Effects of sepiolite addition to acrylic-latex paint on pull-off adhesion strength in nanosilver-impregnated and thermally-modified beech (Fagus orientalis L.) wood

Abstract Sepiolite is a silicate mineral that improves the fire properties in solid wood when mixed with a water-based coating. The present study was carried out to investigate and evaluate the effects of sepiolite addition to acrylic-latex paint on the pull-off adhesion strength, as an important ch...

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Main Authors: Hamid R. Taghiyari, Petar Antov, Abolfazl Soltani, Dorina Camelia Ilies, Elham Nadali, Seng Hua Lee, Vasile Grama, Tripa Simona
Format: Article
Language:English
Published: Nature Portfolio 2024-02-01
Series:Scientific Reports
Subjects:
Online Access:https://doi.org/10.1038/s41598-024-54451-9
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author Hamid R. Taghiyari
Petar Antov
Abolfazl Soltani
Dorina Camelia Ilies
Elham Nadali
Seng Hua Lee
Vasile Grama
Tripa Simona
author_facet Hamid R. Taghiyari
Petar Antov
Abolfazl Soltani
Dorina Camelia Ilies
Elham Nadali
Seng Hua Lee
Vasile Grama
Tripa Simona
author_sort Hamid R. Taghiyari
collection DOAJ
description Abstract Sepiolite is a silicate mineral that improves the fire properties in solid wood when mixed with a water-based coating. The present study was carried out to investigate and evaluate the effects of sepiolite addition to acrylic-latex paint on the pull-off adhesion strength, as an important characteristic of paints and finishes used in the modern furniture industry and historical furniture as well for preservation and restoration of heritage objects. Sepiolite was added at the rate of 10%, and brushed onto plain-sawn beech (Fagus orientalis L.) wood specimens, unimpregnated and impregnated with a 400 ppm silver nano-suspension, which were further thermally modified at 185 °C for 4 h. The results showed that thermal modification had a decreasing effect on the pull-off adhesion strength, primarily as a result of the thermal degradation of cell-wall polymers (mostly hemicelluloses). Still, a decreased wettability as a result of condensation and plasticization of lignin was also partially influential. Based on the obtained results,thermal modification was found to have a significant influence on pull-off adhesion strength. Sepiolite addition had a decreasing effectin all treatments, though the effect was not statistically significant in all treatments. The maximum and minimum decreases due to sepiolite addition were observed in the unimpregnated control (21%) and the thermally-modified NS-impregnated (4%) specimens. Other aspects of the sepiolite addition, and further studies that cover different types of paints and coatings, should be evaluated before coming to a final firm conclusion in this regard.
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spelling doaj.art-143adf33602e455f8f817d6bc17a52052024-03-05T19:04:26ZengNature PortfolioScientific Reports2045-23222024-02-0114111210.1038/s41598-024-54451-9Effects of sepiolite addition to acrylic-latex paint on pull-off adhesion strength in nanosilver-impregnated and thermally-modified beech (Fagus orientalis L.) woodHamid R. Taghiyari0Petar Antov1Abolfazl Soltani2Dorina Camelia Ilies3Elham Nadali4Seng Hua Lee5Vasile Grama6Tripa Simona7Wood Science and Technology Department, Faculty of Materials Engineering &Interdisciplinary Sciences, Shahid Rajaee Teacher Training University (SRTTU)Department of Mechanical Wood Technology, Faculty of Forest Industry, University of ForestryDepartment of Civil Engineering – Geotechnics, Faculty of Civil Engineering, Shahid Rajaee Teacher Training University (SRTTU)Department of Geography, Tourism, and Territorial Planning, Faculty of Geography, Tourism, and Sport, University of OradeaDepartment of Wood & Paper Science and Technology, Faculty of Natural Resources, University of TehranDepartment of Wood Industry, Faculty of Applied Sciences, Universiti Teknologi MARA (UiTM) Cawangan PahangDepartment of Geography, Tourism, and Territorial Planning, Faculty of Geography, Tourism, and Sport, University of OradeaDepartment of Textiles, Leather and Industrial Management, Faculty of Energy Engineering and Industrial Management, University of OradeaAbstract Sepiolite is a silicate mineral that improves the fire properties in solid wood when mixed with a water-based coating. The present study was carried out to investigate and evaluate the effects of sepiolite addition to acrylic-latex paint on the pull-off adhesion strength, as an important characteristic of paints and finishes used in the modern furniture industry and historical furniture as well for preservation and restoration of heritage objects. Sepiolite was added at the rate of 10%, and brushed onto plain-sawn beech (Fagus orientalis L.) wood specimens, unimpregnated and impregnated with a 400 ppm silver nano-suspension, which were further thermally modified at 185 °C for 4 h. The results showed that thermal modification had a decreasing effect on the pull-off adhesion strength, primarily as a result of the thermal degradation of cell-wall polymers (mostly hemicelluloses). Still, a decreased wettability as a result of condensation and plasticization of lignin was also partially influential. Based on the obtained results,thermal modification was found to have a significant influence on pull-off adhesion strength. Sepiolite addition had a decreasing effectin all treatments, though the effect was not statistically significant in all treatments. The maximum and minimum decreases due to sepiolite addition were observed in the unimpregnated control (21%) and the thermally-modified NS-impregnated (4%) specimens. Other aspects of the sepiolite addition, and further studies that cover different types of paints and coatings, should be evaluated before coming to a final firm conclusion in this regard.https://doi.org/10.1038/s41598-024-54451-9Coating and finishPaint pull-off strengthPorous structureSepioliteSilver nano-suspensionThermal modification
spellingShingle Hamid R. Taghiyari
Petar Antov
Abolfazl Soltani
Dorina Camelia Ilies
Elham Nadali
Seng Hua Lee
Vasile Grama
Tripa Simona
Effects of sepiolite addition to acrylic-latex paint on pull-off adhesion strength in nanosilver-impregnated and thermally-modified beech (Fagus orientalis L.) wood
Scientific Reports
Coating and finish
Paint pull-off strength
Porous structure
Sepiolite
Silver nano-suspension
Thermal modification
title Effects of sepiolite addition to acrylic-latex paint on pull-off adhesion strength in nanosilver-impregnated and thermally-modified beech (Fagus orientalis L.) wood
title_full Effects of sepiolite addition to acrylic-latex paint on pull-off adhesion strength in nanosilver-impregnated and thermally-modified beech (Fagus orientalis L.) wood
title_fullStr Effects of sepiolite addition to acrylic-latex paint on pull-off adhesion strength in nanosilver-impregnated and thermally-modified beech (Fagus orientalis L.) wood
title_full_unstemmed Effects of sepiolite addition to acrylic-latex paint on pull-off adhesion strength in nanosilver-impregnated and thermally-modified beech (Fagus orientalis L.) wood
title_short Effects of sepiolite addition to acrylic-latex paint on pull-off adhesion strength in nanosilver-impregnated and thermally-modified beech (Fagus orientalis L.) wood
title_sort effects of sepiolite addition to acrylic latex paint on pull off adhesion strength in nanosilver impregnated and thermally modified beech fagus orientalis l wood
topic Coating and finish
Paint pull-off strength
Porous structure
Sepiolite
Silver nano-suspension
Thermal modification
url https://doi.org/10.1038/s41598-024-54451-9
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