Isonicotinic acid-ligated cobalt (II) phthalocyanine-modified titania as photocatalyst for benzene degradation via fluorescent lamp
The utilization of bis(isonicotinic acid)phthalocyaninatocobalt (II) [CoPc(isa)2] incorporated on TiO2 has been studied as a photocatalyst to degrade benzene vapor under fluorescent lamp (indoor light) conditions. The photocatalytic activity of [CoPc(isa)2]-TiO2 compared to TiO2 showed an increase i...
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| Format: | Article |
| Language: | English |
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Growing Science
2016-06-01
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| Series: | Current Chemistry Letters |
| Subjects: | |
| Online Access: | http://www.growingscience.com/ccl/Vol5/ccl_2016_7.pdf |
| _version_ | 1818806179714826240 |
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| author | Joey Andrew A. Valinton Ji Hye Son Jeremiah John O. Zafra Gil Nonato C. Santos Michael Angelo B. Promentilla Derrick Ethelbhert C. Yu |
| author_facet | Joey Andrew A. Valinton Ji Hye Son Jeremiah John O. Zafra Gil Nonato C. Santos Michael Angelo B. Promentilla Derrick Ethelbhert C. Yu |
| author_sort | Joey Andrew A. Valinton |
| collection | DOAJ |
| description | The utilization of bis(isonicotinic acid)phthalocyaninatocobalt (II) [CoPc(isa)2] incorporated on TiO2 has been studied as a photocatalyst to degrade benzene vapor under fluorescent lamp (indoor light) conditions. The photocatalytic activity of [CoPc(isa)2]-TiO2 compared to TiO2 showed an increase in the extent of degradation. The axial isonicotinic acid ligand attached to CoPc improved the degradation rate of benzene as compared with unligated CoPc-TiO2 which may be attributed to the enhancement of electronic structure in the complex due to the additional isonicotinic acid ligand and its possible attachment to the TiO2 surface through the carboxylic acid moiety. Therefore, covalently-linked CoPc(isa)2 to TiO2 can enhance the extent of photodegradation of benzene and other common volatile organic compounds under indoor lighting conditions. |
| first_indexed | 2024-12-18T19:05:40Z |
| format | Article |
| id | doaj.art-141634fcad6f41558ebf22ff41e370cd |
| institution | Directory Open Access Journal |
| issn | 1927-7296 1927-730X |
| language | English |
| last_indexed | 2024-12-18T19:05:40Z |
| publishDate | 2016-06-01 |
| publisher | Growing Science |
| record_format | Article |
| series | Current Chemistry Letters |
| spelling | doaj.art-141634fcad6f41558ebf22ff41e370cd2022-12-21T20:56:26ZengGrowing ScienceCurrent Chemistry Letters1927-72961927-730X2016-06-0153939810.5267/j.ccl.2016.4.002Isonicotinic acid-ligated cobalt (II) phthalocyanine-modified titania as photocatalyst for benzene degradation via fluorescent lampJoey Andrew A. ValintonJi Hye SonJeremiah John O. ZafraGil Nonato C. SantosMichael Angelo B. Promentilla Derrick Ethelbhert C. YuThe utilization of bis(isonicotinic acid)phthalocyaninatocobalt (II) [CoPc(isa)2] incorporated on TiO2 has been studied as a photocatalyst to degrade benzene vapor under fluorescent lamp (indoor light) conditions. The photocatalytic activity of [CoPc(isa)2]-TiO2 compared to TiO2 showed an increase in the extent of degradation. The axial isonicotinic acid ligand attached to CoPc improved the degradation rate of benzene as compared with unligated CoPc-TiO2 which may be attributed to the enhancement of electronic structure in the complex due to the additional isonicotinic acid ligand and its possible attachment to the TiO2 surface through the carboxylic acid moiety. Therefore, covalently-linked CoPc(isa)2 to TiO2 can enhance the extent of photodegradation of benzene and other common volatile organic compounds under indoor lighting conditions.http://www.growingscience.com/ccl/Vol5/ccl_2016_7.pdfAxially-ligated cobalt (II) phthalocyaninePhotocatalystIndoor air pollutionBenzeneTitanium (IV) oxidePhotosensitization |
| spellingShingle | Joey Andrew A. Valinton Ji Hye Son Jeremiah John O. Zafra Gil Nonato C. Santos Michael Angelo B. Promentilla Derrick Ethelbhert C. Yu Isonicotinic acid-ligated cobalt (II) phthalocyanine-modified titania as photocatalyst for benzene degradation via fluorescent lamp Current Chemistry Letters Axially-ligated cobalt (II) phthalocyanine Photocatalyst Indoor air pollution Benzene Titanium (IV) oxide Photosensitization |
| title | Isonicotinic acid-ligated cobalt (II) phthalocyanine-modified titania as photocatalyst for benzene degradation via fluorescent lamp |
| title_full | Isonicotinic acid-ligated cobalt (II) phthalocyanine-modified titania as photocatalyst for benzene degradation via fluorescent lamp |
| title_fullStr | Isonicotinic acid-ligated cobalt (II) phthalocyanine-modified titania as photocatalyst for benzene degradation via fluorescent lamp |
| title_full_unstemmed | Isonicotinic acid-ligated cobalt (II) phthalocyanine-modified titania as photocatalyst for benzene degradation via fluorescent lamp |
| title_short | Isonicotinic acid-ligated cobalt (II) phthalocyanine-modified titania as photocatalyst for benzene degradation via fluorescent lamp |
| title_sort | isonicotinic acid ligated cobalt ii phthalocyanine modified titania as photocatalyst for benzene degradation via fluorescent lamp |
| topic | Axially-ligated cobalt (II) phthalocyanine Photocatalyst Indoor air pollution Benzene Titanium (IV) oxide Photosensitization |
| url | http://www.growingscience.com/ccl/Vol5/ccl_2016_7.pdf |
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