Comparison of 14C and U-Th ages of two Holocene phreatic overgrowths on speleothems from Mallorca (Western Mediterranean): Environmental implications

This investigation reports on the comparison between ICP-MS U-Th and AMS 14C ages of Phreatic Overgrowths on Speleothems (POS) from two different caves on the island of Mallorca (Spain). These speleothem encrustations form at the water table of coastal caves in a low-amplitude tide-controlled microe...

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Main Authors: Tuccimei Paola, Van Strydonck Mark, Ginés Angel, Ginés Joaquin, Soligo Michele, Villa Igor, Fornós Joan J.
Format: Article
Language:English
Published: University of South Florida Libraries 2011-01-01
Series:International Journal of Speleology
Subjects:
Online Access:http://www.ijs.speleo.it/pdf/74.603.40(1)_Tuccimei.et.al.pdf
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author Tuccimei Paola
Van Strydonck Mark
Ginés Angel
Ginés Joaquin
Soligo Michele
Villa Igor
Fornós Joan J.
author_facet Tuccimei Paola
Van Strydonck Mark
Ginés Angel
Ginés Joaquin
Soligo Michele
Villa Igor
Fornós Joan J.
author_sort Tuccimei Paola
collection DOAJ
description This investigation reports on the comparison between ICP-MS U-Th and AMS 14C ages of Phreatic Overgrowths on Speleothems (POS) from two different caves on the island of Mallorca (Spain). These speleothem encrustations form at the water table of coastal caves in a low-amplitude tide-controlled microenvironment and are used to reconstruct past sea level changes. The aim of this study is to evaluate if this particular type of speleothem is datable using 14C method and to investigate possible problems connected with the incorporation of dead carbon inherited from the dissolution of 14C-free limestone. The results show that 14C ages are strongly site dependent and appear related to local residence time of water infiltration through the soil and epikarst. When short transit time and limited interaction with soil and bedrock, as in Cova de Cala Varques A, the so-called “reservoir” effect is negligible and 14C and U-Th ages corresponds within the error range. When the residence time is longer, as in Cova des Pas de Vallgornera, 14C ages are steadily 2,300-2,400 years older than the U-Th data, as shown by the mean value (25%) of estimated percent dead carbon proportions and by higher and better correlated contents of major and trace elements in the vadose support of this speleothem encrustation. The potential use of this multi-method approach to paleoenvironmental studies is also suggested.
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spelling doaj.art-142464bbdccd4337b1d0edcde05a2c162022-12-21T19:51:14ZengUniversity of South Florida LibrariesInternational Journal of Speleology0392-66721827-806X2011-01-0140118Comparison of 14C and U-Th ages of two Holocene phreatic overgrowths on speleothems from Mallorca (Western Mediterranean): Environmental implicationsTuccimei PaolaVan Strydonck MarkGinés AngelGinés JoaquinSoligo MicheleVilla IgorFornós Joan J.This investigation reports on the comparison between ICP-MS U-Th and AMS 14C ages of Phreatic Overgrowths on Speleothems (POS) from two different caves on the island of Mallorca (Spain). These speleothem encrustations form at the water table of coastal caves in a low-amplitude tide-controlled microenvironment and are used to reconstruct past sea level changes. The aim of this study is to evaluate if this particular type of speleothem is datable using 14C method and to investigate possible problems connected with the incorporation of dead carbon inherited from the dissolution of 14C-free limestone. The results show that 14C ages are strongly site dependent and appear related to local residence time of water infiltration through the soil and epikarst. When short transit time and limited interaction with soil and bedrock, as in Cova de Cala Varques A, the so-called “reservoir” effect is negligible and 14C and U-Th ages corresponds within the error range. When the residence time is longer, as in Cova des Pas de Vallgornera, 14C ages are steadily 2,300-2,400 years older than the U-Th data, as shown by the mean value (25%) of estimated percent dead carbon proportions and by higher and better correlated contents of major and trace elements in the vadose support of this speleothem encrustation. The potential use of this multi-method approach to paleoenvironmental studies is also suggested.http://www.ijs.speleo.it/pdf/74.603.40(1)_Tuccimei.et.al.pdfC14U/Th datingHoloceneSpeleothemcoastal karstMallorca
spellingShingle Tuccimei Paola
Van Strydonck Mark
Ginés Angel
Ginés Joaquin
Soligo Michele
Villa Igor
Fornós Joan J.
Comparison of 14C and U-Th ages of two Holocene phreatic overgrowths on speleothems from Mallorca (Western Mediterranean): Environmental implications
International Journal of Speleology
C14
U/Th dating
Holocene
Speleothem
coastal karst
Mallorca
title Comparison of 14C and U-Th ages of two Holocene phreatic overgrowths on speleothems from Mallorca (Western Mediterranean): Environmental implications
title_full Comparison of 14C and U-Th ages of two Holocene phreatic overgrowths on speleothems from Mallorca (Western Mediterranean): Environmental implications
title_fullStr Comparison of 14C and U-Th ages of two Holocene phreatic overgrowths on speleothems from Mallorca (Western Mediterranean): Environmental implications
title_full_unstemmed Comparison of 14C and U-Th ages of two Holocene phreatic overgrowths on speleothems from Mallorca (Western Mediterranean): Environmental implications
title_short Comparison of 14C and U-Th ages of two Holocene phreatic overgrowths on speleothems from Mallorca (Western Mediterranean): Environmental implications
title_sort comparison of 14c and u th ages of two holocene phreatic overgrowths on speleothems from mallorca western mediterranean environmental implications
topic C14
U/Th dating
Holocene
Speleothem
coastal karst
Mallorca
url http://www.ijs.speleo.it/pdf/74.603.40(1)_Tuccimei.et.al.pdf
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