Efficient manganese luminescence induced by Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer in rare earth fluoride and phosphate nanocrystals

<p>Abstract</p> <p>Manganese materials with attractive optical properties have been proposed for applications in such areas as photonics, light-emitting diodes, and bioimaging. In this paper, we have demonstrated multicolor Mn<sup>2+ </sup>luminescence in the visible re...

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Main Authors: Ding Yun, Liang Liang-Bo, Li Min, He Ding-Fei, Xu Liang, Wang Pan, Yu Xue-Feng
Format: Article
Language:English
Published: SpringerOpen 2011-01-01
Series:Nanoscale Research Letters
Online Access:http://www.nanoscalereslett.com/content/6/1/119
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author Ding Yun
Liang Liang-Bo
Li Min
He Ding-Fei
Xu Liang
Wang Pan
Yu Xue-Feng
author_facet Ding Yun
Liang Liang-Bo
Li Min
He Ding-Fei
Xu Liang
Wang Pan
Yu Xue-Feng
author_sort Ding Yun
collection DOAJ
description <p>Abstract</p> <p>Manganese materials with attractive optical properties have been proposed for applications in such areas as photonics, light-emitting diodes, and bioimaging. In this paper, we have demonstrated multicolor Mn<sup>2+ </sup>luminescence in the visible region by controlling Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer in rare earth nanocrystals [NCs]. CeF<sub>3 </sub>and CePO<sub>4 </sub>NCs doped with Mn<sup>2+ </sup>have been prepared and can be well dispersed in aqueous solutions. Under ultraviolet light excitation, both the CeF<sub>3</sub>:Mn and CePO<sub>4</sub>:Mn NCs exhibit Mn<sup>2+ </sup>luminescence, yet their output colors are green and orange, respectively. By optimizing Mn<sup>2+ </sup>doping concentrations, Mn<sup>2+ </sup>luminescence quantum efficiency and Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer efficiency can respectively reach 14% and 60% in the CeF<sub>3</sub>:Mn NCs.</p>
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spelling doaj.art-1472e2acda7d427aabb187fcd810285e2023-08-02T03:46:56ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2011-01-0161119Efficient manganese luminescence induced by Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer in rare earth fluoride and phosphate nanocrystalsDing YunLiang Liang-BoLi MinHe Ding-FeiXu LiangWang PanYu Xue-Feng<p>Abstract</p> <p>Manganese materials with attractive optical properties have been proposed for applications in such areas as photonics, light-emitting diodes, and bioimaging. In this paper, we have demonstrated multicolor Mn<sup>2+ </sup>luminescence in the visible region by controlling Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer in rare earth nanocrystals [NCs]. CeF<sub>3 </sub>and CePO<sub>4 </sub>NCs doped with Mn<sup>2+ </sup>have been prepared and can be well dispersed in aqueous solutions. Under ultraviolet light excitation, both the CeF<sub>3</sub>:Mn and CePO<sub>4</sub>:Mn NCs exhibit Mn<sup>2+ </sup>luminescence, yet their output colors are green and orange, respectively. By optimizing Mn<sup>2+ </sup>doping concentrations, Mn<sup>2+ </sup>luminescence quantum efficiency and Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer efficiency can respectively reach 14% and 60% in the CeF<sub>3</sub>:Mn NCs.</p>http://www.nanoscalereslett.com/content/6/1/119
spellingShingle Ding Yun
Liang Liang-Bo
Li Min
He Ding-Fei
Xu Liang
Wang Pan
Yu Xue-Feng
Efficient manganese luminescence induced by Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer in rare earth fluoride and phosphate nanocrystals
Nanoscale Research Letters
title Efficient manganese luminescence induced by Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer in rare earth fluoride and phosphate nanocrystals
title_full Efficient manganese luminescence induced by Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer in rare earth fluoride and phosphate nanocrystals
title_fullStr Efficient manganese luminescence induced by Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer in rare earth fluoride and phosphate nanocrystals
title_full_unstemmed Efficient manganese luminescence induced by Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer in rare earth fluoride and phosphate nanocrystals
title_short Efficient manganese luminescence induced by Ce<sup>3+</sup>-Mn<sup>2+ </sup>energy transfer in rare earth fluoride and phosphate nanocrystals
title_sort efficient manganese luminescence induced by ce sup 3 sup mn sup 2 sup energy transfer in rare earth fluoride and phosphate nanocrystals
url http://www.nanoscalereslett.com/content/6/1/119
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