OCCURRENCE AND SOURCES OF PRIORITY POLYCYCLIC AROMATIC HYDROCARBONS IN SEDIMENT SAMPLES ALONG THE AURÁ RIVER (NORTHERN BRAZIL)

Polycyclic aromatic hydrocarbons (PAHs) are organic compounds generated by the organic matter incomplete combustion and there are sixteen PAHs (16-USEPA-PAHs) considered as priority in environmental studies by the Environmental Protection Agency of the United States. The aims of this work was to det...

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Main Authors: Camila Carneiro Santos, Lorena da Silva Soares, José Augusto Martins Corrêa
Format: Article
Language:English
Published: Sociedade Brasileira de Geoquímica 2016-09-01
Series:Geochimica Brasiliensis
Subjects:
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author Camila Carneiro Santos
Lorena da Silva Soares
José Augusto Martins Corrêa
author_facet Camila Carneiro Santos
Lorena da Silva Soares
José Augusto Martins Corrêa
author_sort Camila Carneiro Santos
collection DOAJ
description Polycyclic aromatic hydrocarbons (PAHs) are organic compounds generated by the organic matter incomplete combustion and there are sixteen PAHs (16-USEPA-PAHs) considered as priority in environmental studies by the Environmental Protection Agency of the United States. The aims of this work was to determine the major source and spatial variations of the 16-USEPA-PAHs in the sediments of Aurá river. North of the Aurá river exists a landfill site, currently disabled, which operated in an uncontrolled and irregular manner for about 24 years. PAHs were identified and quantified in sediment from 10 sites inside the river and in its mouth. The samples were analyzed by HPLC/UV-Vis-DAD to assess the degree of contamination. Total PAH concentrations (ΣPAHs) ranged from 3 824.21 to 15 693.91 ng g-1. In general, a concentration gradient was observed. The sediment samples were classified as highly contaminated (ΣPAHs > 500 ng g-1). Compared to other areas, PAH concentrations in Aurá river are relatively similar to highly industrialized and polluted places. The ratios of low molecular weight/high molecular weight PAHs (LMW/HMW), indicates a pyrolytic origin, which have shown to be mostly from waste combustion.
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spelling doaj.art-145d2b319d0948b3ab547bfe0c427da32022-12-21T22:51:04ZengSociedade Brasileira de GeoquímicaGeochimica Brasiliensis0102-98002358-28122016-09-01301263210.21715/GB2358-2812.2016301026OCCURRENCE AND SOURCES OF PRIORITY POLYCYCLIC AROMATIC HYDROCARBONS IN SEDIMENT SAMPLES ALONG THE AURÁ RIVER (NORTHERN BRAZIL)Camila Carneiro Santos0Lorena da Silva Soares1José Augusto Martins Corrêa2Universidade Federal do ParáUniversidade Federal ParáUniversidade Federal do ParáPolycyclic aromatic hydrocarbons (PAHs) are organic compounds generated by the organic matter incomplete combustion and there are sixteen PAHs (16-USEPA-PAHs) considered as priority in environmental studies by the Environmental Protection Agency of the United States. The aims of this work was to determine the major source and spatial variations of the 16-USEPA-PAHs in the sediments of Aurá river. North of the Aurá river exists a landfill site, currently disabled, which operated in an uncontrolled and irregular manner for about 24 years. PAHs were identified and quantified in sediment from 10 sites inside the river and in its mouth. The samples were analyzed by HPLC/UV-Vis-DAD to assess the degree of contamination. Total PAH concentrations (ΣPAHs) ranged from 3 824.21 to 15 693.91 ng g-1. In general, a concentration gradient was observed. The sediment samples were classified as highly contaminated (ΣPAHs > 500 ng g-1). Compared to other areas, PAH concentrations in Aurá river are relatively similar to highly industrialized and polluted places. The ratios of low molecular weight/high molecular weight PAHs (LMW/HMW), indicates a pyrolytic origin, which have shown to be mostly from waste combustion.polycyclic aromatic hydrocarbonsamazon riverhigh performance liquid chromatography
spellingShingle Camila Carneiro Santos
Lorena da Silva Soares
José Augusto Martins Corrêa
OCCURRENCE AND SOURCES OF PRIORITY POLYCYCLIC AROMATIC HYDROCARBONS IN SEDIMENT SAMPLES ALONG THE AURÁ RIVER (NORTHERN BRAZIL)
Geochimica Brasiliensis
polycyclic aromatic hydrocarbons
amazon river
high performance liquid chromatography
title OCCURRENCE AND SOURCES OF PRIORITY POLYCYCLIC AROMATIC HYDROCARBONS IN SEDIMENT SAMPLES ALONG THE AURÁ RIVER (NORTHERN BRAZIL)
title_full OCCURRENCE AND SOURCES OF PRIORITY POLYCYCLIC AROMATIC HYDROCARBONS IN SEDIMENT SAMPLES ALONG THE AURÁ RIVER (NORTHERN BRAZIL)
title_fullStr OCCURRENCE AND SOURCES OF PRIORITY POLYCYCLIC AROMATIC HYDROCARBONS IN SEDIMENT SAMPLES ALONG THE AURÁ RIVER (NORTHERN BRAZIL)
title_full_unstemmed OCCURRENCE AND SOURCES OF PRIORITY POLYCYCLIC AROMATIC HYDROCARBONS IN SEDIMENT SAMPLES ALONG THE AURÁ RIVER (NORTHERN BRAZIL)
title_short OCCURRENCE AND SOURCES OF PRIORITY POLYCYCLIC AROMATIC HYDROCARBONS IN SEDIMENT SAMPLES ALONG THE AURÁ RIVER (NORTHERN BRAZIL)
title_sort occurrence and sources of priority polycyclic aromatic hydrocarbons in sediment samples along the aura river northern brazil
topic polycyclic aromatic hydrocarbons
amazon river
high performance liquid chromatography
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AT lorenadasilvasoares occurrenceandsourcesofprioritypolycyclicaromatichydrocarbonsinsedimentsamplesalongtheaurarivernorthernbrazil
AT joseaugustomartinscorrea occurrenceandsourcesofprioritypolycyclicaromatichydrocarbonsinsedimentsamplesalongtheaurarivernorthernbrazil