Chloridodiphenyl{[1-(1,3-thiazol-2-yl-κN)ethylidene]-4-phenylthiosemicarbazidato-κ2N1,S}tin(IV) methanol monosolvate
The title compound, [Sn(C6H5)2(C12H11N4S2)Cl]·CH4O, is formed during the reaction between 2-acetylthiazole 4-phenylthiosemicarbazone (Hacthptsc) and diphenyltin(IV) dichloride in methanol. In the crystal structure, the Sn atom exhibits an octahedral geometry with the [N2S] anionic tride...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811037627 |
| _version_ | 1818321984448102400 |
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| author | Hongtao Yu Ramaiyer Venkatraman Samuel S. R. Dasary Sri Ranjini Arumugam Frank R. Fronczek |
| author_facet | Hongtao Yu Ramaiyer Venkatraman Samuel S. R. Dasary Sri Ranjini Arumugam Frank R. Fronczek |
| author_sort | Hongtao Yu |
| collection | DOAJ |
| description | The title compound, [Sn(C6H5)2(C12H11N4S2)Cl]·CH4O, is formed during the reaction between 2-acetylthiazole 4-phenylthiosemicarbazone (Hacthptsc) and diphenyltin(IV) dichloride in methanol. In the crystal structure, the Sn atom exhibits an octahedral geometry with the [N2S] anionic tridentate thiosemicarbazone ligand having chloride trans to the central N and the two phenyl groups trans to each other. The Sn—Cl distance is 2.5929 (6), Sn—S is 2.4896 (6) and Sn—N to the central N is 2.3220 (16) Å. The MeOH molecules link the Sn complexes into one-dimensional chains via N—H...O and O—H...Cl hydrogen bonds. |
| first_indexed | 2024-12-13T10:49:35Z |
| format | Article |
| id | doaj.art-1448f79d328e47428f55cade85ca3465 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:49:35Z |
| publishDate | 2011-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1448f79d328e47428f55cade85ca34652022-12-21T23:49:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1409m141010.1107/S1600536811037627Chloridodiphenyl{[1-(1,3-thiazol-2-yl-κN)ethylidene]-4-phenylthiosemicarbazidato-κ2N1,S}tin(IV) methanol monosolvateHongtao YuRamaiyer VenkatramanSamuel S. R. DasarySri Ranjini ArumugamFrank R. FronczekThe title compound, [Sn(C6H5)2(C12H11N4S2)Cl]·CH4O, is formed during the reaction between 2-acetylthiazole 4-phenylthiosemicarbazone (Hacthptsc) and diphenyltin(IV) dichloride in methanol. In the crystal structure, the Sn atom exhibits an octahedral geometry with the [N2S] anionic tridentate thiosemicarbazone ligand having chloride trans to the central N and the two phenyl groups trans to each other. The Sn—Cl distance is 2.5929 (6), Sn—S is 2.4896 (6) and Sn—N to the central N is 2.3220 (16) Å. The MeOH molecules link the Sn complexes into one-dimensional chains via N—H...O and O—H...Cl hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811037627 |
| spellingShingle | Hongtao Yu Ramaiyer Venkatraman Samuel S. R. Dasary Sri Ranjini Arumugam Frank R. Fronczek Chloridodiphenyl{[1-(1,3-thiazol-2-yl-κN)ethylidene]-4-phenylthiosemicarbazidato-κ2N1,S}tin(IV) methanol monosolvate Acta Crystallographica Section E |
| title | Chloridodiphenyl{[1-(1,3-thiazol-2-yl-κN)ethylidene]-4-phenylthiosemicarbazidato-κ2N1,S}tin(IV) methanol monosolvate |
| title_full | Chloridodiphenyl{[1-(1,3-thiazol-2-yl-κN)ethylidene]-4-phenylthiosemicarbazidato-κ2N1,S}tin(IV) methanol monosolvate |
| title_fullStr | Chloridodiphenyl{[1-(1,3-thiazol-2-yl-κN)ethylidene]-4-phenylthiosemicarbazidato-κ2N1,S}tin(IV) methanol monosolvate |
| title_full_unstemmed | Chloridodiphenyl{[1-(1,3-thiazol-2-yl-κN)ethylidene]-4-phenylthiosemicarbazidato-κ2N1,S}tin(IV) methanol monosolvate |
| title_short | Chloridodiphenyl{[1-(1,3-thiazol-2-yl-κN)ethylidene]-4-phenylthiosemicarbazidato-κ2N1,S}tin(IV) methanol monosolvate |
| title_sort | chloridodiphenyl 1 1 3 thiazol 2 yl amp 954 n ethylidene 4 phenylthiosemicarbazidato amp 954 2n1 s tin iv methanol monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811037627 |
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