Desiccant effect of starch in polylactic acid composites

Polylactic acid (PLA)/starch and PLA/starch-glycerol composites with different glycerol contents were prepared in a wide composition range, in order to study their applicability as packaging materials for dry products. Water uptake was determined at a temperature of 23 °C and different relative humi...

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Main Authors: J. Moczo, D. Kun, E. Fekete
Format: Article
Language:English
Published: Budapest University of Technology 2018-11-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0009205&mi=cd
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author J. Moczo
D. Kun
E. Fekete
author_facet J. Moczo
D. Kun
E. Fekete
author_sort J. Moczo
collection DOAJ
description Polylactic acid (PLA)/starch and PLA/starch-glycerol composites with different glycerol contents were prepared in a wide composition range, in order to study their applicability as packaging materials for dry products. Water uptake was determined at a temperature of 23 °C and different relative humidities. Structure and mechanical properties were also investigated. PLA/ unplasticized starch composites could absorb a considerable amount of water. As a result, they may be adequate as a biodegradable inner container in dry packaging. The absorption capacity of the composites increased significantly with increasing starch content and relative humidity, respectively. Unplasticized starch exhibited not only a desiccant but also a reinforcing effect in PLA, thus both stiffness and strength increased with increasing starch loading. The nfluence of glycerol content on the water uptake was difficult to reveal due to the migration of glycerol from the bulk to the surface. Furthermore, glycerol weakened the PLA/starch adhesion and softened starch particles.
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spelling doaj.art-146187aa2c4d4529b314cb46bb35764c2022-12-21T19:11:47ZengBudapest University of TechnologyeXPRESS Polymer Letters1788-618X2018-11-0112111014102410.3144/expresspolymlett.2018.88Desiccant effect of starch in polylactic acid compositesJ. MoczoD. KunE. FeketePolylactic acid (PLA)/starch and PLA/starch-glycerol composites with different glycerol contents were prepared in a wide composition range, in order to study their applicability as packaging materials for dry products. Water uptake was determined at a temperature of 23 °C and different relative humidities. Structure and mechanical properties were also investigated. PLA/ unplasticized starch composites could absorb a considerable amount of water. As a result, they may be adequate as a biodegradable inner container in dry packaging. The absorption capacity of the composites increased significantly with increasing starch content and relative humidity, respectively. Unplasticized starch exhibited not only a desiccant but also a reinforcing effect in PLA, thus both stiffness and strength increased with increasing starch loading. The nfluence of glycerol content on the water uptake was difficult to reveal due to the migration of glycerol from the bulk to the surface. Furthermore, glycerol weakened the PLA/starch adhesion and softened starch particles.http://www.expresspolymlett.com/letolt.php?file=EPL-0009205&mi=cdBiopolymers, biocompositesthermoplastic starchpolylactic acidbiodegradable packagingwater uptake
spellingShingle J. Moczo
D. Kun
E. Fekete
Desiccant effect of starch in polylactic acid composites
eXPRESS Polymer Letters
Biopolymers, biocomposites
thermoplastic starch
polylactic acid
biodegradable packaging
water uptake
title Desiccant effect of starch in polylactic acid composites
title_full Desiccant effect of starch in polylactic acid composites
title_fullStr Desiccant effect of starch in polylactic acid composites
title_full_unstemmed Desiccant effect of starch in polylactic acid composites
title_short Desiccant effect of starch in polylactic acid composites
title_sort desiccant effect of starch in polylactic acid composites
topic Biopolymers, biocomposites
thermoplastic starch
polylactic acid
biodegradable packaging
water uptake
url http://www.expresspolymlett.com/letolt.php?file=EPL-0009205&mi=cd
work_keys_str_mv AT jmoczo desiccanteffectofstarchinpolylacticacidcomposites
AT dkun desiccanteffectofstarchinpolylacticacidcomposites
AT efekete desiccanteffectofstarchinpolylacticacidcomposites