Cooling of hydrothermal fluids rich in carbon dioxide can create large karst cave systems in carbonate rocks

Abstract Karst systems, comprising interconnected voids and caves, are ubiquitous in carbonate formations and play a pivotal role in the global water supply. Accumulating evidence suggests that a significant portion of the global karst is hypogenic, formed via rock dissolution by groundwater ascendi...

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Main Authors: Roi Roded, Einat Aharonov, Amos Frumkin, Nurit Weber, Boaz Lazar, Piotr Szymczak
Format: Article
Language:English
Published: Nature Portfolio 2023-12-01
Series:Communications Earth & Environment
Online Access:https://doi.org/10.1038/s43247-023-01082-z
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author Roi Roded
Einat Aharonov
Amos Frumkin
Nurit Weber
Boaz Lazar
Piotr Szymczak
author_facet Roi Roded
Einat Aharonov
Amos Frumkin
Nurit Weber
Boaz Lazar
Piotr Szymczak
author_sort Roi Roded
collection DOAJ
description Abstract Karst systems, comprising interconnected voids and caves, are ubiquitous in carbonate formations and play a pivotal role in the global water supply. Accumulating evidence suggests that a significant portion of the global karst is hypogenic, formed via rock dissolution by groundwater ascending from depth (rather than by infiltration from the surface), yet the exact formation mechanism remains unclear. Here we show that cooling of carbon dioxide-rich geothermal fluids, which turns them into highly corrosive agents due to their retrograde solubility, can dissolve and sculpt large caves on short geological timescales. A conceptual hydro-thermo-geochemical scenario is numerically simulated, showing cave formation by rising hot water discharging into a confined layer. Our models predict field observations characteristic of hypogenic caves, including enigmatic locations of the largest passages and intricate maze-like networks. Finally, we suggest that deep-seated carbon dioxide consumption during karst formation may constitute a link to the global carbon cycle.
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spelling doaj.art-142c20af076b4fd98b951e844b7305152023-12-10T12:32:50ZengNature PortfolioCommunications Earth & Environment2662-44352023-12-014111510.1038/s43247-023-01082-zCooling of hydrothermal fluids rich in carbon dioxide can create large karst cave systems in carbonate rocksRoi Roded0Einat Aharonov1Amos Frumkin2Nurit Weber3Boaz Lazar4Piotr Szymczak5Institute of Earth Sciences, The Hebrew UniversityInstitute of Earth Sciences, The Hebrew UniversityInstitute of Earth Sciences, The Hebrew UniversityDepartment of Earth and Planetary Sciences, The Weizmann Institute of ScienceInstitute of Earth Sciences, The Hebrew UniversityInstitute of Theoretical Physics, Faculty of Physics, University of WarsawAbstract Karst systems, comprising interconnected voids and caves, are ubiquitous in carbonate formations and play a pivotal role in the global water supply. Accumulating evidence suggests that a significant portion of the global karst is hypogenic, formed via rock dissolution by groundwater ascending from depth (rather than by infiltration from the surface), yet the exact formation mechanism remains unclear. Here we show that cooling of carbon dioxide-rich geothermal fluids, which turns them into highly corrosive agents due to their retrograde solubility, can dissolve and sculpt large caves on short geological timescales. A conceptual hydro-thermo-geochemical scenario is numerically simulated, showing cave formation by rising hot water discharging into a confined layer. Our models predict field observations characteristic of hypogenic caves, including enigmatic locations of the largest passages and intricate maze-like networks. Finally, we suggest that deep-seated carbon dioxide consumption during karst formation may constitute a link to the global carbon cycle.https://doi.org/10.1038/s43247-023-01082-z
spellingShingle Roi Roded
Einat Aharonov
Amos Frumkin
Nurit Weber
Boaz Lazar
Piotr Szymczak
Cooling of hydrothermal fluids rich in carbon dioxide can create large karst cave systems in carbonate rocks
Communications Earth & Environment
title Cooling of hydrothermal fluids rich in carbon dioxide can create large karst cave systems in carbonate rocks
title_full Cooling of hydrothermal fluids rich in carbon dioxide can create large karst cave systems in carbonate rocks
title_fullStr Cooling of hydrothermal fluids rich in carbon dioxide can create large karst cave systems in carbonate rocks
title_full_unstemmed Cooling of hydrothermal fluids rich in carbon dioxide can create large karst cave systems in carbonate rocks
title_short Cooling of hydrothermal fluids rich in carbon dioxide can create large karst cave systems in carbonate rocks
title_sort cooling of hydrothermal fluids rich in carbon dioxide can create large karst cave systems in carbonate rocks
url https://doi.org/10.1038/s43247-023-01082-z
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AT amosfrumkin coolingofhydrothermalfluidsrichincarbondioxidecancreatelargekarstcavesystemsincarbonaterocks
AT nuritweber coolingofhydrothermalfluidsrichincarbondioxidecancreatelargekarstcavesystemsincarbonaterocks
AT boazlazar coolingofhydrothermalfluidsrichincarbondioxidecancreatelargekarstcavesystemsincarbonaterocks
AT piotrszymczak coolingofhydrothermalfluidsrichincarbondioxidecancreatelargekarstcavesystemsincarbonaterocks