170260555813Chemisorption of n-Butylamine and n-Butylmercaptan on Fluoride-Modified CoMo/AlO CatalystsZ. SarbakA. PogorzelskaThe chemisorption of n-butylamine (n-BA) and n-butylmercaptan (n-BM) on cobalt–molybdenum catalysts supported on alumina containing fluoride ions was studied. The active phases of the catalysts were introduced in two ways: either simultaneously or in two stages. It was shown that the chemisorption of n-BA increased with increasing concentration of fluoride ions, but no such relationship was observed for n-BM. The sequence in which fluoride ions and CoMo were introduced had no significant effect on the effectiveness of chemisorption.https://doi.org/10.1260/02636170260555813
spellingShingle Z. Sarbak
A. Pogorzelska
Chemisorption of n-Butylamine and n-Butylmercaptan on Fluoride-Modified CoMo/AlO Catalysts
Adsorption Science & Technology
title Chemisorption of n-Butylamine and n-Butylmercaptan on Fluoride-Modified CoMo/AlO Catalysts
title_full Chemisorption of n-Butylamine and n-Butylmercaptan on Fluoride-Modified CoMo/AlO Catalysts
title_fullStr Chemisorption of n-Butylamine and n-Butylmercaptan on Fluoride-Modified CoMo/AlO Catalysts
title_full_unstemmed Chemisorption of n-Butylamine and n-Butylmercaptan on Fluoride-Modified CoMo/AlO Catalysts
title_short Chemisorption of n-Butylamine and n-Butylmercaptan on Fluoride-Modified CoMo/AlO Catalysts
title_sort chemisorption of n butylamine and n butylmercaptan on fluoride modified como alo catalysts
url https://doi.org/10.1260/02636170260555813
work_keys_str_mv AT zsarbak chemisorptionofnbutylamineandnbutylmercaptanonfluoridemodifiedcomoalocatalysts
AT apogorzelska chemisorptionofnbutylamineandnbutylmercaptanonfluoridemodifiedcomoalocatalysts