Hexaaquazinc(II) bis[tris(3-carboxypyridine-2-carboxylato)zincate(II)]
The title compound, [Zn(H2O)6][Zn(C7H4NO4)3]2, consists of two [Zn(py-2,3-dcH)3]− anions (py-2,3-dcH is 3-carboxypyridine-2-carboxylate) and one [Zn(H2O)6]2+ cation. The anion is a six-coordinate complex located on a threefold rotation axis with a slightly distorted octahedral geometry...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810047252 |
| _version_ | 1818285897481715712 |
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| author | Mehrnaz Gharagozlou Andya Nemati Vratislav Langer |
| author_facet | Mehrnaz Gharagozlou Andya Nemati Vratislav Langer |
| author_sort | Mehrnaz Gharagozlou |
| collection | DOAJ |
| description | The title compound, [Zn(H2O)6][Zn(C7H4NO4)3]2, consists of two [Zn(py-2,3-dcH)3]− anions (py-2,3-dcH is 3-carboxypyridine-2-carboxylate) and one [Zn(H2O)6]2+ cation. The anion is a six-coordinate complex located on a threefold rotation axis with a slightly distorted octahedral geometry around Zn2+ ion. The cation is also six-coordinate with an octahedral geometry around the Zn atom, located at a overline{3} axis. Non-covalent interactions such as π–π stacking [centroid–centroid distance = 3.828 (4)Å] and O—H...O hydrogen bonds play important roles in stabilizing the supramolecular structure. |
| first_indexed | 2024-12-13T01:16:00Z |
| format | Article |
| id | doaj.art-140bbb847161492582eb698f5b8bc99a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:16:00Z |
| publishDate | 2010-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-140bbb847161492582eb698f5b8bc99a2022-12-22T00:04:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1606m160710.1107/S1600536810047252Hexaaquazinc(II) bis[tris(3-carboxypyridine-2-carboxylato)zincate(II)]Mehrnaz GharagozlouAndya NematiVratislav LangerThe title compound, [Zn(H2O)6][Zn(C7H4NO4)3]2, consists of two [Zn(py-2,3-dcH)3]− anions (py-2,3-dcH is 3-carboxypyridine-2-carboxylate) and one [Zn(H2O)6]2+ cation. The anion is a six-coordinate complex located on a threefold rotation axis with a slightly distorted octahedral geometry around Zn2+ ion. The cation is also six-coordinate with an octahedral geometry around the Zn atom, located at a overline{3} axis. Non-covalent interactions such as π–π stacking [centroid–centroid distance = 3.828 (4)Å] and O—H...O hydrogen bonds play important roles in stabilizing the supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S1600536810047252 |
| spellingShingle | Mehrnaz Gharagozlou Andya Nemati Vratislav Langer Hexaaquazinc(II) bis[tris(3-carboxypyridine-2-carboxylato)zincate(II)] Acta Crystallographica Section E |
| title | Hexaaquazinc(II) bis[tris(3-carboxypyridine-2-carboxylato)zincate(II)] |
| title_full | Hexaaquazinc(II) bis[tris(3-carboxypyridine-2-carboxylato)zincate(II)] |
| title_fullStr | Hexaaquazinc(II) bis[tris(3-carboxypyridine-2-carboxylato)zincate(II)] |
| title_full_unstemmed | Hexaaquazinc(II) bis[tris(3-carboxypyridine-2-carboxylato)zincate(II)] |
| title_short | Hexaaquazinc(II) bis[tris(3-carboxypyridine-2-carboxylato)zincate(II)] |
| title_sort | hexaaquazinc ii bis tris 3 carboxypyridine 2 carboxylato zincate ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810047252 |
| work_keys_str_mv | AT mehrnazgharagozlou hexaaquazinciibistris3carboxypyridine2carboxylatozincateii AT andyanemati hexaaquazinciibistris3carboxypyridine2carboxylatozincateii AT vratislavlanger hexaaquazinciibistris3carboxypyridine2carboxylatozincateii |